• Journal of the Korean Ceramic Society
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• v.21 no.4
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• pp.355-360
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• 1984

The effect of 2% of $P_2O_5$ substituted in gypsum(5 mol% as $HPO_3$) on the early hydration characteristics of $C_3A$ were investigated and then gypsum only and gypsum mixed with $Ca(H_2PO_4)_2$.$H_2O$(2% as $P_2O_5$) were studied separately for comparison. The early hydration reaction of $C_3A$ with each gypsum were examined by measuring the rate of heat libera-tion of hydration with calorimeter and by analysing the hydration products with X-ray diffractometer and differential thermal analyser. It was shown that phosphogypsum substituted with $P_2O_6$ in the crystal lattice accelerated exceedingly the formation of the ettrignite and following hydrated products. However the other gypsum especially gypsum without any phosphate delayed the formation of various hydration products, It was consequently suggested that when phosphogypsum are used as the retarder of cement setting its reta-rding effect for setting of cement is not ascribed to the retardation of ettringite formation.

• Korean Journal of Materials Research
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• v.25 no.11
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• pp.590-597
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• 2015

In this article, poly methyl triethoxy silane was compounded with an inorganic waterproof admixture at a certain ratio to improve the performance of gypsum products; a new type of high-efficiency compound water-proofing additive was also investigated. Furthermore, the waterproof mechanism and the various properties on the hardened gypsum plaster were investigated in detail by XRD and SEM. The results show that the intenerate coefficient of gypsum plaster increased to more than 0.9; the water absorbing rate decreased to less than 10 %. Both the bending strength and the compressive strength of gypsum plaster increased by various degrees. The intenerate coefficient reached a maximum value of 0.73 and the strength of the samples showed almost no change when 5% cement alone was added. In this new type of the high-efficiency compound with waterproof additive, the optimal technological parameters for formulas were obtained to be: 5% cement, 18 % mineral powder, and 0.8% poly methyl triethoxy silane, to compound gypsum plaster. Meanwhile, the production of high performance gypsum as a building material has become possible.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.05a
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• pp.222-223
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• 2014

In this study, industrial by-products including blast furnace slag, incineration ash and waste gypsum were used with recycled fine aggregates to manufacture the zero-cement mortar.The replacement ratio of dihydrate gypsum and anhydrite gypsum was fixed as 0 and 10%, the replacement ratio fo WA1 was fixed as 0.5% and 1.0%, respectively. It could be identified that when the replacement of gypsum was 10% and WA1 of 1.0%, the strength could be in the range of normal strength.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.15 no.6
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• pp.127-133
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• 2006

Rapid prototyping technologies have been widely used to reduce the development cost of new products. Manufacturing industries are nowadays characterized by the flexibility and complexity of products. This to due to the rapid development of manufacturing technology and diverse needs of customers. In this paper, the best homing out and casting condition for getting casting product of resin pattern(photopolymer) have been examined experimentally. In generally, the burning out and casting conditions have effect on the casting products. Using the direct casting. we directly Producted the Jewelry. And in this paper, we used only gypsum. Many study of casting for resin have been used to dental investment. A dental investment is good for resin casting. but dental investment is too hard and not useful on the jewelry casting. Therefore we need to find the way of resin casting by gypsum.

• Journal of Technologic Dentistry
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• v.42 no.4
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• pp.321-325
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• 2020

Purpose: This study is to evaluate the accuracy of gypsum replica models made from various gypsum products. Methods: One main model was made of stainless steel by CNC milling process. Molds were formed from the main model, and the gypsum replica models were made using 8 types of type IV gypsum, 10 pieces each. The main model was digitized by a contact scanner (Incise; Renishaw) and the gypsum replicas were digitized by an optical scanner (E4; 3Shape A/S). The difference between the main model and the gypsum replicas were measured by inspection software (3D Systems). One-way ANOVA was performed to evaluate the statistical significance of differences between groups. In addition, the independent sample T test was performed to determine the difference between the conventional and scannable stone group (n=10, α=0.05). Results: The root mean square of the stone models were 7.24 ㎛ to 10.78 ㎛, and statistical significance was found between the two groups (SR, FR) and the other 6 groups (IS, SG, CA, CS, ER, EBG) (p<0.05). The accuracy of the gypsum replicas was 9.04 ㎛ and 7.62 ㎛ in the conventional and scannable stone group, respectively. There was statistical significance between the two groups (p<0.01). Conclusion: In the limited results of this study, the product with low setting expansion and the scannable showed high accuracy. Therefore, in order to obtain a stable and accurate scan model, it is more effective in terms of accuracy to use a scannable stone with a low setting expansion.

• Journal of the Korean Ceramic Society
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• v.54 no.2
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• pp.128-136
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• 2017

Fly ash from a circulating fluidized bed combustion boiler (CFBC fly ash) is very different in mineralogical composition, chemical composition, and morphology from coal ash from traditional pulverized fuel firing because of many differences in their combustion processes. The main minerals of CFBC fly ash are lime and anhydrous gypsum; however, due to the fuel type, the strength development of CFBC fly ash is affected by minor components of active $SiO_2$ and $Al_2O_3$. The initial hydration product of the circulating fluidized bed combustion fly ash (B CFBC ash) using petro coke as a fuel is Portlandite which becomes gypsum after 7 days. Due to the structural features of the portlandite and gypsum, the self-cementitious strength of B CFBC ash was low. While the hydration products of the circulating fluidized bed combustion fly ash (A CFBC ash) using bituminous coal as a fuel were initially portlandite and ettringite, after 7 days the hydration products were gypsum and C-S-H. Due to the structural features of ettringite and C-S-H, A CFBC ash showed a certain degree of self-cementitious strength.

• Journal of the Korea Furniture Society
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• v.19 no.1
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• pp.83-90
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• 2008

Gypsum-wood composites were made by introducing inorganic substances into wood using calcium chloride, first treating solution, and sodium sulfate, secondary treating solution, by double diffusion process under atmospheric pressure at room temperature. The process conducted as follows: water saturated specimens were soaked in calcium chloride solutions at several concentration. Then the specimens were soaked further in saturated sodium sulfate solution, and they were leached in flowing tap water for 24h. To attain sufficient weight percent gain (WPG) values, the suitable concentration of calcium chloride and soaking time in saturated sodium sulfate solution were 20% and 48h, respectively. Inorganic substances were produced mainly in the lumina of tracheides. It was made sure that these substances were dihydrate gypsum($CaSO_4$ $2H_2O$) by X -ray microanalysis (SEM-EDX). The composites had good fire resistance due to low heat transfer rate of gypsum formed in wood. However, the composites had little decay resistances, because they showed high weight losses by test fungi attacks.

• Journal of Technologic Dentistry
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• v.30 no.1
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• pp.17-23
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• 2008

Gypsum products are used for the preparation of stone casts of oral and maxillofacial structures and as important adjuncts to dental laboratory operations involved in the production of dental prosthesis. Accuracy and dimensional stability over time are properties of concern in fixed prothodontics. Gypsum products used in denstry are a form calcium sulfate hemihydrate and are classified as 1 of 5 types according to International Standard Organization(ISO) 6873. All die materials exhibit some dimensional change during setting, but expansion and contraction during setting and dimensional changes in response to varations in temperature and the water-powder ratio must be minimal. Although numerous investigators have studied the properties of die materials, several products have been introduced recently with manufacturer claims of superior dimensional stalility. The aim of this study was to determine the surface properties using various separating materials of dental gypsum products The results were as follows 1. In the comparison of first and second plaster distances before separation in different separating agent, there was no significant difference except using Trio separating agent. The interface using Trio separating agent forms like to pores. 2. In the comparison of first and second plaster distances after separation in different separating agent, there was significant difference. The interface of plasters using WD-40, Trio and Vaseline was showed some gaps. Each they were measured at average 7.97 $\pm$ 2.07 ${\mu}m$, 63.09 $\pm$ 23.25 ${\mu}m$, 27.59 $\pm$ 4.19 ${\mu}m$. 3. In the comparison of the surface, the surface of control sample(using none seperating agent) showed irregular properties and the surface using Trio and Vaseline become wrinkled. Specially the surface using Vaseline was showed shiny properties. But the surface using MAGIC SEP, Plaster seperating agent, WD-40 showed regular properties.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.4
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• pp.55-63
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• 2020

This study investigates the mechanical properties and reaction products of activated slag pastes depending on gypsum presence and calcium carbonate addition in terms of compressive strength tests and synchrotron X-ray diffraction. The chemicals of CaO and NaOH are used as activators with different two dosages. The reaction of CaO-activated slag without gypsum just accelerated by addition of calcium carbonate at early ages, but no improvement was observed at later ages. On the other hand, the mechanical properties of CaO-activated slag pastes with gypsum were improved with calcium carbonate, enhancing the stability of ettringite. The variation of mechanical properties of NaOH-activated slag pastes was negligible depending on calcium carbonate addition in case of no gypsum. The addition of calcium carbonate into NaOH-activated slag pastes with gypsum deteriorated its mechanical properties due to the ion competition between CO₃^2- ions and SO₃^2- ions, decreasing crystallinity of reaction products.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.05a
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• pp.242-243
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• 2014

In this study, industrial by-products including blast furnace slag, incineration ash and waste gypsum were used with recycled fine aggregates to manufacture the zero-cement mortar. The replacement ratio of anhydrite gypsum was fixed as 0, 10%, 20% the replacement ratio fo WA1 was fixed as 0.5% and 1.0%, respectively. It could be identified that when the replacement of gypsum was 20% and WA1 of 1.0%, the strength could be in the range of normal strength.