• Proceedings of the KIEE Conference
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• 2005.07b
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• pp.1285-1287
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• 2005

고온초전도 선재 중에서 YBCO 박막을 금속테이프에 증착하여 제조되는 coated conductor는 높은 자기장에서도 임계전류밀도의 감소가 크지 않아 고자장용 초전도 자석을 제조하는데 많이 활용될 것으로 기대되고 있다. coated conductor를 고자장용 초전도 자석제작에 활용하기 위해서는 긴 길이의 도체를 제조하는 것과 함께, 도체의 접합기술이 필요하다. 이는 초전도 자석을 영구전류모드로 운전하기 위해서는 도체의 접촉저항이 충분히 적어야 하기 때문이다. 그러나 박막형 coated conductor는 아직 긴 길이의 선재제조기술이 확립되어 있지 않고, 또 박막형 coated conductor의 형태와 사용되는 제조기술이 본질적으로 초전도 접합을 형성시키기에 매우 어려워서 아직 까지 초전도 접합에 대한 연구결과가 발표되지 않고 있으며, 접합 특성을 측정하는 기술도 개발되지 않았다. 본 연구에서는 coated conductor의 접합특성을 측정하기 위한 기본적인 시험방법을 제안하고, 전도성 금속접합재를 이용한 접합시료를 제작하여 그 특성을 평가한 결과를 발표한다.

• Progress in Superconductivity and Cryogenics
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• v.21 no.3
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• pp.27-31
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• 2019

Large grain YBCO bulk superconductors are fabricated by the top-seeded melt growth (TSMG) or top-seeded infiltration growth (TSIG) method. Both growth methods use at least one of $YBa_2Cu_3O_{7-{\delta}}$, $Y_2BaCuO_5$, $BaCuO_3$ pre-reacted precursor powders. However, the synthesis of the pre-reacted powders includes multiple calcination runs which are cost-bearing and time-consuming. In this work, we report the successful growth of single-domain YBCO bulk superconductors directly by using the powder compact that has been pressed from the mixture of $Y_2O_3$, $BaCuO_3$ and CuO powders without any intermediate grinding step. Single-domain YBCO bulk superconductor has been also prepared by using $Y_2O_3$, $BaO_2$ and CuO powders without intermediate grinding step. Investigations on the trapped magnetic field and microstructure of the melt-processed specimen show that the elimination of the repeated processes of calcinations and pulverization has hardly affected on the crystal growth and the magnetic properties of the grown YBCO bulk superconductors. However, it is thought that the presence of residual carbon affects on the size of Y211 particles in melt-processed YBCO bulk superconductor.

• Progress in Superconductivity and Cryogenics
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• v.24 no.3
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• pp.35-40
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• 2022

To fabricate large grain YBCO bulk superconductors by melt process, Sm123 single crystal with a high melting point are mostly used as seeds. However, it also uses Y123 film deposited on MgO single crystal substrate. This study investigated the growth behavior of the Y123 grain during a melt process when single grain YBCO bulk was used as a seed. Single grain Y123 bulk was grown when the seed size was small. When the seed size was relatively large, multiple grains were grown but the grains were still large. Y123 seed crystal was completely decomposed during high temperature anneal at 1040℃ and new Y123 crystals were nucleated during a slow cooling stage below a peritectic temperature. Thereafter, newly formed Y123 crystals from the seed area are thought to grow into the Y1.8 powder compact. The crystallographic orientations of newly nucleated Y123 grains are independent of the crystallographic orientation of Y123 seed. It is thought that the crystallographic orientation of newly nucleated Y123 crystal can be controlled by using Y211-free Y123 single crystal as a seed of homo-seeding melt growth.

• Progress in Superconductivity and Cryogenics
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• v.8 no.3
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• pp.13-17
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• 2006

The effect of the addition of the nano size $Y_2O_3$ powder on the microstructurte and superconducting properties of YBCO thin film deposited on LAO single crystalline substrate by TFA-MOD method was studied. Nano size $Y_2O_3$ powder was added to the stoichiometric precursor solution with a cation ratio of Y : Ba . Cu = 1 : 2 : 3 prepared using TFA as chelating agent. Precursor solutions with and without $Y_2O_3$ addition were coated on $LaAlO_3(100)$ single crystalline substrates by dip coating method. Calcination and conversion heat treatments were performed in controlled atmosphere containing moisture Current carrying capacity(Jc) of YBCO film was enhanced about 50% by $Y_2O_3$ doping and it is thought to be due to the better connectivity of YBCO grains and/or the flux pinning by the $Y_2O_3$ particles embedded in YBCO grains.

• Progress in Superconductivity and Cryogenics
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• v.10 no.1
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• pp.1-5
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• 2008

The effect of $BaCeO_3$ doping on the critical current density of YBCO film by TFA-MOD method was studied. $BaCeO_3$ doping was made by two method; one is direct addition of $BaCeO_3$ nano-sized powder prepared by citrate process followed by grinding with planetary ball mill for 10 hours. Another is addition of Ba-Ce precursor solution prepared with Ba-acetate and Ce acetate dissolved in TFA to the YBCO-TFA precursor solution. The film was made by standard dip coating and heat treatment process with conversion temperature of $790^{\circ}C$ in 1000 ppm oxygen containing moisturized Ar gas atmosphere. The direct addition of $BaCeO_3$ powder resulted in YBCO film with good epitaxial growth and no evidence of second phase formation. The addition through precursor solution resulted in the increase of critical current density upto 30 at% doping and uniform dispersion of $BaCeO_3$ fine inclusion was confirmed by SEM-EDX.

• Progress in Superconductivity and Cryogenics
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• v.9 no.2
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• pp.7-10
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• 2007

Persistent mode HTS pancake coil has been fabricated using a coated conductor by a "wind-and-flip" method. A coated conductor with the length of 1.2 meters was divided at the center along the length. The sliced coated conductor was wound on a pair of bobbins with a diameter of around 4 cm and two pancake coils connected superconductively without a resistive joint were prepared. By flipping one of the pancake coils, the magnetic field generated by each coil is to be aligned to the same direction and generate meaningful magnetic field while the magnetic fields of two spit coils are canceled without flipping. Permanent current was induced by flowing current to the coil immersed in liquid nitrogen pool using a power supply. A magnetic field of 48.8 Gauss was generated when 20 A of current was flowing in the pancake coils. The "Wind and flip" method can be applied for the fabrication of a long solenoid magnet by winding a sliced coated conductor on a cylindrical bobbin. It is also introduced that the construction of multiple sets of pancake (or solenoid) coils is possible by a "wind-and-flip" method using a wide coated conductor.

• Progress in Superconductivity and Cryogenics
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• v.12 no.1
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• pp.1-5
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• 2010

Silver stabilizing layer of coated conductor has been prepared by dip coating method using organic silver complexes containing 10 wt% silver as a starting material. Coated silver complex layer was dried in situ with hot air and converted to crystalline silver by post heat treatment in flowing oxygen atmosphere. A dense continuous silver layer with good surface coverage and proper thickness of 230 nm is obtained by multiple dip coatings and heat treatments. The film heat treated at $500^{\circ}C$ showed good mechanical adhesion and crystallographic property. The interface resistivity between superconducting YBCO layer and silver layer prepared by dip coating was measured as $0.67\;{\times}\;10^{-13}\;{\Omega}m^2$. Additional protecting copper layer with the thickness of $20\;{\mu}m$ was successfully deposited by electroplating. The critical current measured with the specimen prepared by dip coating and sputtering on same quality YBCO layer showed similar value of ~140 A and proved its ability to replace sputtering method for industrial production of coated conductor.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.46 no.8
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• pp.67-78
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• 2009

Radiation characteristics of microstrip patch antennas integrated with mushroom-like EBG structures in all directions and length direction on a substrate with the relative dielectric constant of 10 are systematically analyzed. As the substrate thickness increases, the effect of the surface wave on the input impedance and radiation pattern of a patch antenna increases. The effect of EBG structures on the input impedance of a patch antenna is negligible when the distances between EBG structures and the center of a patch antenna are 0.4 ${\gamma}_0$, 0.2 ${\gamma}_0$ and 0.1 ${\gamma}_0$ for the substrate thickness of 3.2 mm, 1.6 mm and 0.8 mm, respectively. The forward radiation is improved due to the suppression of surface wave when the periods of EBG structures integrated are larger than 2, 2, 3 periods for the substrate thickness of 3.2 mm, 1.6 mm and 0.8 mm, respectively. The effects of EBG structures on the radiation characteristics of a patch antenna integrated with EBG structures in all directions and length direction are similar.

• International Commerce and Information Review
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• v.16 no.4
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• pp.385-408
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• 2014

The purpose of this paper is to find the determinants of Korean FDI(1996~2012) in China using the spatial autoregressive model and four regions of China is analyzed respectively. Most previous studies ignored spatial interdependence to analyze the determinants of Korean outward FDI in China. Empirical results of total Chinese area shows per RGDP and spatial effects are positive and significant variables. Results of region A reveal that per RGDP is positive and spatial effects are negative and significant. Results of region B shows that both per GDP and spatial effects are positive. All variables of region C are insignificant but those of region D are significant and positive. This means that Korean companies to invest in region D should consider spatial characteristics of surrounding areas of D.

• Bulletin of the Korean Chemical Society
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• v.29 no.8
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• pp.1491-1494
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• 2008

A novel platinum aminoalkoxide complex, Pt$(dmamp)_2$ has been prepared by the reaction of cis-$(py)_2PtI_2$ with two equivalents of Na(dmamp) (dmamp = 1-dimethylamino-2-methyl-2-propanolate). Single-crystal X-ray crystallographic analysis shows that the Pt(dmamp)2 complex keeps a square planar geometry with each two nitrogen atoms and two oxygen atoms having trans configuration. Platinum films have been deposited on TaN/ Ta/Si substrates by metal organic chemical vapor deposition (MOCVD) using Pt$(dmamp)_2$. As-deposited platinum thin films did not contain any appreciable amounts of impurities except a little carbon. As the deposition temperature was increased, the films resistivity and deposition rate increased. The electrical resistivity (13.6 $\mu\Omega$cm) of Pt film deposited at 400 ${^{\circ}C}$ is a little higher than the bulk value (10.5 $\mu\Omega$cm) at 293 K. The chemical composition, crystalline structure, and morphology of the deposited films were investigated by X-ray photoelectron spectroscopy, X-ray diffraction, and atomic force microscopy.