• Title/Summary/Keyword: Green Chemistry

Search Result 944, Processing Time 0.029 seconds

Effect of LED mixed light conditions on the glucosinolate pathway in brassica rapa (배추 유묘의 글루코시놀레이트 합성 기작에 미치는 LED 혼합광의 효과)

  • Moon, Junghyun;Jeong, Mi Jeong;Lee, Soo In;Lee, Jun Gu;Hwang, Hyunseung;Yu, Jaewoong;Kim, Yong-Rok;Park, Se Won;Kim, Jin A
    • Journal of Plant Biotechnology
    • /
    • v.42 no.3
    • /
    • pp.245-256
    • /
    • 2015
  • In the agricultural industries, LEDs are used as supplementary, as well as main lighting sources in closed cultivation systems. In cultivation using artificial light sources, various light qualities have been tried to supplement fluorescent lamps to promote plant growth and metabolism. Microarray analysis of Brassica rapa seedlings under blue and fluorescent mixed with blue light conditions identified changes in three genes of the glucosinolate pathway. This attracted attention as functional materials highly expressed 3.6-4.6 fold under latter condition. We selected four more genes of the glucosinolate pathway from the Brassica database and tested their expression changes under fluorescent light mixed with red, green, and blue, respectively. Some genes increased expression under red and blue mixed conditions. The Bra026058, Bra015379, and Bra021429; the orthologous genes of CYP79F1, ST5a, and FMOGS-OX1 in Arabidopsis, are highly expressed in Brassica rapa under fluorescent mixed with blue light conditions. Further, Bra029355, Bra034180, Bra024634, and Bra022448; the orthologous genes of MAM1, AOP3, UGT74B1, and BCAT4 in Arabidopsis, are highly expressed in Brassica rapa under fluorescent mixed with red light conditions. The various light conditions had unique effects on the varieties of Brassica, resulting in differences in glucosinolate synthesis. However, in some varieties, glucosinolate synthesis increased under mixed blue light conditions. These results will help to construct artificial light facilities, which increase functional crops production.

Comparison of Non-structural Carbohydrate Concentration Between Zoysiagrass and Creeping Bentgrass During Summer Growing Season (하계 생육기 동안 Zoysiagrass와 Creeping Bentgrass의 비구조적 탄수화물 함량의 비교)

  • Kim, Dae-Hyun;Jung, Woo-Jin;Lee, Bok-Rye;Kim, Kil-Yong;Kim, Tae-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
    • /
    • v.22 no.2
    • /
    • pp.145-152
    • /
    • 2002
  • To compare the Carbon metabolic response to high temperature stress in Zoysiagrass [Zoysia matrella (L.) Merr.] and Creeping bentgrass (Agrostis palustris Huds) with respect to heat tolerance, C metabolites were determined from April to September. Sampling was carried out on an established golf course (Muan Country Club, Chonnam, Korea). Shoot mass(g Dry weight per hole cup) of creeping bentgrass started to decrease from June and recovered from August whereas that of zoysiagrass was less varied. Chlorophyll content in creeping bentgrass was significantly higher than zoysiagrass until July, and then decreased by 43% from July to August. Zoysiagrass contained higher soluble sugar than creeping bentgrass throughout experimental period. Soluble sugar in zoysiagrass increased about 58% from April to May, and less varied until August. Soluble sugar in creeping bentgrass slightly increased until July and sharply decreased at August. Starch concentration in zoysiagrass continuously decreased to September after a significant increase from April to May. A remarkable fluctuation in both starch and fluctuation concentration was observed between June and August showing high accumulation for June to July and high degradation for July to August. These results suggest that through creeping bentgrass suffers much severely from high temperature stress than zoysiagrass especially June to August. An active accumulation and degradation in nonstructural carbohydrate in creeping bentgrass during this period might be associated with heat stress.

A Study on the Hydraulic Characteristics of Rashig Super-Ring Random Packing in a Counter-Current Packed Tower (역류식 충전탑에서 Raschig Super-ring Random Packing의 수력학적 특성에 대한 연구)

  • Kang, Sung Jin;Lim, Dong-Ha
    • Clean Technology
    • /
    • v.26 no.2
    • /
    • pp.102-108
    • /
    • 2020
  • In recent years, packed column has been widely used in separation processes, such as absorption, desorption, distillation, and extraction, in the petrochemical, fine chemistry, and environmental industries. Packed column is used as a contacting facility for gas-liquid and liquid-liquid systems filled with random packed materials in the column. Packed column has various advantages such as low pressure drop, economical efficiency, thermally sensitive liquids, easy repairing restoration, and noxious gas treatment. The performance of a packed column is highly dependent on the maintenance of good gas and liquid distribution throughout a packed bed; thus, this is an important consideration in a design of packed column. In this study, hydraulic pressure drop, hold-up as a function of liquid load, and mass transfer in the air, air/water, and air-NH3/water systems were studied to find the geometrical characteristic for raschig super-ring experiment dry pressure drop. Based on the results, design factors and operating conditions to handle noxious gases were obtained. The dry pressure drop of the random packing raschig super-ring was linearly increased as a function of gas capacity factor with various liquid loads in the Air/Water system. This result is lower than that of 35 mm Pall-ring, which is most commonly used in the industrial field. Also, it can be found that the hydraulic pressure drop of raschig super-ring is consistently increased by gas capacity factor with various liquid loads. When gas capacity factor with various liquid loads is increased from 1.855 to 2.323 kg-1/2 m-1/2 S-1, hydraulic pressure drop increases around 17%. Finally, the liquid hold-up related to packing volume, which is a parameter of specific liquid load depending on gas capacity factor, shows consistent increase by around 3.84 kg-1/2 m-1/2 S-1 of the gas capacity factor. However, liquid hold-up significantly increases above it.

Esterification Reaction of Animal Fat for Bio-diesel Production (바이오디젤 생산을 위한 동물성 오일의 에스테르화 반응)

  • Kim, Sung-Min;Kim, Deog-Keun;Lee, Jin-Suk;Park, Soon-Chul;Rhee, Young-Woo
    • Clean Technology
    • /
    • v.18 no.1
    • /
    • pp.102-110
    • /
    • 2012
  • In this study, the production of bio-diesel from animal oil by esterification and trans-esterification was investigated. There were three different extraction methods for oil extraction from raw animal fat. Heterogeneous catalysts such as Amberlyst-15 and Amberlyst BD-20 and a homogeneous catalyst such as sulfuric acid were used for esterification. Among three catalysts, the removal efficiency of Free Fatty Acid (FFA) was the highest in sulfuric acid. Response surface method was carried out to find the optimal esterification condition of sulfuric acid and methanol. After the esterification under the optimal condition, this animal fat was used for the trans-esterification. Animal oil used for trans-esterification was below 1% of FFA content and 0.09% of water content. The catalysts for trans-esterification were KOH, NaOH and $NaOCH_3$. To investigate the effects of catalyst type and amount on trans-esterification, The amount of catalyst were changed with 0.3, 0.6 and 0.9 wt%. The molar ratio of methanol/oil was changed with 4, 6, 9 and 12. The amount of catalyst was fixed to 0.8 wt%. The KOH catalyst showed the highest FAME conversion for trans- esterification, and the optimal methanol/oil weight ratio was 6. In the experiments of various catalysts and methanol molar ratios, the highest content of FAME is 96%. However, this FAME content was below Korean bio-diesel standard which is 96.5% of FAME content. After distillation, FAME content increased to 98%.