• Journal of Korean Society of Environmental Engineers
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• v.36 no.8
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• pp.588-595
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• 2014

Carbon nanomaterials such as fullerene, carbon nanotube and graphene are representative nanomaterials and widely used in various fields. Carbon nanomaterials can be exposed to environments during their production, usage and disposal, spreading to different systems and posing a great threat to various ecological receptors. Researches are conducted in order to determine the possibility of groundwater exposure to carbon nanomaterials due to their release and passage through soils. If soils can play a significant role in limiting the transport of carbon nanomaterials, the possibility of groundwater exposure to carbon nanomaterials can be reduced greatly. This review paper presented the research works performed for the mobility of carbon nanomaterials in soil media. Also, the paper provided the factors affecting the transport of carbon nanomaterials in soil media along with the DLVO theory/colloid filtration theory/transport model, which are used to describe the transport of carbon nanomaterials in soil media. Recently, production of carbon nanomaterials and their commercial and environmental applications increase rapidly in Korea. Therefore, researches regarding the fate and transport of domestic carbon nanomaterials in soil environments should be performed in various environmental conditions.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.2
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• pp.193-201
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• 2000

Partitioning of hydrophobic organic compounds (HOCs) to a biosurfactant, hydroxypropyl-${\beta}$-cyclodextrin (HPCD), was conducted to evaluate the feasibility of using HPCD to remove HOCs from soil/groundwater. HOC partitioning to HPCD was very fast, with over 95% of the complexation occurring within 10 min. Some influence of solution chemistry and HOC concentration on HOC-HPCD complex formation coefficients was observed. HPCD sorption on soil as quantified by both a fluorescence technique and total organic carbon measurements was negligible, indicating no significant affinity of HPCD for the solid phase. Although the HOC solubilization capability of HPCD was lower than that of synthetic surfactants such as SDS and Tween 80, HPCD can be effective in removing sorbed HOCs from a model subsurface environment, primarily because of its negligible sorption to the solid phase (i.e., all the HPCD added facilitates HOC elution). However, in contrast with conventional surfactants, HPCD becomes relatively less effective for HOC partitioning with increasing HOC size and hydrophobicity. Therefore, comparisons between HPCD and synthetic surfactants for enhanced remediation applications must consider the specific HOC(s) present and the potential for surfactant material losses to the solid phase, as well as other more generally recognized considerations such as material costs and potential toxicological effects.

• Economic and Environmental Geology
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• v.40 no.4
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• pp.445-459
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• 2007

Superconducting Gravimeter(SG) was installed and has been successfully operated at MunGyung, Kyungsang province in Korea in March 2005. It was registered as the 21st observatory of the Global Geodynamics Project. Since SG can precisely measure the gravity variations below the 1mHz frequency band, it has the outstanding capability to sense and resolve many different periodic gravity components from each other. From the raw data collected between 18 March 2005 and 21 February 2006 diurnal and semi-diurnal tidal band's residual gravity components were analyzed. During this process, the instrumental noises, air pressure, and ground water corrections were carried out. Values of $-3.18nm/s^2/hPa\;and\;17nm/s^2/m$ were used respectively in the air pressure and groundwater corrections. Hartmann-Wenzel and Whar-Dehant Earth tide models were adopted to compute the residual gravity for Q1, O1, P1, K1, M2, N2, S2, K2 tidal bands. For the ocean loading correction, SCW80, FES952, and FES02 models were used and compared. As a result, FES02 ocean loading model has shown the best match for the data processing at MunGyung SG MunGyung SG gravity was compared with GRACE satellite gravity. The correlation coefficient between the two gravity after groundwater correction was 0.628, which is higher than before ground water correction. To evaluate sensitivity at MunGyung SG gravity statition, the gravity data measured during 2005 Indodesian earthquake was compared with STS-2 broad band seismometer data. The result clearly revealed that the SG could recorded the same period of earthquake with seismometer event and a few after-shock events those were detected by seismometer.

• Journal of Soil and Groundwater Environment
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• v.11 no.1
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• pp.37-44
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• 2006

This study summarizes advantages and disadvantages of numerical methods and compares ELLAM and LEZOOMPC to develop an efficient numerical modeling technique on contaminant transport. Eulerian-Lagrangian method and Eulerian method are commonly used numerical techniques. However Eulerian-Lagrangian method does not conserve mass globally and fails to treat boundary in a straightforward manner. Also, Eulerian method has restrictions on the size of Courant number and mesh Peclet number because of time truncation error. ELLAM (Eulerian Lagrangian Localized Adjoint Method) which has been popularly used for past 10 years in numerical modeling, is known for overcoming these numerical problems of Eulerian-Lagrangian method and Eulerian method. However, this study investigates advantages and disadvantages of ELLAM and suggests a change for the better. To figure out the disadvantages of ELLAM, the results of ELLAM, LEZOOMPC (Lagrangian-Eulerian ZOOMing Peak and valley Capturing), and visual MODFLOW are compared for four examples having different mesh Peclet numbers. The result of ELLAM generates numerical oscillation at infinite of mesh Peclet number, but that of LEZOOMPC yields accurate simulations. The simulation results suggest that the numerical error of ELLAM could be alleviated by adopting some schemes in LEZOOMPC. In other words, the numerical model which combines ELLAM with backward particle tracking, forward particle tracking, adaptively local zooming, and peak/valley capturing of LEZOOMPC can be developed for not only overcoming the numerical error of ELLAM, but also keeping the numerical advantage of ELLAM.

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.54-61
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• 2012

In this study, the adsorption of $Cu^{2+}$ from aqueous solution by the biochar derived from woody biomass at different pyrolysis temperatures has been investigated. The woody biomass wastes used in this study were branch of willow ($Salix$ $koreensis$ $Andersson$) and bark of chestnut ($Castanea$ $crenata$ $var.$ $dulcis$). Three biochar samples prepared by heating each biomass at temperature of $300^{\circ}C$, $500^{\circ}C$, and $700^{\circ}C$were tested for the adsorption capacity of Cu. Also the physicochemical properties of the developed biochars were studied using different characterization techniques such as FT-IR, SEM, BET surface area, and cation exchange capacity (CEC). The adsorption of Cu could be well described by Langmuir model for both willow and chestnut biochars with $R^2{\geq}0.98$. The maximum adsorption capacities of the biochar produced at $700^{\circ}C$ from the Langmuir equation were found to be 12.5 mg $g^{-1}$ and 16.9 mg $g^{-1}$ for willow and chestnut, respectively. Chestnut biochar was found to interact more effectively with the active sites available for Cu, resulting higher removal of Cu(II) than wiloow biochar. Ion exchange and surface complexation found to be the main mechanisms involved in the adsorption process. This study demonstrated the feasibility of the biochars derived from woody biomass to be as a low-cost potential adsorbent for heavy metals as Cu(II) removal in aquatic system.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.1-11
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• 2003

In order to measure aperture variation dependent on normal stress and to characterize on relationship between aperture variation and hydraulic conductivity this study measured apertures of rock fractures under a high resolution confocal laser scanning microscope (CLSM) with application of five stages of uniaxial normal stresses. From this method the response of aperture can be continuously characterized on one specimen by different loads of normal stress. The results of measurements showed a rough geometry of fracture bearing non-uniform aperture. They also revealed different values of aperture variations according to the load stages on each position along a fracture due to the fracture roughness. Laboratory permeability tests were also conducted to evaluate the changes of permeability coefficients related to the aperture variations by different loads. The results of permeability tests revealed that the hydraulic conductivity was not reduced at a fixed rate with increase of normal load. Moreover, the rates of aperture variations did not match to those of hydraulic conductivity. The hydraulic conductivity calculated in this study did not follow the cubic law, representing that the parallel plate model is not suitable to express the fracture geometry corresponding to the results of aperture measurements under the CLSM.

• The Journal of Engineering Geology
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• v.25 no.2
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• pp.291-298
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• 2015

For hydrogeological studies, it is of importance to observe hydraulic head in order to interpret groundwater flow, characterize aquifers, and calibrate groundwater flow model. This study analyzed the zonal variation of hydraulic heads at the eight monitoring wells (GM-1~GM-8) installed with multi-packers in a coastal area and verified vertical and lateral trends of the hydraulic gradients. Hydraulic heads were expressed as the depth of water because the monitoring wells have different depths. The hydraulic gradient at the nearest well (GM-5) shows 0.0142 with increasing trend of hydraulic gradient along depth. This fact indicates typical phenomenon of the discharge area. On the other hand, GM-1 and GM-2 wells in coastal area demonstrate constant hydraulic gradient down to the depth of 100 meters while at the zone of deeper than 100 m the hydraulic gradients illustrate 0.0196 and 0.0735, respectively. This indicates that horizontal flow is dominant at shallower zone than 100 m whereas upward flow is dominant at the zone deeper than 100 m. GM-3 well located farther than the other wells from the coast shows a small hydraulic gradient of 0.0046 that evidences a prevalent horizontal flow between the recharge area and the discharge area.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.2
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• pp.133-141
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• 2020

A geological repository comprises a natural barrier and an engineered barrier system. Its design components consist of canisters, buffers, backfill, and near-field rock. Among the engineered barrier system components, bentonite buffers minimize the groundwater flow from near-field rock and prevent the release of nuclide. Investigation of the hydraulic conductivity of the buffer to groundwater flow is an important factor in the performance evaluation of the stability and integrity of the engineered barrier of the repository. In this study, saturated hydraulic conductivity tests were performed using Gyeongju bentonite at various dry densities and temperatures, and a hydraulic conductivity prediction model was developed through multiple regression analysis using the 120 result sets of hydraulic conductivity. The test results showed that the hydraulic conductivity tends to decrease as the dry density increases. In addition, the hydraulic conductivity increased with increasing temperature. The multiple regression analysis results showed that the coefficient of determination (R²) of the hydraulic conductivity prediction equation was as high as 0.93. The hydraulic conductivity prediction equation presented in this study could be used for the design of engineered barrier systems.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.51-61
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• 1997

The objective of this study is to evaluate the feasibility of Pumping-and-Treatment system (PTS) for remediation of the saturated zones contaminated with NAPLs. A simulation is carried out for the removal of DNAPLs (denser-than-water non-aqueous phase liquids) and LNAPLS (lighter-than-water non-aqueous phase liquids) distributing at and below the water table. In the study, LNAPL and DNAPL are assumed to be n-hexane and 1,1-dichloroacetone, respectively. The model system studied consists of four heterogeneous soil layers with different permeabilities. Groundwater flows through the bottom layer and a pumping well is located under the initial water table. The time-driven deformation of the water table and removal efficiency of contaminants are estimated after vacuum application to the inlet of the well. In the calculation, FVM (Finite Volumetric Method) with SIMPLEC algorithm is applied. Results show that removal efficiencies of both DNAPL and LNAPL are negligible for the first 5 days after the PTS operation. However, when the cone-shape water table is formed around the inlet of the pumping well, the rapid removal rate is obtained since NAPLs migrate rapidly through the curvature of the water table. The removal efficiency of DNAPL is estimated to be higher than that of LNAPL due to the gravity. The results also show that the fluctuation or cone-shaped depression of the water table enhances the removal efficiency of NAPLs in saturated zones. The simulation results could provide a basis of the PTS design for the removal of NAPLs in saturated zones.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.2
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• pp.95-100
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• 1999

Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.