• 제목/요약/키워드: H2 absorption

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Evaluation of electrical energy consumption in UV/H2O2 advanced oxidation process for simultaneous removal of NO and SO2

  • Shahrestani, Masoumeh Moheb;Rahimi, Amir
    • Environmental Engineering Research
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    • 제24권3호
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    • pp.389-396
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    • 2019
  • The electrical energy consumption (EEC) in removal of NO by a $UV/H_2O_2$ oxidation process was introduced and related to removal efficiency of this gas. The absorption-reaction of NO was conducted in a bubble column reactor in the presence of $SO_2$. The variation in NO removal efficiency was investigated for various process parameters including NO and $SO_2$ inlet concentrations, initial concentration of $H_2O_2$ solution and gas flow rate. EEC values were obtained in these different conditions. The removal efficiency was increased from about 22% to 54.7% when $H_2O_2$ concentration increased from 0.1 to 1.5 M, while EEC decreased by about 70%. However, further increase in $H_2O_2$ concentration, from 1.5 to 2, had no significant effect on NO absorption and EEC. An increase in NO inlet concentration, from 200 to 500 ppm, decreased its removal efficiency by about 10%. However, EEC increased from $2.9{\times}10^{-2}$ to $3.9{\times}10^{-2}kWh/m^3$. Results also revealed that the presence of $SO_2$ had negative effect on NO removal percentage and EEC values. Some experiments were conducted to investigate the effect of $H_2O_2$ solution pH. The changing of pH of oxidation-absorption medium in the ranges between 3 to 10, had positive and negative effects on removal efficiency depending on pH value.

테라헤르츠 분광학을 이용한 중수(D2O)와 경수(H2O) 혼합물의 특성연구 (Terahertz Characteristics of D2O and H2O Mixtures)

  • 정중건;손주혁
    • 한국광학회지
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    • 제19권6호
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    • pp.435-438
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    • 2008
  • 중수($D_2O$, 산화중수소)는 수소원자(H)보다 중성자 한 개가 더 많은 수소원자 동위원소(D)로 이루어진 물이다. 중수는 자연 상태의 물 가운데 5만분의 1정도 존재하며 경수($H_2O$)와 매우 비슷한 성질을 가지고 있으나 경수보다 11%정도 무겁고, 특이점은 235 K로 228 K인 경수와 약간의 차이를 가진다. 중수는 중성자를 흡수하여 원자로의 중성자 감속재로 쓰이고 최근 중수 농도에 따라 세포에 미치는 독성효과가 다르게 나타나는 현상이 발견 되어 암 치료에 사용하려는 연구가 진행되고 있다. 우리는 테라헤르츠 시간축 분광학을 이용하여 경수와 중수 혼합물의 농도별 굴절률과 흡수율 변화를 거대 분자간 결합에너지 영역을 포함하는 테라헤르츠 영역 ($0{\sim}2.5\;THz$)에서 측정하여 중수의 비율이 높을수록 굴절률은 감소하고 흡수율 또한 감소하는 결과를 얻었다.

수평원관상의 LiBr-수용액에 수증기가 흡수될때의 열 및 물질전달 (Coupled Heat and Mass Transfer during the Absorption of Water Vapor into LiBr-H2O Liquid Solution Flowing down the Outside of the Horizontal Cylinder)

  • 이관수;서석청;김영인;박동규
    • 대한설비공학회지:설비저널
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    • 제17권2호
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    • pp.140-149
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    • 1988
  • The problem of heat and mass transfer accompanying the absorption of water vapor into LiBr-$H_2O$ liquid solution flowing over the outside of the horizontal cylinder was theoretically studied to understand the absorption process occuring in the absorber of the absorption heat pump. Numerical results are presented for various quantities of interest relating to temperature, concentration, heat flux and mass flux. Also, the effects of mass flowrate, initial average velocity, and the radius of the cylinder were investigated.

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2 중효용 흡수식 히트점프의 난방 성능 해석 (Thermodynamic Analysis of an Absorption Heat Pump Heating System with LiBr-Water Solution)

  • 원승호;이원용;정헌생
    • 태양에너지
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    • 제9권3호
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    • pp.73-80
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    • 1989
  • This paper presents as assessment based on steady-state thermodynamic analysis and computer modeling of a double effect generation absorption heating cycle for solar air-conditioning to find operating temperature ranges. The influences of component temperatures on the heating coefficients of performance and mass flow ratio have been investigated to obtain optimum operating conditions for the proposed air conditioning system. And the single and double effect absorption cycles are compared with each other over the same range of temperatures.

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H2O2 산화제를 이용한 δ-FeOOH의 합성과 입자 크기 제어 (Synthesis and Particle Size Control of δ-FeOOH Using H2O2 Oxidizing Agent)

  • 신성민;김경환;홍정수
    • 한국전기전자재료학회논문지
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    • 제37권3호
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    • pp.292-296
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    • 2024
  • In this study, Iron (III) oxide-hydroxide (δ-FeOOH) was successfully synthesized using hydrogen peroxide (H2O2) as an oxidizing agent. The synthesis of δ-FeOOH was carried out by controlling the amount of H2O2, and pure δ-FeOOH was successfully synthesized in ranges from 0.2 mL to 0.6 mL of H2O2. The size of the synthesized δ-FeOOH particles was compared by controlling the amount of oxidant H2O2. The average particle size of the synthesized pure δ-FeOOH particles increased from 875.1 nm to 897.2 nm as the amount of H2O2 was increased. The optical properties of δ-FeOOH synthesized under these specific conditions were investigated. All δ-FeOOH showed a similar trend of increasing and decreasing light absorption from 800 nm to 400 nm, although there was a slight difference in the amount of light absorption, with the largest amount of light absorption at 410 nm. The band gap energy of δ-FeOOH through the Tauc plot method was about 2.1~2.2 eV when H2O2 was 0.2~1.4mL. With a sufficient small particle size, simple control of that particle size, and a small band gap energy enough to absorb light in the visible spectrum, δ-FeOOH could be useful in a variety of applications, including photoelectrochemistry and battery electrodes.

Graphite Furnace Atomic Absorption Spectrophotometric Determination of Trace Horseradish Peroxidase Using Nanosilver

  • Jiang, Zhi-Liang;Tang, Ya-Fang;Wei, Lin;Liang, Ai-Hui
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2732-2736
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    • 2011
  • In pH 4.2 HAc-NaAc buffer solution, horseradish peroxidase (HRP) catalyzed $H_2O_2$ oxidation of nanosilver to form $Ag^+$. After centrifugation, $Ag^+$ in the supernatant can be measured by graphite furnace atomic absorption spectrophotometry (GFAAS) at the silver absorption wavelength of 328.1 nm. When HRP concentration increased, the $Ag^+$ concentration in the supernatant increased, and the absorption value enhanced. The HRP concentration in the range of 0.84-50 $ng{\cdot}mL^{-1}$ was linear to the enhanced absorption value (${\Delta}A$), with a regression equation of ${\Delta}A$=0.012C+0.11, correlation coefficient of 0.9988, and detection limit of 0.41 $ng{\cdot}mL^{-1}$ HRP. The proposed GFAAS method was used to detect HRP in waste water samples, with satisfactory results.

Chinese Medicine Granule Affects the Absorption and Transport of Glucose in Porcine Small Intestinal Brush Border Membrane Vesicles under Heat Stress

  • Song, Xiaozhen;Xu, Jianqin;Wang, Tian;Liu, Fenghua
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권2호
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    • pp.246-253
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    • 2009
  • This study was conducted to investigate the effects of Chinese medicine granule (CMG, including Cortex Phellodendron, Atractylodes Rhizome, Agastache Rugosa and Gypsum Fibrosum) on absorption and transport of glucose in porcine small intestinal brush border membrane vesicles (BBMVs) under heat stress. Forty-eight 2-month-old Chinese experimental barrows were screened according to weight and litter origin, and then allotted to three groups and treated as follows: Normal temperature control group (NTCG; $23^{\circ}C$), high temperature control group (HTCG; $26^{\circ}C$ for 19 h, $40^{\circ}C$ for 5 h); Chinese medicine granule anti-stress group (CMGG; $26^{\circ}C$ for 19 h, $40^{\circ}C$ for 5 h) (n = 16 per group). The results showed that high temperature treatment decreased (p<0.05) the growth performance and intestinal glucose absorption but there was no change (p>0.05) in the expression of SGLT1 and GLUT2 genes in the small intestine of pigs compared with the NTCG. Dietary supplementation with CMG improved the growth performance, and increased the activity of disaccharidases in duodenum and jejunum of heat stressed pigs (p<0.05). CMG treatment increased (p<0.05) the protein levels of SGLT1 and GLUT2 in the small intestine, and up-regulated (p<0.05) the expression of SGLT1 and GLUT2 genes in the duodenum and jejunum but without changing (p>0.05) them in the ileum compared with the HTCG. These results indicated that CMG treatment significantly improved porcine growth performance, and increased intestinal glucose absorption and transport by BBMVs under heat stress, in addition to up-regulating the expression of SGLT1 and GLUT2 genes in porcine duodenum and jejunum.

충전탑에서 흡수에 따른 물질전달과 수력학적 거동에 관한 연구 (A Study on Hydraulic Behavior and Mass Transfer by Absorption in Packing Tower)

  • 김석택
    • 한국환경과학회지
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    • 제9권5호
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    • pp.393-396
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    • 2000
  • Packing tower has been used in the chemical industry and the protection of environment for a long time. In the view of environmental protection purification of exhaust gas can be performance effective by gas absorption in counter-current packing tower. In this study characteristics of hydraulic and mass transfer were investigated in D. $0.3m {\times} H. 1.4m$ packing tower with 50mn plastic Hiflow-ring. This study was carried out "Test systems were experimented in conditions of Air, $Air/H_2O. NH_3-Air/H_2O, NH_3-Air/H_2O-H_2SO_4$ and $SO_2-Air/H_2O-NaOH$ under steady state" The extent of test included dry and wetting pressure drop physical law separation efficiency and hold-up as function of gas and liquid load.quid load.

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Simulation of $H_2O/LiBr$ Triple Effect Absorption Systems with a Modified Reverse Flow

  • Jo, Young-Kyong;Kim, Jin-Kyeong;Kang, Yang-Tae
    • International Journal of Air-Conditioning and Refrigeration
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    • 제15권3호
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    • pp.114-121
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    • 2007
  • In this study, a modified reverse flow type, one of the triple effect absorption cycles, is studied for performance improvement. The cycle simulation is carried out by using EES(Engineering Equation Solver) program for the working fluid of $H_2O/LiBr$ solution. The split-ratios of solution flow rate, UA of each component, pumping mass flow rate of solution are considered as key parameters. The results show that the optimal SRH (split ratio of high side) and SRL (split ratio of low side) values are 0.596 and 0.521, respectively. Under these conditions, the COP is maximized to 2.1. The optimal pumping mass flow rate is selected as 3 kg/s and the corresponding UAEV A is 121 kW/K in the present system. The present simulation results are compared to the other literature results from Kaita's (2002) and Cho's (1998) triple effect absorption systems. The present system has a lower solution temperature and a higher COP than the Kaita's modified reverse flow, and it also gives a higher COP than the Cho's parallel flow by adjusting split ratios.

Thermal and Absorbing Performance in a Vertical Absorber

  • Cho, Keum-Nam;Kim, Jung-Kuk
    • International Journal of Air-Conditioning and Refrigeration
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    • 제8권2호
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    • pp.51-59
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    • 2000
  • The purpose of the present study is to investigate the absorbing characteristics in a vertical falling film type absorber using LiBr-H$H_2O$ solution as working fluids with the concentration of 60 wt%. The experimental apparatus consists of an absorber with the diameter of 17.2 mm and the length of 1150 mm, a generator, an evaporator (condenser), a weak solution tank and a sampling trap device and so on. The parameters were the solution temperatures of 45 and 50$^{\circ}$C, coolant temperatures of 30 and 35$^{\circ}$C, and the film Reynolds numbers from 50 to 150. The pressure drop in the absorber increased as the solution and coolant temperatures decreased. The pressure drop in the absorber increased up to the film Reynolds number of 90, however, decreased at the film Reynolds number above 90. The maximum absorption mass flux was observed at the film Reynolds number of 90. Absorption mass fluxes increased as the coolant temperature decreased. Accordingly, absorption mass fluxes and heat transfer coefficients under the subcooled condition increased more than those under the superheated condition. It is claimed that heat transfer coefficients are deeply affected by the solution temperature more than the coolant temperature within the experimental range.

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