• 한국세라믹학회지
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• 제26권2호
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• pp.187-194
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• 1989

Synthesis of spinel pigment on ZnO-Fe2O3 system. The object of this research is the synthesis of new spinel pigments on the basic of ZnO-Fe2O3 system which was substituted by ZnO-Fe2O3 by MgO-Al2O3. This research was progressed by measuring the X-ray diffraction and the reflectances of the substitued ZnO-Fe2O3 group. Which was obtained by sintering at the temperature of 1,00$0^{\circ}C$, 1,10$0^{\circ}C$, 1,20$0^{\circ}C$ and 1,25$0^{\circ}C$ and them by regrinding. In order to coloring test, here basic compositions of Barium glaze, Zinc glaze, Lime glaze, Lead glaze and Talc glaze used in this experiment are obtained from the ceramic work. Adding synthetic stains in these basic glazes with 3%, mixing and glazing on the specimen. The specimens was fired at 1,28$0^{\circ}C$ in reducing and oxidizing atmosphere in the gas kiln. The results of the research as follow. 1. Many kinds of spinel pigment was produced on ZnO-Fe2O3 system that is to say, not always only spinel. 2. Spinel peak was observed strongly on the ZnO-Fe2O3 system withsubstituting by MgO-Fe2O3 and MgO-Al2O3 group(the ratio of MgO, Al2O3 being increased, observed more strongly). 3. The most effective temperature ranges was 1,20$0^{\circ}C$~1,25$0^{\circ}C$. 4. The color of spinel pigments on this system was observed by "stable YR". 5. It was yellow red in oxidizing and green in reducing atmosphere on the coloring test.ring test.

• 한국문화재보존과학회:학술대회논문집
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• 한국문화재보존과학회 2006년도 제24회 학술대회발표 논문집
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• pp.213-217
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• 2006

• 대한안전경영과학회지
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• 제9권6호
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• pp.197-204
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• 2007

Ceramic pigments were developed by using 4 kinds of Brass scraps. Each Brass scraps were mixed with same weight-ratio of Husk ash, and fine-ground by Rotate ring mill(RRG-120, Armstech industrial. co. Ltd, Korea) after firing at $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. As a result, analysis of particle size of synthetic pigments by particle size analyser, they are $3{\mu}m$ as average. The resulting pigments were characterized by using XRD, FT-IR, SEM Structure of the crystals are Zn2SiO4,, and ZnO, Cu2O, CuO, and cristobalite are existed and particles' shape are plate or needle. As a result of analysis of chemical composition by XRF, synthetic pigments have high SiO2 and CuO content and have SnO2, ZnO and NiO, too. 1wt%, 3wt% and 5wt% pigments were added in each lime glaze, lime-barium glaze and lime-magnesia glaze, and fired at oxidation and reducing atmosphere to figure hue in glazes out. As a result of analysis of color, chroma and brightness by UV, colors of glazes fired at oxidation atmosphere turned into green from sky blue, and colors of glazes fired at reducing atmosphere turned into pink and red.

• 한국문화재보존과학회:학술대회논문집
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• 한국문화재보존과학회 2005년도 제21회 발표논문집
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• pp.174-177
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• 2005

• 한국결정성장학회지
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• 제17권6호
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• pp.264-271
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• 2007

본 연구에서는 $Fe_2O_3-CoO-Cr_2O_3-MnO_2$계 색상의 무기안료를 공침법을 사용하여 합성하였다. 출발원료로는 $FeCl_3,\;CoCl_2,\;CrCl_3,\;MnCl_2$를 사용하였으며 침전제로는 2N-KOH를 사용하였다. $MnCl_2$는 10 mole%로 고정한 후 세 가지 원료로서 6가지 조성비를 만들어 안료를 합성하였다. 조합된 시료는 1.5시간 $1350^{\circ}C$에서 하소하였다. XRD, FT-IR, SEM 과 UV spectrophotometer를 사용하여 안료의 특성 분석을 하였다. 합성된 안료는 석회유, 석회 바륨유에 각각 6wt%씩 첨가하여 $1260^{\circ}C$ 산화소성, $1240^{\circ}C$ 환원 소성하였다. UV Spectrometer를 사용하여 색상분석을 한 결과는 black, bluish black, dark grayish green을 나타냈다.

• 한국산학기술학회논문지
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• 제14권6호
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• pp.3102-3107
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• 2013

$Al_2O_3$, CoO, $Cr_2O_3$, ZnO, $SrO_2$ 및 Kaolin을 이용하여 무기안료를 제조하였다. 제조방법은 원료분말들을 일정비율로 배합하고 분쇄한 후 소성을 시키고 분쇄 및 건조과정을 거쳐 제조하였다. 안료의 원료 중 $Cr_2O_3$의 비율이 증가할수록 청색에서 녹색으로 발현되는 것을 알 수 있었으며 안료의 조성에 관계없이 소성시킨 안료의 입자크기가 작아질수록 색도가 밝아지는 것을 알 수 있었다. 그리고 소성시 최고온도는 $1,250^{\circ}C$정도가 가장 적합한 것으로 조사되었다. 안료의 유약적합성 실험에서는 안료 성분 중 $Cr_2O_3$의 비율이 증가할수록 녹색에 가까워졌으며 CoO의 비율이 증가할수록 청색감이 증가하였다.

• 대한화학회지
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• 제4권1호
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• pp.27-37
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• 1957

High-fire stain is influenced by the conditions of glaze, firing atmosphere, etc. On the contrary, low fire stain is not influenced by those conditions but obtainable in arbitrary colors and it is indispensable for pottery decoration. It is difficult for us to study into the color in the sphere of result publication method and expression of color. Looking over the literature on this subject, I have been confronted with much difficulties, accordingly, I made a basic and systematic experiment as to six low-firing stains (blue, green, blue-green, brown black and yellow) and made it proper to be applied in these studies. On pigment, I confirmed the influence of the assistant coloring matter by mixing up the coloring matter and the assistant coloring matter in various proportions. On flux, I measured the melting point by making PbO-$SiO_2$ system and PbO-$B_2O_3-SiO_2$ system and decided the range of usage. Also I checked the coloring by making the pigment on laze with pigment and flux manufactured, and concluded the pigment and flux adaptation to it.

• 한국세라믹학회지
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• 제44권10호
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• pp.554-561
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• 2007

Synthesis and characterization of pigments by using $Fe_2O_3,\;CoO,\;Cr_2O_3\;and\;MnO_2$ were undertaken. The resulting pigments were characterized by using XRD, SEM, FT-IR and UV-Vis spectrophotometer. The color of glazed tiles containing 6 wt% pigment changed from dark green to black depending on the compositions of used materials. Pigments were calcined with mixed materials at $1350^{\circ}C$, and the dark green and dark brown color were obtained. Pigments were used to determine possible interactions between a pigment and a glaze.

• 한국세라믹학회지
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• 제47권4호
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• pp.302-307
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• 2010

This study aims to synthesize emerald-green malayaite pigments using $CaCO_3$, $SiO_2$, $SnO_2$ and $V_2O_5$. For this purpose, the optimum composition is $CaV_{0.25}Sn_{0.687}SiO_5$ and heating condition is at $1250^{\circ}C$ for 6 h of soaking time. The samples were characterized by X-ray diffraction (XRD), the Fourier Transform Infrared Spectrometers(FT-IR), the Raman Spectrometer, Scanning Electron Microscope(SEM) and the UV/Vis spectroscopy. The substituted V ion for Sn was observed to be quadrivalence. The analytical results of the synthesized pigment showed the tetragonal crystal, a typical form of Malayaite, and the particle size to be approximately $5{\sim}10\;{\mu}m$. The color in lime glaze added 12 wt% pigment was emerald green, and CIE Lab parameters are $L^*=67.73$, $a^*=-12.39$ and $b^*=9.28$.

• 대한공간정보학회지
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• 제7권1호
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• pp.65-74
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• 1999

문화재의 정밀 수치자료와 분석체계의 구축은 대상물의 보존과 복원을 위한 기초자료로서 매우 중요한 의미를 지니고 있다. 본 연구는 보다 효율적으로 문화재를 관리하기 위한 수치자료의 획득과 분석시스템의 구축에 관한 것이다. 분청사기 매병에 대해 소프트카피 사진측량기법을 적용하여 정밀 3차원 수치자료를. 구축하고 이를 기반으로 다양한 공간분석과 모니터링을 수행하므로써 문화재 보존을 위한 효율적인 방법을 제시하였다.