• Title/Summary/Keyword: H2 absorption

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QUANTIFYING DARK GAS

  • LI, DI;XU, DUO;HEILES, CARL;PAN, ZHICHEN;TANG, NINGYU
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.75-78
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    • 2015
  • A growing body of evidence has been supporting the existence of so-called "dark molecular gas" (DMG), which is invisible in the most common tracer of molecular gas, i.e., CO rotational emission. DMG is believed to be the main gas component of the intermediate extinction region from Av~0.05-2, roughly corresponding to the self-shielding threshold of $H_2$ and $^{13}CO$. To quantify DMG relative to $H{\small{I}}$ and CO, we are pursuing three observational techniques; $H{\small{I}}$ self-absorption, OH absorption, and THz $C^+$ emission. In this paper, we focus on preliminary results from a CO and OH absorption survey of DMG candidates. Our analysis shows that the OH excitation temperature is close to that of the Galactic continuum background and that OH is a good DMG tracer co-existing with molecular hydrogen in regions without CO. Through systematic "absorption mapping" by the Square Kilometer Array (SKA) and ALMA, we will have unprecedented, comprehensive knowledge of the ISM components including DMG in terms of their temperature and density, which will impact our understanding of galaxy evolution and star formation profoundly.

A Study on Improvement of the Physical Properties of 4 Component Working Fluid in Gas Fired Absorption Chillers (가스흡수식 냉방기용 4성분계 작동매체의 물성 향상 연구)

  • Baek, Young-Soon;Oh, Young-Sam;Lee, Yong-Won;Park, Dal-Ryung;Koo, Ki-Kap
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.400-406
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    • 1999
  • In an effort to obtain high efficiency in gas fired absorption chillers, a new working fluid has been developed with thc addition of the component of $LiNO_3$, LiCl and LiI to the conventional solution of $LiBr-H_2O$. The solubility and vapor pressure of the 4 component working fluid developed in this work were measured and compared to the results of $LiBr-H_2O$ solution. It was observed that there exists an optimal mole ratio of the inorganic salts in terms of solubility. The mole ratio of LiBr, $LiNO_3$ and LiCl was found to be around 5:1:1~2 in the $LiBr-LiNO_3-LiCl-H_2O$ mixture, and in the case of $LiBr-LiO_3-Lil-H_2O$ and $LiBr-Lil-LiCl-H_2O$ mixtures, the mole ratio of LiBr, $LiNO_3$ and Lil/ LiBr, LiI and LiCl were found to be around 5:1:1 and 5:1:0.5~1 respectively. The vapor pressure of the 4 component working fluid of the optimal mole ratio was increascd with adding the component of $LiNO_3$, LiCl and LiI except for $LiBr-LiNO_3-LiCl-H_2O$ mixture. The absorption capacity of $LiBr-LiNO_3-LiCl-H_2O$ mixture was obtained higher than that of $LiBr-H_2O$ mixture.

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Absorption of SO2 at High Temperatures by Ionic Liquids and the Absorption Mechanism

  • Tian, Shidong;Hou, Yucui;Wu, Weize;Ren, Shuhang;Qian, Jianguo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2791-2796
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    • 2014
  • The capture of $SO_2$ at or close to the temperatures of real flue gas is much more attractive in application. In this work, two kinds of ionic liquids (ILs) based on lactate anion were used to absorb $SO_2$ at high temperatures from 100 to $120^{\circ}C$. The ILs show high absorption capacities of over one mol $SO_2$ per mol IL at $110^{\circ}C$. The absorption of $SO_2$ by the ILs based on lactate anion is reversible and the ILs can be reused for the capture of $SO_2$ at high temperatures with high absorption capacity and thermal stability. Furthermore, the absorption mechanism of $SO_2$ by the ILs was studied by FT-IR, $^1H$ NMR and $^{13}C$ NMR spectra. It has been found that there are strong chemical interactions between the ILs and $SO_2$. Also the absorption mechanism is different when there is water present in ILs compared to when there is not.

The Uptake of Lead Ion with Staphylococcus epidermidis (Staphylococcus epidermidis 를 이용한 납 이온의 축적에 관한 연구)

  • 김종혜;김말남
    • Korean Journal of Microbiology
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    • v.30 no.4
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    • pp.310-315
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    • 1992
  • Absorption of $\textrm{Pb}^{2-}$ from aqueous solution was studied using Staphylococcus epidermidis. Cells of exponential phase were employed as absorbents. Uptake ratio defined as the ratio of amount of $\textrm{Pb}^{2+}$ absorbed to that of initial $\textrm{Pb}^{2+}$. Absorption of $\textrm{Pb}^{2+}$ increased with increase in cell concentration. while amount of $\textrm{Pb}^{2+}$ per unit cell mass decreased. Uptake ratio of $\textrm{Pb}^{2+}$ augmented and then diminished after exhibiting a maximum as the pH of the solution increased. Equilibrium absorption of $\textrm{Pb}^{2+}$ deviated from Freundlich isotherm especially at higher concentration of $\textrm{Pb}^{2+}$ due to the precipitation phenomena. HCI and EDTA were founded to desorb $\textrm{Pb}^{2+}$ more effectively than $\textrm{Na}_{2}\textrm{CO}_{3}$ or $\textrm{NaHCO}_{3}$. After 10 cycles of absorption and desorption. $\textrm{Pb}^{2+}$ absorption capability remained almost unchanged and the biomass had leaked out 30-40 wt/%. Uptake ratio of Pb2+ decreased in the presence of other heavy metal ions due to the competitive absorption The inhibition of $\textrm{Pb}^{2+}$ absorption appeared to have a strong correlation with ionic radius of the competing ions. Especially $\textrm{Cr}^{3-}$, $\textrm{Co}^{2+}$ or $\textrm{Fe}^{2+}$ having smaller ionic radius depressed more significantly the uptake of $\textrm{Pb}^{2+}$ than any other metal ions tested.

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Analysis of Absorption Refrigeration Cycles to Utilize Treated Sewage (하수처리수이용 흡수식냉동사이클의 해석)

  • Lee, Y.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.2
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    • pp.288-298
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    • 1996
  • The gas-fired absorption refrigeration system to utilize treated sewage is available for environmental protection and energy conservation. Simulation analysis on the double-effect absorption refrigeration cycles with parallel or series flow type has been performed. The working fluid is Lithium Bromide and water solution. The main purpose of this study is evaluating the possibilities of effective utilization of treated sewage as a cooling water for the absorber and condenser. The efficiency of a couple of cycles has been studied and simulation results show that higher coefficient of performance could be obtained for parallel flow type. The other purpose of the present study is to determine the optimum designs and operating conditions based on the operating constraints and the coefficent of performance in the paralledl flow type.

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Rectification Characteristic of Packing Materials in the Packed-type Rectifier of $NH_3/H_2O$ Absorption Heat Pump (암모니아 흡수식 열펌프 충전식 정류기의 정류 특성에 관한 연구)

  • 김돈수;윤상국
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.10
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    • pp.775-780
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    • 2002
  • An experimental study on the characteristics of several kinds of packing materials was carried out in order to get the optimum design data for the packed-type rectification system of an NH$_3$/$H_2O$ GAX absorption heat pump. Several suitable packing materials were examined and the bulk of steel wire was shown as the most effective packing material in rectifier. The optimum volumetric ratio of packed steel wire in rectifier was obtained as around 36%. The performance results can be adapted in rectifier design of absorption heat pump.

Detection of Spurious Jindo Hongju

  • Choi, Kap-Seong;Song, Bo-Hyeon;Kim, Jung-Ho
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 1996.04a
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    • pp.25-25
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    • 1996
  • ;Jindo Hongju is an unique red-colored traditional distilled wine of Korea. The unique attractive color of Jindo Hongju is due to the pigments of gromwell (Lithospermum erythrorhizon) root, derivatives of naphtoquinone such as shikonin and acetylshikonin. Which are extracted during the distillation process. The attractive color of the gromwell pigments is easily changed to dark red or to brown causing deterioration of the Quality of Jindo Hongju. Due to the discoloration of the pigments and to the limited supply of gromwell roots, some brewers manufacture spurious Jindo Hongju using artificial colorants. This study was performed to devise a simple method of detecting spurious Jindo Hongju products. The color of the gromwell pigments was greatly affected by pH change and the change could be demonstrated by the change of the absorption spectrum. At pH 4.0 the normal pH of Jindo Hongju, the absorption spectra of gromwell pigments and genuine Hongju products showed an absorption maximum of 520 nm. The absorption maximum was shifted to 570 nm and to 616 nm as the pH was raised to 7.0 and 11.0 respectively. This transition due to the pH change was also demonstrated on em chromaticity diagram. The characteristic transition due to pH change of gromwell pigment solution was not observed with an artificial colorant (red No.2) which was suspected to be used in the manufacture of imitation products. The absorption spectra of most of the Jindo Hongju collected from the market were similar to that of the gromwell pigments and showed the characteristic transition due to pH change with the addition of NaOH. However, with a few of the products, the absorption spectra was similar to that of the artificial colorant and the characteristic transition due to pH change was not observed, indicating these products might have been forged. The result of study suggests that the transition of the absorption spectrum and the change of the color due to pH change be used for the detection of imitation products. Farther more, since, at pH above 9.0, the color of the gromwell pigments and genuine Jindo Hongju could be visually differentiated from that of the artificial colorant and forged products, it might be possible that the forged products be easily detected by raising the pH to above 9.0 and visually comparing the color with that of the gromwell pigment at the same pH.me pH.

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Characterization of valacyclovir transport mechanism across the intestinal epithelium

  • Han, H.;Covitz, M.;Surendran, N.;Stewart, B.;Amidon, G.L.
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1997.04a
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    • pp.119-119
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    • 1997
  • Valacyclovir is a L-valyl ester prodrug of acyclovir which is a highly effective and selective antiviral agent in the treatment of herpes virus diseases. Valacyclovir is rapidly and almost completely converted to acyclovir and increases the oral bioavailability of acyclovir three to five fold. However, the intestinal absorption mechanism of valacyclovir is not clear. If the improved absorption mechanism of valacyclovir is fully understood, it will provide a rationale of designing the amino acid ester prodrugs of polar drugs containing hydroxyl group. The main objective of our present study is to characterize the membrane transport mechanism of valacyclovir. Methods : Intestinal absorption of valacyclovir was investigated by using in-situ rat perfusion study and its wall permeability was estimated by modified boundary layer model. The membrane transport mechanism was also investigated through the uptake study in Caco-2 cells and in CHO-hPepTl cells. Results : In the rat perfusion study, the wall permeability of valacyclovir was ten times higher than acyclovir and showed concentration dependency, Valacyclovir also demonstrated a D,L stereo-selectivity with L-isomer having an approximately five-fold higher permeability than D-isomer. Mixed dipeptides and cephalexin, which are transported by dipeptide carriers, strongly competed with valacyclovir for the intestinal absorption, while L-valine did not show any competition with valacyclovir. This indicated that the intestinal absorption of valacyclovir could be dipeptide carrier-mediated. In addition, the competitive uptake study in Caco-2 cells presented that dipeptides reduced the valacyclovir uptake but valine did not. Also, in IC$\sub$50/ study, valacyclovir showed strong inhibition on the $^3$H-gly-sar uptake in CHO-hPepTl cells over-expressing a human intestinal peptide transporter. Taken together, the result from our present study indicated that valacyclovir utilized the peptide transporter for the intestinal absorption.

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CO2 Absorption by Alkali-modified Amino Acid Salts (알칼리금속을 함침시킨 아미노산 염 수용액의 이산화탄소 흡수특성 연구)

  • Lim, Yun-Hui;Jo, Young-Min;Park, Joon-Seok
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.526-531
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    • 2011
  • The present study attempted to impregnate alkali metals to amino acid in order to improve $CO_2$ absorption capacity. A used amino acid was glycine, of which pH increased up to about 11 with the addition of alkalies. $CO_2$ absorption capacity of amino acid salts was evaluated in a batch and a continuous process. The absorption capacity appeared in turns as; Sodium Glycinate ${\geq}$ Lithium Glycinate > Potassium Glycinate. Amino acid salts showed lower absolute capacity of $CO_2$ absorption than primary amine (Monoethanolamine) at $20^{\circ}C$. In a continuous absorption with 10% $CO_2$ flow, the increasing the reaction temperature, the increasing rate of absorption for amino and was higher that of than amino absorbent.

Performance Analysis of a 5 RT Air-Cooled $NH_3-H_2O$ Absorption Chiller with the Variations of Heat Input and Ambient Temperature (5 RT 공랭형 $NH_3-H_2O$ 흡수식 냉동기의 발생기 입력 열량과 외기온도 변화에 따른 성능분석)

  • 윤희정;김성수;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.5
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    • pp.438-443
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    • 2004
  • The objective of this paper is to study the effects of the input gas flow rate and the ambient temperature variation on the absorption cycle performance. An air-cooled NH$_3$-$H_2O$ absorption chiller is tested in the present study. The nominal cooling capacity of the single effect maching is 17.6 ㎾ (5.0 USRT). The cooling capacity, coefficient of performance, burner efficiency, and each state point are measured with the variations of the heat input and the ambient temperature. It is found that the COP and cooling capacity increase with increasing the generator exit temperature up to a certain temperature and then decrease. It is also found that the COP and the cooling capacity decrease with increasing the ambient temperature. The maximum COP of 0.51 is obtained from the present experiment.