• Bulletin of the Korean Chemical Society
• /
• v.33 no.7
• /
• pp.2325-2332
• /
• 2012

A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.

• Journal of Animal Environmental Science
• /
• v.18 no.2
• /
• pp.75-84
• /
• 2012

Current estimation of greenhouse gas (GHG) emissions from livestock agriculture in Korea was based on Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories (1996 IPCC GL) published in 1996 and emission data were published in National Inventory Report. New guideline book, 2006 IPCC Guidelines for National Greenhouse Gas Inventories (2006 IPCC GL), however, was published in 2006. Hence preparation to apply new guideline for the estimation of GHG emission would be necessary. In this study, 1996 IPCC GL and 2006 IPCC GL for livestock agriculture were compared. Estimated GHG emissions based on Tier 1 methods of 1996 IPCC GL and 2006 IPCC GL between 2000 and 2008 were also compared. Estimated GHG emissions based on 2006 IPCC GL were 1.27~1.33 times higher than those based on 1996 IPCC GL. These results were mainly caused by emission factors of each IPCC GL. More researches should be conducted to decrease uncertainties of national GHG inventories.

• Environmental and Resource Economics Review
• /
• v.30 no.3
• /
• pp.503-533
• /
• 2021

This paper analyzes the relationships among the energy consumption, renewable energy production, real gross regional domestic product(GRDP), and greenhouse gas(GHG) emissions. It uses the metropolitan city and province level data for Korea from 2010 to 2018, employing a panal vector autoregressive(VAR) model. We find that an increase in energy consumption has a limited impact on boosting renewable energy production or gross regional domestic product, while it leads to an increase in greenhouse gas emissions. A rise in renewable energy production can increase gross regional domestic product, but it has no meaningful effects on energy consumption and the reduction of green house gas emissions. Our finding indicates that it is crucial to expand the supply of renewable energy as well as to decrease energy consumption in order to achieve the goal of reducing greenhouse gas emissions and reaching economic growth.

• Journal of Climate Change Research
• /
• v.7 no.1
• /
• pp.85-93
• /
• 2016

This study the efficiency of greenhouse gas reduction of 'low carbon car collaboration fund' and its alternative 'control of average fuel efficiency and greenhouse gas', and 'improving driving behavior' were analyzed by using LEAP, long term energy analysis model. Total 4 scenarios were set, baseline scenario, without energy-saving activity, 'low carbon car collaboration fund' scenario, 'fuel efficiency improving scenario', and 'improving driving behavior' scenario. The contents of analysis were forecast of energy demand by scenario and application as well as reduction of greenhouse gas emission volume, and the period taken for analysis was every 1 year during 2015~2030. Baseline scenario, greenhouse gas emission volume in 2015 would be 7,935,697 M/T and 13,081,986 M/T in 2030, increased 64.8%. The analysis result was average annual increase rate of 3.4%. The expected average annual increase rate of other scenarios was, 'low carbon car collaboration fund' scenario 1.7%, 'fuel efficiency improving' scenario 3.0%. and 'improving driving behavior' scenario 3.4%. and these were each 1.7%, 0.3%. 0.3% reduce from baseline scenario. The largest reduction was 'low carbon car collaboration fund' scenario, and there after were 'fuel efficiency improving scenario', and 'improving driving behavior' scenario.

• Journal of Climate Change Research
• /
• v.1 no.1
• /
• pp.13-20
• /
• 2010

Recently, the operation of construction equipments have increased by many construction project. So a respectable amount of greenhouse gas is expected from construction equipments. But the greenhouse gas emissions from construction equipment have been high uncertainty due investigation of a lack of activity data and emission factors in Korea. In this study, annual greenhouse gas emissions from construction equipment are estimated by IPCC's Tier 2 and Tier 3 method. These methods require emission factors, fuel consumption, average kilowatts and operating hours. As the results, the nationwide emission from construction equipments by Tier 2 and Tier 3 are calculated as $21,784kton-CO_2eq/year$ and $22,811kton-CO_2eq/year$ in 2008.

• Resources Recycling
• /
• v.32 no.2
• /
• pp.43-51
• /
• 2023

In this research, through LCA analysis, the environmental impact of automotive engine manufacturing and re-manufacturing was analyzed from the perspective of the entire process, and the greenhouse gas reduction effect was calculated based on this. The amount of greenhouse gas emitted from the process of acquiring and manufacturing raw materials for automotive engines is about 3,473 kg for new manufacturing and 872 kg for re-manufacturing. Thus, the amount of greenhouse gas reduction by engaging in re-manufacturing is about 2,601 kg; the analysis shows a reduction effect in each part of the entire process except for the processing stage. As a result of the LCA weighted analysis, the environmental impact of new product manufacturing was found to be 1.07E+03 Eco-point, and it was 2.67E+02 Eco-point for re-manufacturing. The share of GWP(Global Warming Potential) among the six major impact categories(Abiotic Depletion Potential, Acidification Potential, Eutrophication Potential, Global Warming Potential, Ozone-layer Depletion Potential, Photochemical Oxidant Creation Potential) as high at 99.72%(new manufacturing) and 99.68%(re-manufacturing).

• Journal of Biosystems Engineering
• /
• v.26 no.5
• /
• pp.441-448
• /
• 2001

Hot air heater with light oil combustion is used as the most common heater for greenhouse heating in the winter season. However, exhaust gas heat discharged to atmosphere through chimney reaches up to 10~20% of total heat capacity of the oil burred. In order to recover the heat of this exhaust gas and to use for greenhouse heating, the heat pipe type exhaust heat recovery system was manufactured and tested in this experiment. The system consisted of a heat exchanger made of heat pipes, ø15.88${\times}$600mm located in the rectangular box of 675(L)${\times}$425(W)${\times}$370(H)mm, an air suction fan and air ducts. The number of heat pipe was 60, calculated considering the heat exchange amount between exhaust gas and air and heat transfer capacity of a heat pipe. The working fluid of heat pipe was acetone because acetone is known for its excellent heat transfer capacity. The system was attached to the exhaust gas path. According to the performance test it could recover 53,809 to 74,613kJ/h depending on the inlet air temperature of 12 to -12˚at air flow rate of 1.100㎥/h. The temperature of the exhaust gas left the heat exchanger dropped to 100$^{\circ}C$ from 270$^{\circ}C$ after the heat exchange between the suction air and the exhaust gas.

• Journal of Korean Society for Atmospheric Environment
• /
• v.26 no.6
• /
• pp.657-665
• /
• 2010

Carbon dioxide ($CO_2$) is known to be a major greenhouse gas partially emitted from waste combustion facilities. According to the greenhouse gas emission inventory in Korea, the quantity of the gas emitted from waste sector in 2005 represents approximately 2.5 percent of all domestic greenhouse gas emission. Currently, the emission rate of greenhouse gas from the waste sector is relatively constant partly because of both the reduced waste disposal in landfills and the increased amounts of waste materials for recycling. However, the greenhouse gas emission rate in waste sectors is anticipated to continually increase, mainly due to increased incineration of solid waste. The objective of this study was to analyze the property of Municipal Solid Waste (MSW) and estimate $CO_2$ emissions from domestic MSW incineration facilities. The $CO_2$ emission rates obtained from the facilities were surveyed, along with other two methods, including Tier 2a based on 2006 IPCC Guideline default emission factor and Tier 3 based on facility specific value. The $CO_2$ emission rates were calculated by using $CO_2$ concentrations and gas flows measured from the stacks. Other parameters such as waste composition, dry matter content, carbon content, oxidation coefficient of waste were included for the calculation. The $CO_2$ average emission rate by the Tier 2a was 34,545 ton/y, while Tier 3 was 31,066 ton/y. Based on this study, we conclude that Tier 2a was overestimated by 11.2 percent for the $CO_2$ emission observed by Tier 3. Further study is still needed to determine accurate $CO_2$ emission rates from municipal solid waste incineration facilities and other various combustion facilities by obtaining country-specific emission factor, rather than relying on IPCC default emission factor.

• Coupled systems mechanics
• /
• v.12 no.6
• /
• pp.531-537
• /
• 2023

Municipal solid waste landfills are unpredictable bioreactors which in cases of mishandling and bad supervision presents numerous risks. The key to municipal waste landfills is to approach them from the point of prevention of the possible consequences, which means using methods of organized waste disposal, and also utilizing landfill gas, as an unavoidable consequence with disposal of municipal solid waste with a high share of biodegradable organic matter. This paper presents an overview about problems of solid municipal waste management, type and composition of waste, and an overview of waste management condition. Further, the problem of landfill and landfill gasses is described with the calculation models of landfill production, as well as the use of the SWM GHG Calculator and LandGEM software on a specific example of gas production for the central zone at Sarajevo landfill "Smiljevici". Main focus of this thesis is the analysis of potentials of greenhouse gas emission reduction measures from the waste management. Overview of the best available techniques in waste management is presented as well as the methodology used for calculations. Scenarios of greenhouse gas emission reduction in waste management were defined so that emissions were calculated using the appropriate model. In the final section of the paper, its description of the problem of collection and utilization the landfill gas at the sanitary landfill "Smiljevici", and implementation of the system for landfill gas collection and solution suggestion for the gasification and exploitation of gas. Energy, environmental and economic benefits can be accomplished by utilizing municipal solid waste as fuel in industry and energy and moreover by utilizing energy generation from landfill gas, which this thesis emphasizes.

• Proceedings of the KSR Conference
• /
• 2011.05a
• /
• pp.536-543
• /
• 2011

The previous researches on railway sector have focused on the total greenhouse gas(GHG) emission through national approaches. The aim of this study was to calculate GHG emission at a local government level to measure each city's GHG intensity on rail transportation. This study followed 'the guidelines for local government greenhouse gas inventory(issued by Korea Environment Corporation)' including VKT(Vehicle kilometers Travelled) methodology for railway inventory at a metropolitan area. As a result, the gyeongsangbuk-do emitted the highest GHG emissions at a local government level, followed by chungcheongnam-do and chungcheongbuk-do in 2006. Among several cities, Gimcheon-city emitted the highest GHG at basic government level in 2006. In future, the calculation of GHG emissions at local government level can be applied to establish various policies for GHG reduction.