• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2325-2332
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• 2012

A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.

• 한국축산시설환경학회지
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• 제18권2호
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• pp.75-84
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• 2012

현재 우리나라 축산부문의 온실가스 배출량 계산은 1996년에 출판된 '1996년 IPCC 국가 온실가스 인벤토리 지침서 (1996 IPCC지침)'에 따라 계산하고 있으며 그 배출량 데이터는 국가 인벤토리 보고서에 사용하고 있다. 하지만 새로운 지침서, '2006년 IPCC 국가 온실가스 인벤토리 지침서 (2006 IPCC 지침)'가 2006년에 출판되었기 때문에 온실가스 배출량 계산을 위한 새로운 지침서를 적용하기 위한 준비가 필요하다. 본 연구에서는 축산에서 1996 IPCC 지침과 2006 IPCC 지침을 비교하였다. 또한 2000년부터 2008년 사이의 온실가스 배출량을 Tier 1 방법으로 계산하였다. 2006 IPCC 지침으로 계산한 온실가스 배출량은 1996 IPCC 지침을 이용할 때와 비교하여 1.27~1.33배 더 많았다. 이는 배출계수의 차이에 의한 것으로 나타났다. 국가 온실가스 인벤토리의 불확실성을 감소시키기 위해 더 많은 연구가 필요하다.

• 자원ㆍ환경경제연구
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• 제30권3호
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• pp.503-533
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• 2021

본 연구는 2010~18년 동안의 우리나라 16개 광역시·도(세종시 제외)별 자료와 패널 벡터자기회귀(Panel VAR) 모형을 이용하여 에너지 소비량, 신재생에너지 생산량, 실질 지역 내 총생산, 온실가스 배출량 간의 관계를 실증분석하였다. 분석 결과, 에너지 소비 증가가 신재생에너지 생산 및 지역 내 총생산을 증가시키는 효과는 제한적인 가운데 온실가스 배출을 증가시키는 것으로 나타났다. 신재생에너지 생산 증가는 지역 내 총생산을 증가시킬 수 있는 반면 에너지 소비 및 온실가스 배출량 저감에는 대체로 유의미한 영향을 미치지 않았다. 이러한 분석 결과는 국가 온실가스 저감과 지역 경제성장 목표 달성을 위해서는 에너지 소비 감소와 함께 신재생에너지 보급 확대가 중요함을 보여준다.

• 한국기후변화학회지
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• 제7권1호
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• pp.85-93
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• 2016

This study the efficiency of greenhouse gas reduction of 'low carbon car collaboration fund' and its alternative 'control of average fuel efficiency and greenhouse gas', and 'improving driving behavior' were analyzed by using LEAP, long term energy analysis model. Total 4 scenarios were set, baseline scenario, without energy-saving activity, 'low carbon car collaboration fund' scenario, 'fuel efficiency improving scenario', and 'improving driving behavior' scenario. The contents of analysis were forecast of energy demand by scenario and application as well as reduction of greenhouse gas emission volume, and the period taken for analysis was every 1 year during 2015~2030. Baseline scenario, greenhouse gas emission volume in 2015 would be 7,935,697 M/T and 13,081,986 M/T in 2030, increased 64.8%. The analysis result was average annual increase rate of 3.4%. The expected average annual increase rate of other scenarios was, 'low carbon car collaboration fund' scenario 1.7%, 'fuel efficiency improving' scenario 3.0%. and 'improving driving behavior' scenario 3.4%. and these were each 1.7%, 0.3%. 0.3% reduce from baseline scenario. The largest reduction was 'low carbon car collaboration fund' scenario, and there after were 'fuel efficiency improving scenario', and 'improving driving behavior' scenario.

• 한국기후변화학회지
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• 제1권1호
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• pp.13-20
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• 2010

현재 건설기계는 산업발전과 건설공사의 증가에 따라 사용이 늘고 있다. 그러나 국내 건설기계 온실가스 배출량은 활동도 자료가 미비하고 국내 배출계수가 없어 불확실성이 큰 실정이다. 본 연구에서 최근 배출량 산정 방법(Tier 2, Tier 3), 배출계수, 연료 소비량, 평균 정격 출력, 가동 시간을 이용하여 배출량을 산정하였다. 그 결과 2008년도 건설기계의 온실가스 배출량은 Tier 2, Tier 3 산출 방법에 의하여 각각 21,784천 $ton-CO_2eq/yr$, 22,811천 $ton-CO_2eq/yr$으로 산출되어 Tier 3에 의한 배출량이 Tier 2에 의한 배출량보다 약 4.7% 크게 산정되었다.

• 자원리싸이클링
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• 제32권2호
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• pp.43-51
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• 2023

본 연구에서는 자동차엔진의 신품제조시와 재제조시 발생하는 환경영향을 전과정 관점에서 산정하고 이를 기반으로 온실가스 저감효과를 산정하였다. 자동차엔진 원부자재 원료취득 및 제조공정에서 배출되는 온실가스량은 신품제조시 약 3,473 kg, 재제조시 약 872 kg으로 재제조를 통해 저감되는 온실가스량은 약 2,601kg으로 나타나 폐기 단계를 제외한 전과정 측면에서 저감효과가 있는 것으로 분석되었다. LCA 가중화 분석 결과 신품 제조시 환경영향은 1.07E+03 Eco-point, 재제조시 2.67E+02 Eco-point로 나타났으며, 주요 6대 영향 범주 중 지구온난화 점유비율이 99.72%, 99.68%로 높게 나타났다.

• Journal of Biosystems Engineering
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• 제26권5호
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• pp.441-448
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• 2001

Hot air heater with light oil combustion is used as the most common heater for greenhouse heating in the winter season. However, exhaust gas heat discharged to atmosphere through chimney reaches up to 10~20% of total heat capacity of the oil burred. In order to recover the heat of this exhaust gas and to use for greenhouse heating, the heat pipe type exhaust heat recovery system was manufactured and tested in this experiment. The system consisted of a heat exchanger made of heat pipes, ø15.88${\times}$600mm located in the rectangular box of 675(L)${\times}$425(W)${\times}$370(H)mm, an air suction fan and air ducts. The number of heat pipe was 60, calculated considering the heat exchange amount between exhaust gas and air and heat transfer capacity of a heat pipe. The working fluid of heat pipe was acetone because acetone is known for its excellent heat transfer capacity. The system was attached to the exhaust gas path. According to the performance test it could recover 53,809 to 74,613kJ/h depending on the inlet air temperature of 12 to -12˚at air flow rate of 1.100㎥/h. The temperature of the exhaust gas left the heat exchanger dropped to 100$^{\circ}C$ from 270$^{\circ}C$ after the heat exchange between the suction air and the exhaust gas.

• 한국대기환경학회지
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• 제26권6호
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• pp.657-665
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• 2010

Carbon dioxide ($CO_2$) is known to be a major greenhouse gas partially emitted from waste combustion facilities. According to the greenhouse gas emission inventory in Korea, the quantity of the gas emitted from waste sector in 2005 represents approximately 2.5 percent of all domestic greenhouse gas emission. Currently, the emission rate of greenhouse gas from the waste sector is relatively constant partly because of both the reduced waste disposal in landfills and the increased amounts of waste materials for recycling. However, the greenhouse gas emission rate in waste sectors is anticipated to continually increase, mainly due to increased incineration of solid waste. The objective of this study was to analyze the property of Municipal Solid Waste (MSW) and estimate $CO_2$ emissions from domestic MSW incineration facilities. The $CO_2$ emission rates obtained from the facilities were surveyed, along with other two methods, including Tier 2a based on 2006 IPCC Guideline default emission factor and Tier 3 based on facility specific value. The $CO_2$ emission rates were calculated by using $CO_2$ concentrations and gas flows measured from the stacks. Other parameters such as waste composition, dry matter content, carbon content, oxidation coefficient of waste were included for the calculation. The $CO_2$ average emission rate by the Tier 2a was 34,545 ton/y, while Tier 3 was 31,066 ton/y. Based on this study, we conclude that Tier 2a was overestimated by 11.2 percent for the $CO_2$ emission observed by Tier 3. Further study is still needed to determine accurate $CO_2$ emission rates from municipal solid waste incineration facilities and other various combustion facilities by obtaining country-specific emission factor, rather than relying on IPCC default emission factor.

• Coupled systems mechanics
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• 제12권6호
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• pp.531-537
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• 2023

Municipal solid waste landfills are unpredictable bioreactors which in cases of mishandling and bad supervision presents numerous risks. The key to municipal waste landfills is to approach them from the point of prevention of the possible consequences, which means using methods of organized waste disposal, and also utilizing landfill gas, as an unavoidable consequence with disposal of municipal solid waste with a high share of biodegradable organic matter. This paper presents an overview about problems of solid municipal waste management, type and composition of waste, and an overview of waste management condition. Further, the problem of landfill and landfill gasses is described with the calculation models of landfill production, as well as the use of the SWM GHG Calculator and LandGEM software on a specific example of gas production for the central zone at Sarajevo landfill "Smiljevici". Main focus of this thesis is the analysis of potentials of greenhouse gas emission reduction measures from the waste management. Overview of the best available techniques in waste management is presented as well as the methodology used for calculations. Scenarios of greenhouse gas emission reduction in waste management were defined so that emissions were calculated using the appropriate model. In the final section of the paper, its description of the problem of collection and utilization the landfill gas at the sanitary landfill "Smiljevici", and implementation of the system for landfill gas collection and solution suggestion for the gasification and exploitation of gas. Energy, environmental and economic benefits can be accomplished by utilizing municipal solid waste as fuel in industry and energy and moreover by utilizing energy generation from landfill gas, which this thesis emphasizes.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2011년도 춘계학술대회 논문집
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• pp.536-543
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• 2011

The previous researches on railway sector have focused on the total greenhouse gas(GHG) emission through national approaches. The aim of this study was to calculate GHG emission at a local government level to measure each city's GHG intensity on rail transportation. This study followed 'the guidelines for local government greenhouse gas inventory(issued by Korea Environment Corporation)' including VKT(Vehicle kilometers Travelled) methodology for railway inventory at a metropolitan area. As a result, the gyeongsangbuk-do emitted the highest GHG emissions at a local government level, followed by chungcheongnam-do and chungcheongbuk-do in 2006. Among several cities, Gimcheon-city emitted the highest GHG at basic government level in 2006. In future, the calculation of GHG emissions at local government level can be applied to establish various policies for GHG reduction.