• Bulletin of the Korean Chemical Society
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• 제25권7호
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• pp.977-982
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• 2004

The reaction of $cis-[Cr([14]-decane)(OH_2)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = benzoate(bz) or chlorobenzoate(cbz)} leads to a new compound $[Cr([14]-decane)(bz)_2]ClO_4$ or $[Cr([14]-decane)(cbz)_2]ClO_4$. These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. The crystal structure of $[Cr([14]-decane)(cbz)_2]^+$ was determined. The complex shows a distorted octahedral coordination environment with the macrocycle adopting a folded cis-V conformation. The angle $N_{axial}-Cr-N_{axial}$ deviates by $14.5^{\circ}$ from the ideal value of $180^{\circ}$for a perfect octahedron. The bond angle cis-O-Cr-O between the Cr(III) ion and the two carboxylate oxygen atoms of the monodentate p-chlorobenzoate ligands is close to 90$^{\circ}$. The FAB mass spectra of the $cis-[Cr([14]-decane)(La)_2]ClO_4$ display peaks due to the molecular ions $[Cr([14]-decane)(bz)_2-H]^\;,\;[Cr([14]-decane)(cbz)_2-2H]^$ at m/z 578, 646, respectively.

• 한국광학회지
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• 제13권1호
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• pp.65-69
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• 2002

불소원자(F)와 D$_2$ 기체 발열반응에 의해 레이저 이득매질인 DF 여기분자를 생성시키는 구조의 연속발진형 불화중수소 (DF)화학 레이저를 설계, 제작하고 발진 실험을 수행하였다. 불소원자는 F$_2$ 기체와 H$_2$ 기체를 연소시켜 생성시키고, 불소원자를 초음속 노즐을 통과시킨 직후에 D$_2$ 기체를 분사하여 형성된 DF 여기분자 초음속 흐름을 활성 매질로 사용하여 레이저를 발진시켰다. 본 연구에서 얻은 레이저 발진 출력은 101W이며, 최적의 유량조건에서 얻은 화학 효율은 5.12%, 비출력은 96.5 J/g이다.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2001년도 추계학술대회 논문집
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• pp.292-300
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• 2001

The paper describes spectroscopic characteristics of plasma induces in the pulsed YAG laser welding of alloys containing a large amount of volatile elements. The authors have conducted the spectroscopic analyses of laser induced Al-Mg alloys plasma in the air and argon atmosphere. In the air environment, the identified spectra were atomic lines of Al, Mg, Cr, Mn, Cu, Fe and Zn, and singly ionized Mg lines, as well as the intense molecular spectra of A10 and Mg0 formed by chemical reactions of evaporated Al and Mg atoms from the pool surface with oxygen in the air. In argon atmosphere, Mg0 and AI0 spectra vanished, but AIH spectrum was detected. The hydrogen source was presumably hydrogen dissolved in the base metals, water absorbed on the surface oxide layer, or $H_2$ and $H_2O$ in the shielding gas. The resonant 1ines of Al and Mg were strongly self-absorbed, in particular, self-absorption of the Mg 1ine was predominant. These results show that the laser induced plasma was made of metal1ic vapor with relatively low temperature and high density.

• 한국세라믹학회지
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• 제19권2호
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• pp.127-132
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• 1982

This experiment has been carried out for the purpose of investigating the effect of additives on densification and grain growth in magnesium oxide by a two-step process; hot pressing and heat treating. MgO powder has been obtained by calcining extra reagent grade MgCO3 at 90$0^{\circ}C$ for 30 minutes, and additives have been added to $MgCO_3$ in the form of soluble salts-Al$(NO_3)_3$$. $9H_2O$ and $Cr(NO_3)_3$.9H_2O$. The hot pressing has been carried out with changes of soaking time at 125$0^{\circ}C$ under the pressure of 250kg/$\textrm{cm}^2$, and the heat treating also at same temperature. The initial particle size of MgO measured by particle size analyzer was 0.86 microns. Densification rate obeyed the equation D=K lnt + C, and grain growth rate obeyed the equation G-G0=kt1/2. It was vaporization of some $Cr_2O_3$ and formation of solid solution that had an influence on desification of MgO containing $Cr_2O_3$. Activation energy for grain growth of pure MgO was 62.4 kcal/mole, therefore grain growth was supposed to be diffusioncontrolled process. But after heat treatmeat, excess additives were expected to slow down the grain growth by the formation of second phase or the solute atoms at grainboundary.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 2011년도 한국우주과학회보 제20권1호
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• pp.27.3-27.3
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• 2011

The plasmasphere is filled with the ions and electron transported mostly from the mid-latitude ionosphere. In the topside ionosphere where the $O^+$ ions are still major ions, the $O^+$ ions are in chemical equilibrium with the $H^+$ ions and exchange their charges with each other's parent atoms with similar rates in both reactions. During the day, the newly produced $H^+$ ions flow upward to fill the plasmasphere while they flow downward and contribute to the maintenance of the ionospheric density at night under the geomagnetically quiet condition. The ionosphere and plasmasphere are coupled by these plasma fluxes and therefore strongly affect each other. In order to study these coupling we utilized the plasma density measurements from JASON satellite. This satellite measures vertical total electron content (TEC) from the ground to the satellite orbit (about 1336 km) and slant TEC from the satellite orbit to much higher GPS satellites by using the on-board dual-frequency altimeter and GPS receiver, respectively. The former measurement can represent the ionospheric TEC while the latter can represent the plasmaspheric TEC in the equatorial region. We compared these data with different seasons, solar activities and local times, and the results will be presented.

• 한국환경과학회지
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• 제3권1호
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• pp.57-64
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• 1994

On the basis of the principle of Bratch's electronegativity equalization, we calculated group partial charges and group electronegativities for nonionic surfactants with Pauling's elecoonegativity parameters by using numerical calculation method. From calculated outputs we have investigated structural stability of micelle, characteristics of hydrophilic and hydrophobic groups, and relation between CMC(Critical Micelle Concentraion) and group partial charge and group electronegativity of hydrophilic and hydrophobic groups for nonionic surfactants. We have known that CMC by micelle formation depends upon group partial charge and group electronegativity of hydrophilic and hydrophobic groups for surfactants. Also, the structural stability of micelle in H2O solution is related to the electric double layer by the hydrophilic group of nonionic surfactants with H atoms in water CMC is diminished by the decrease of repeating units in hydrophilic group at constant hydrophobic group and is diminished by the increments of alkyl chains in hydrophobic group at constant hydrophilic group for nonionic surfactants. In conclusion, CMC is diminished because there is no electrostatic repulsion and is diminished of Debye length by the increments of partial charge of hydrophobic group.

• 한국안광학회지
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• 제8권2호
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• pp.31-35
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• 2003

몇 가지 합성한 poly(6-dialkylamino-1,3,5-triazine-2,4-dithioxylene) 유도체들은 poly(6-dialkylamino-1,3,5-triazine-2,4-dithiol과 m- 또는 p-dibromide xylene으로부터 $70^{\circ}C$에서 약 24시간 동안 cetyltrimethyl ammo-nium bromide와 중축합반응 시켜서 얻었다. 합성해서 얻은 유도체들의 굴절률이 97~196.6을 보였으며, 물흡광계수는 97~196.6범위에서 나타났다. 따라서 이들 고분자 유도체들이 높은 전자밀도를 가지는 황 원자와 트리아진 고리를 가지므로 인해 복굴절 현상이 없으면서 높은 굴절률을 가진다는 것을 알았다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권2호
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• pp.69-75
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• 1999

The characteristics of $H_2$ gas detection have been investigated using the Pt-MIS capacitor composed of the LPCVD nitride on the oxide. The flat band voltage shift is measured as 0.1 V in 1,000 ppm $H_2$ gas ambient and to be independent of Pt catalyst thickness. It is found that the flatband voltage shift is proportional to the hydrogen concentrations. The response and recovery time of Pt-MIS capacitor are 5 mins and 25 mins respectively. The samples of 30nm thick Pt revealed much higher sensitivity than that of 150nm samples. The samples of 150nm Pt showed that the flatband voltage shift of the device is due to the formation of the dipole layer of the adsorbed hydrogen atoms at the Pt-insulator interface.

• 약학회지
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• 제54권4호
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• pp.300-308
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• 2010

Adrenoceptor has been considered to be an important target in psychiatric disorders. Based on x-ray structures of bovine rhodopsin, we established homology model of ${\alpha}_{2c}$-adrenoceptor (ADA2C_rat) and then analyzed docking from binding model of receptor-ligand complex with high-active compound No.29 in tricyclic isoxazole analogues (1-30). We observed that the N (1.907 $\AA$) and O (1.712 $\AA$) atoms of isoxazole ring on the docked ligand (No.29) formed H-bonding interaction with O-H of Ser5.32 and carmeron phenyl ring centroid of tricyclic isoxazole formed $\pi-\pi$ interaction at 3.342 $\AA$ distance with phenyl ring centroid of Phe6.52. According to predictions of blood-brain distribution (logBB) through penetration of blood-brain barrie (BBB) and polar surface area (PSA) of the ligands, the high-active compound No.29 has values of logBB=-0.203, PSA=67.50, respectively. These results suggest that the high-active compound No.29 is a novel anti-depressant with the characteristics such as dopamine and serotonin.

• Applied Biological Chemistry
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• 제19권1호
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• pp.51-56
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• 1976

$SO_2$ 수용액의 화학적 변화를 in vitro system에서 조사하였다. 농도가 다른 수용액이 20시간 후에 비슷한 Eh값에 도달하였으며 산성용액에서는 Eh값이 그 이상 증가하지 않았다. Eh값은 알카리성용액에서 보다는 중성용액에서 크게 증가하였고 암흑에서 보다는 광조건하에서 다소 높은 경향을 나타냈다. 유리상태의 $SO_2$함량은 아황산염의 농도가 증가하거나, 광에 노출한 경우, 또는 pH가 높은 때에 크게 감소하였다. 발생기수소는 고농도의 $SO_2$나 산성용액에서 보다는 중성 혹은 알카리성 용액에서 더욱 많이 생성되었다.