• Proceedings of the Korea Concrete Institute Conference
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• 1993.04a
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• pp.93-98
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• 1993

In order to discuss the mechanical properties of fiber reinforced composites with fly ash, lime, gypsum and polymer emulsion-Stylene Butadiene Rubber Latex (SBR) , experimental studies on FRC were carried out. The kinds of fiber used in FRC are PAN-dervied and Pitch-derived carbon fiver, alkali-resistance glass fiber. As a test results, the flexural strength and tougthness of fiber reinforced fly ash. lime.gypsum cement composites are remarkably increased by fiber contents ,but compressive strength of the composites are influenced by kinds of fiber more than by fiber contents. Also, addition of a polymer emulsion (SBR) to the composites decreased the bulk specific gravity, but compressive and flexural strengths, toughness of the composites are not influenced by it, are considerably improved by increasing fiber contents.

• Journal of the Korean Geosynthetics Society
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• v.17 no.2
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• pp.19-31
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• 2018

Recently the ground subsidence which seriously weakens the safety of cities tends to increase. The purpose of this paper is to develop the materials by using industrial by-products for the application to emergency restoration process in case of ground subsidence. In this paper the laboratory tests including pH test, initial setting test, unconfined compressive strength test, and flow test were performed in order to evaluate the design properties of Controlled Low Strength Material (CLSM). The field test was carried out for evaluating the performance for the early strength of CLSM and the workability for emergency restoration. Test results showed that the strength will be too high to re-excavate the ground when the cement ratio is more than 4%. The optimum mixing ratio appears to be most effective when the mixing ratio of the bottom ash and the gypsum is approximately 50:50 and the cement content is 2%.

• Journal of the Korea Concrete Institute
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• v.21 no.1
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• pp.21-27
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• 2009

In this study, experimental findings on the resistance to magnesium sulfate attack of portland cement mortar and paste specimens incorporating metakaolin (MK) are presented. Specimens with four replacement levels of metakaolin (0, 5, 10 and 15% of cement by mass) were exposed to solutions with concentrations of 0.424% and 4.24% as $MgSO_4$ at ambient temperature. The resistance of mortar specimens was evaluated through visual examination and linear expansion measurements. Additionally, in order to identify the products formed by magnesium sulfate attack, microstructural analyses such as XRD, DSC and SEM/EDS were also performed on the paste samples incorporating metakaolin. Results confirmed that mortar specimens with a high replacement level of metakaolin exhibited lower resistance to a higher concentration of magnesium sulfate solution. It was found that the negative effect of metakaolin on the magnesium sulfate attack is partially attributed to the formation of gypsum and thaumasite. Conclusively, it is necessary to pay a special attention when using metakaolin in concrete structures, particularly under highly concentrated magnesium sulfate environment.

• Journal of the Korea Institute of Building Construction
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• v.15 no.2
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• pp.193-199
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• 2015

As a solution of both environmental issue of reducing carbon dioxide emission and sustainable issue of exhausting natural resources, in concrete industry, many research on recycling various by-products or industrial wastes as the concrete materials has been conducted. The aim of this research is feasibility analysis of additional reaction with ordinary Portland cement and flue gas desulfurization gypsum based on the blast furnace slag and recycled fine aggregate based mortar to achieve the normal strength range. Consequently, in the case of mortar replaced 10% FGD and 30% OPC for BS, 80% of plain OPC mortar's compressive strength was achieved. Furthermore, when the water-to-binder ratio is decreased to keep the practically similar level of flow, it is expected to be achieve the equivalent compressive strength to plain OPC mortar.

• Journal of the Korean Wood Science and Technology
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• v.42 no.5
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• pp.615-623
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• 2014

Increases of public attention on healthy environment lead to the regulation of indoor air quality such as Clean Healthy House Construction Standard. This standard covers emission of total volatile organic compounds (TVOCs) (e.g., formaldehyde, benzene, and toluene), ventilation, and use of environmentally-friendly products or functional products. Moisture absorption and desorption abilities are a recommended functionality for improving indoor air quality. In this study, moisture absorption and desorption capacities of carbonized board from wood-based panels and other materials were determined by using UNT-HEAT-01 according to ISO 24358:2008. Pine had higher moisture absorption and desorption capacities ($49.0g/m^2$ and $35.3g/m^2$, respectively) than hinoki cypress, cement board, gypsum board, oriented strand board, and medium density fiberboard (MDF). The moisture absorption and desorption capacities differed considerably according to the wood species. After carbonization process at $400^{\circ}C$, the absorption and desorption ability of MDF increased to 38% and 60%, respectively. However, moisture absorption and desorption capacities decreased with increasing carbonization temperature, but they were still higher than original MDF. Therefore, it is suggested that carbonization below $600^{\circ}C$ can improve moisture absorption/desorption capacities.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.34 no.2
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• pp.66-72
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• 2024

In this study, the applicability of CCMs (Carbondioxide conversion capture materials) manufactured by reacting carbon dioxide gas with DG (Desulfurization gypsum) as a cement substitute for secondary concrete products were evaluated and the basic physical properties of CCMs-mixed mortar and concrete specimens were measured to derive the optimal mixing ratio. The main chemical oxides of CCMs were CaO and SO₃, and the main crystalline phases were CaSO₄·2H₂O, Ca(OH)₂, CaCO₃, and CaSO₄. In addition, by the results of particle size analysis and heavy metal measurement, the applicability of CCMs as a cement substitute for secondary concrete products was confirmed. As a result of measuring the strength behavior using mortar and concrete specimens with CCMs, the compressive and flexural strength decreased as the mix ratio of CCMs increased, but requirements by the standards for interlocking blocks and retaining wall blocks, which are target products in this study, were satisfied up to the optimal mixing ratio of 10 wt.% substitution. Therefore, its applicability as a cement substitute for secondary concrete products was confirmed.

• Journal of the Korean Ceramic Society
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• v.34 no.8
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• pp.861-869
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• 1997

In order to investigate the reaction in the system of anhydrite II-blast furnace slag, the paste hydration which made up with a liquid/solid ratio of 0.45 for 1, 3, 7, 14, 28days by the addition of accelerators to 10~30wt.% slag with natural gypsum calcined for 1hour at 500/$700^{\circ}C$ was studied by combined water determination, XRD, DTA, DSC and SEM. As a result of this experiment, it was found that hydration rate was faster in the system calcined at 50$0^{\circ}C$. Therefore the anhydrite was converted to calcium sulfate dihydrate in the hydration for 1day but the slag was not almost reacted. For the gypsum calcined at $700^{\circ}C$, the hydraton rate in the system of K2SO4 addition was faster than others in the earier period, but the activated effect of the system of Al2(SO4)3 addition was regarded as the highest over 3days. As the amount of slag was increased, they dydration rate was delayed and ettringite was observed in the case of K2SO4 system. However both Al2(SO4)3 and AlK(SO4)2 systems showed calcium sulfate dhydrate only as hydrated products.

• Advances in concrete construction
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• v.4 no.4
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• pp.231-242
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• 2016

The major problem of a coal combustion-based power plant is that it creates large quantity of solid wastes. So, to achieve the gainful use of waste materials and to avoid other environmental problems, this study was undertaken. The quantity of coal ash by-products, particularly coal fly ash and coal bottom ash has been increasing from the coal power plants around the world. The other objective of this study was to explore the possibility of utilization of coal ash in the production of ash bricks. In 15 different mixes, Mix Designation M-1 to M-15, the varying percentages of lime and gypsum were used and sand was replaced with coal bottom ash. Further, it has been noticed that the water absorption and compressive strength of mix M-15 is 13.36% and 7.85 MPa which is better than the conventional bricks. The test results of this investigation show that the prism strength of coal ash masonry prisms was more than that of the conventional bricks.

• Journal of the Korean Geotechnical Society
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• v.22 no.4
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• pp.31-39
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• 2006

An experimental investigation was carried out to evaluate the strength characteristics of low cement ratio soil stabilizer. The low cement ratio soil stabilizer has been developed by the replacement of certain part of cement with by-product pozzolanic materials such as blast furnace slag, fly ash, waste gypsum and by using activator. A series of unconfined compressive strength tests were performed to investigate and obtain high-strength composite soil stabilizer with large amounts of blast furnace slag and fly ash. Test results show that there were better properties when blast furnace slag, fly ash, waste gypsum, and activator were added in proper ratio. The replacement of certain part of cement with by-product pozzolanic materials improved the strength and pore structure properties.

• Clean Technology
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• v.30 no.2
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• pp.113-122
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• 2024

In order to better understand carbon dioxide recycling, the carbon dioxide capture characteristics of six different alkaline industrial by-products, including incineration ash, desulfurized gypsum, low-grade quicklime, and steelmaking slag were investigated using a laboratory-scale direct aqueous carbonation reactor. In addition to the dissolution characteristics of each sample, the main reaction structure was confirmed through thermogravimetric analysis before and after the reaction, and the reactive CaO content was also defined through thermogravimetric analysis. The carbon dioxide capture capacity and efficiency of quicklime were determined to be 473 g/kg and 86.9%, respectively, and desulfurized gypsum and incineration ash were also evaluated to be relatively high at 51.1 to 131.7 g/kg and 51.2 to 87.7%, respectively. On the other hand, the capture efficiency of steelmaking slag was found to be less than 10% due to the influence of the production and post-cooling conditions. Therefore, in order to apply the carbonation process to steelmaking slag, it is necessary to optimize the slag production conditions. Through this study, it was confirmed that the carbon dioxide capture characteristics of incineration ash, quicklime, and desulfurized gypsum are at levels suitable for carbonation processes. Furthermore, this study was able to secure basic data for resource development technology that utilize carbon dioxide conversion to produce calcium carbonate for construction materials.