• 한국지하수토양환경학회지:지하수토양환경
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• 제18권3호
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• pp.109-118
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• 2013

Characteristics of the transport of zero-valent iron nanoparticles (nZVI) in an aquifer were investigated to evaluate an application of nZVI-based reactive zone technology. Main flow direction of groundwater was north. Preferential flow paths of the groundwater identified by natural gradient tracer test were shown northeast and northwest. The highest groundwater velocity was $4.86{\times}10^{-5}$ m/s toward northwest. When the breakthrough curves obtained from the gravity injection of nZVI were compared with the tracer curves, the transport of nZVI was retarded and retardation factors were 1.17 and 1.34 at monitoring wells located on the northeast and northwest, respectively. The ratios of the amount of nZVI delivered to the amount of tracer delivered at the two wells mentioned above were 24 and 28 times greater than that of the well on the main flow direction, respectively. Attachment efficiency based on a filtration theory was $4.08{\times}10^{-2}$ along the northwest direction that was the main migration route of nZVI. Our results, compared to attachment efficiencies obtained in other studies, demonstrate that the mobility of nZVI was higher than that of results reported in previous studies, regardless of large iron particle sizes of the current study. Based on distribution of nZVI estimated by the attachment efficiency, it was found that nZVI present within 1.05 m from injection well could remove 99% of TCE within 6 months.

• 한국지하수토양환경학회지:지하수토양환경
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• 제10권4호
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• pp.54-61
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• 2005

대수층 축열 에너지(ATES) 시스템은 지반의 특성과 이용량에 따라 매우 경제적인 새로운 대체에너지로 이용될 수 있다. 적절한 ATES 시스템 설계를 통하여 주어진 수리지질 특성에 적합한 ATES 시스템을 개발하기 위해서는 대수 층내 수리열역학적 과정의 이해가 필수적이다. 본 논문에서는 지하수 양수 및 열펌프에 이용된 불을 재주입하는 방식의 지하수 열펌프 운영에 대한 두 가지 시나리오를 통하여 두 개의 층으로 이루어진 대수층 모델에 적용하여 대수층내 열 저장에 대한 수리열역학적 현상을 시뮬레이션하였다. 첫 번째 시나리오에서는 양수 우물과 주입 우물을 계절에 따라 서로 교대로 시스템을 운영한 경우에 열 거동에 의한 온도 분포와 지하수위를 시뮬레이션 하였으며, 두 번째는 주입과 양수 우물 위치를 고정하여 시뮬레이션 하였다. 356일 이후 주입 우물 주변의 온도 분포는 주입수의 온도와 주입정으로 부터의 거리에 지배적인 영향을 받는 것으로 나타났다. 지표온도 분포는 30과 50 m 심도의 온도 분포에 비하면 미미한 변화만 나타났으며, 각 층에서의 열 거동은 공극률과 지하수의 유동 특성에 따라 매우 민감한 것으로 나타났다. 그리고 양수와 주입우물에서의 지하수위와 온도변화를 모니터링하여 열펌프 운영 방식에 따른 효율성을 실험하고, 두 우물간의 열 간섭현상을 분석하였다.

• 지질공학
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• 제28권1호
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• pp.81-99
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• 2018

터널 굴착에 의한 다량의 지하수 배출 그리고 터널 굴착 작업은 지하수 고갈과 지반침하를 유발한다. 그러므로, 수리지질학적 방법 및 모델링에 의해서 터널 굴착과 관련하여 환경 영향을 평가하고 영향 저감대책을 수립하는 것이 매우 중요하다. 이 연구는 야외조사, 수질분석, 추적자시험 그리고 지하수 모델링을 통하여 터널 굴착에 의한 저수지와 계곡수의 고갈을 밝히기 위한 것이다. 현장 수질분석 결과, 터널내 배출 지하수의 화학성분의 농도는 계곡수의 화학성분의 농도보다 약간 더 높다. 실내 수질분석 결과, 계곡수와 배출 지하수의 수질형은 둘 다 $Ca^{2+}+HCO_3{^-}$형이다. 계곡의 주입지점과 터널 간의 1차 및 2차 추적자시험에 의하면 계곡수가 지하로 침투하여 터널로 배출되며, 전기전도도는 1차시험에서는 $70{\mu}S/cm$ 그리고 2차 시험에서는 $40{\mu}S/cm$로 나타났다. 지하수 모델링에 의하면, 터널 굴착 시 터널내로의 지하수 배출량은 $4,942m^3$/일이며, 터널 완공 후 3년이 경과하면 지하수위는 원래 상태로 회복되는 것으로 산정된다. 입자추적 모델링에 의하면, 터널에 가장 가까운 입자는 주입 후 6시간 만에 그리고 가장 먼 입자는 9시간만에 터널에 도달하는 것으로 산정되었으며, 이 결과는 야외 추적자시험 결과와 비슷하다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제15권2호
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• pp.10-17
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• 2010

Advanced oxidation processes (AOPs) have advantages to reduce the processing time and mineralize contaminants dissolved in groundwater. Recently, remediation techniques for organic contamination in groundwater have been studied, and technology using $UV/H_2O_2$ is generally accepted as one of the most powerful and reliable alternative for the remediation of groundwater contamination. In this study, $UV/H_2O_2$ technology, which generates hydroxyl radical ($\cdot$ OH) as known for strong non-selective oxidant, was used to degrade chlorinated solvents (TCE and PCE), and it was expanded to apply continuous stirred tank reactor (CSTR) system (i.e. combinations of three CSTR). The tested parameters for CSTR system were retention time and groundwater/$H_2O_2$ injection volume ratio. To find optimum parameters for CSTR system, various retention time (6 min ~ 90 min) and groundwater/$H_2O_2$ injection volume ratio (5/1 ~ 119/1) were tested. Other conditions for CSTR were adapted from the batch test results, which concentration of $H_2O_2$ and UV dose were 29.4 mM (0.1%) and 4.3 kWh/L, respectively. Based on the experimental results, the optimum parameters for CSTR system were 20 min for retention time and 119/1 for groundwater/$H_2O_2$ injection volume ratio. Applying these optimum conditions, chlorinated solvents (TCE and PCE) were removed at 99.9% and 99.6%. Moreover, the effluent concentrations of TCE and PCE are 0.036 mg/L and 0.087 mg/L, respectively, which are satisfied the regulatory level (TCE 0.3 mg/L, PCE 0.1 mg/L). Consequently, the CSTR system using $UV/H_2O_2$ technology can achieve high removal efficiency in the event of treatment of groundwater contaminated by chlorinated solvents (TCE and PCE).

• 대한토목학회논문집
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• 제42권4호
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• pp.501-508
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• 2022

지하수위 회복을 위한 함양정 운영시 필요 기술은 지반이 파괴에 도달하지 않는 최대 주입압을 결정하는 것이다. 고전적인 토질역학에 기초한 수치해석과 실내시험을 통하여 사질토와 점성토의 항복에 도달하는 최대 주입압력을 추론하였다. 수치해석에서는 주입압력에 따른 점성토의 구속압력 감소에 따른 파괴시, 사질토는 유출동수 경사에 따른 파이핑 발생시 주입압력을 최대 한계압으로 결정하였다. 실내시험에서는 간극수압이 높아지는 것을 배압 증가를 통하여 구현하였으며, 사질토 경우 유효응력이 0이 되기전 최대 배압의 93 %에서 급격한 체적변형이 발생하였다. 점성토의 경우는 유효응력이 0에 도달할 경우 방사방향 변형율이 1.5 %에 도달하였으나 급격한 체적변형이 발생하지 않았다. 따라서 상기 결과에 근거하여 함양정의 최대 주입압력을 수치해석과 실내시험으로 결정할 수 있었다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 추계학술발표회
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• pp.231-234
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• 2001

When constructing subsurface structures and/or wells, the precise estimates of hydraulic parameters must be obtained for operating safety and/or for developing necessary quantity of groundwater. Hydraulic conductivity is mainly subjected to the characteristics of fracture network in the fractured media such as fracture orientation and angle, fracture aperture and frequency, fracture length, interconnectivity of fractures, and filling material, feature of fracture plane. In this study we conducted water injection test at afferent depths on six boreholes drilled in granite of Mt. Geumjeong. hydraulic conductivity was calculated using Moye and Hvorslev methods. The relation between hydraulic conductivity and fracture frequency data obtained from acoustic televiewer and core log were analyzed. The result shows that the correlation between the hydraulic conductivity and the fracture frequency data obtained from acoustic televiewer is better than that with the core log.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 총회 및 춘계학술발표회
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• pp.30-33
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• 2002

In this study, feasibility of using hydrogen peroxide as a chemical oxidant for in-situ treatment by EK-Fenton technology were investigated. Kaolinite, kaolinite/sand mixture and illitic soil spiked by phenol and phenanathrene were used and variation of electrochemical characteristics were examined by EK-Fenton test. For kaolinite that having low buffer capacity, hydrogen peroxide was injected effectively from anode reservoir. However illitic soil that having relatively higher buffer capacity had low hydrogen peroxide introducing efficiency. The test results showed that Hydrogen ions generated by current increased during the treatment decreased under pH 3 in the most of kaolinite specimen. Therefore, stabilized hydrogen oxide was injected more effectively in the kaolinite specimen. This study suggests that efficiency of hydrogen peroxide injection by EK-Fenton thechnoloty is dependent of variation of pH in the soil

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.31-34
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• 2004

Feasibility of electrokinetic(EK)-Fenton process and Ozone chemical oxidation were investigated for tile removal of organic contaminants and heavy metals from the contaminated soil. In EK-Fenton process, accumulated electroosmotic flow(EOF) was 80 L for 26 days. Removal efficiency of TPH, As, and Ni were 61%, 36%, and 47%, respectively. The concentration of As was high near the anode due to the transport of anionic As toward the anode, while the concentration of Ni was high near the cathode by the movement of cationic Ni to the cathode. Field scale application of in-situ ozonation was carried out for removal of TPH in 3-D test cell (3 m$\times$2 m$\times$2 m). After 25 days of ozone injection, more than 80% of removal rate was observed through the test cell.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.69-72
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• 2003

The purpose of this study is the development of hybrid horizontal electrokinetic(EK) remediation system on rifle range soil under unsaturated conditions. In order to remediate soil polluted by multi-species heavy metals, in pi]of scale, a series of EK remediation tests are carried out. PVC and PDB(Plastic Drain Board) electrode systems that connected with the power supply of constant voltage and vacuum pressure of 0.5kgf/$\textrm{cm}^2$ are installed, The test results showed that the pH distribution in the sample is below 8, which is maintained until the test is finished, because of the injection of flushing solution. The final concentration, which is normalized by initial concentration, is ranged about 50 to 90%.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권1호
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• pp.1-6
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• 2015

The objectives of this study were to calculate the radius of influence (ROI) of well for an air-sparging (AS)/soil vapor extraction (SVE) system and to evaluate the applicability of the system applied for the remediation of the petroleum contaminated rail site. For air permeability test, three monitoring wells were installed at a location of 1.3 m, 2.3 m, 3.0 m from the extraction well. And the pressure of each monitoring well was measured by extracting air from the extraction well with the pressure and flow of $(-)2,600mmH_2O$ and $1.58m^3/min$. The ROI for an extraction well was calculated as 4.31 m. Air was injected into the injection well with the pressure and flow of $3,500mmH_2O$ and $0.6m^3/min$ to estimate the radius of influence for oxygen transfer. Oxygen concentrations of air from three monitoring wells were measured. The ROI of an injection well for oxygen transfer was calculated as 3.46 m. The 28 extraction wells and 19 injection wells were installed according to the ROI calculated. The AS/SVE system was operated eight hours a day for five months. The rail site was contaminated with the petroleum and concentrations of benzene, toluene, and xylene were over the 'Worrisome Standard' of the 'Soil Environment Conservation Act'. The contaminated area was estimated as $732m^2$ and contaminants were dispersed up to (-)3 m from the ground. During the operation period, soil samples were collected from 5 points and analyzed periodically. With the AS/SVE system operation, concentrations of benzene, toluene, and xylene were decreased from 7.5 mg/kg to 2.0 mg/kg, from 32.0 mg/kg to 23.0 mg/kg, from 35.5 mg/kg to 23.0 mg/kg, respectively. The combined AS/SVE system applied to the rail site contaminated with volatile organic compounds (VOCs) exhibited a high applicability. But the concentration of contaminants in soil were fluctuated due to the heterogeneous of soil condition. Also the effect of the remediation mechanisms was not clearly identified.