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Development of Ceramic Pigment using Brass Scrap  

Kim, Jun-Ho (Department of Material Science & Engineering, Myongji University)
Jeon, Ok-Hyun (Department of Material Science & Engineering, Myongji University)
Suh, Man-Chul (Department of Chemical Engineering & Biotechnology, Korea Polytechnic University)
Lee, Byung-Ha (Department of Material Science & Engineering, Myongji University)
Publication Information
Journal of the Korea Safety Management & Science / v.9, no.6, 2007 , pp. 197-204 More about this Journal
Abstract
Ceramic pigments were developed by using 4 kinds of Brass scraps. Each Brass scraps were mixed with same weight-ratio of Husk ash, and fine-ground by Rotate ring mill(RRG-120, Armstech industrial. co. Ltd, Korea) after firing at $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. As a result, analysis of particle size of synthetic pigments by particle size analyser, they are $3{\mu}m$ as average. The resulting pigments were characterized by using XRD, FT-IR, SEM Structure of the crystals are Zn2SiO4,, and ZnO, Cu2O, CuO, and cristobalite are existed and particles' shape are plate or needle. As a result of analysis of chemical composition by XRF, synthetic pigments have high SiO2 and CuO content and have SnO2, ZnO and NiO, too. 1wt%, 3wt% and 5wt% pigments were added in each lime glaze, lime-barium glaze and lime-magnesia glaze, and fired at oxidation and reducing atmosphere to figure hue in glazes out. As a result of analysis of color, chroma and brightness by UV, colors of glazes fired at oxidation atmosphere turned into green from sky blue, and colors of glazes fired at reducing atmosphere turned into pink and red.
Keywords
Brass; Pigment; Glaze CuO; ZnO;
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