• Title/Summary/Keyword: Graphite particles

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Effects of Filler Characteristics and Processing Conditions on the Electrical, Morphological and Rheological Properties of PE and PP with Conductive Filler Composites

  • Kim, Youn-Hee;Kim, Dong-Hyun;Kim, Ji-Mun;Kim, Sung-Hyun;Kim, Woo-Nyon;Lee, Heon-Sang
    • Macromolecular Research
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    • v.17 no.2
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    • pp.110-115
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    • 2009
  • The electrical, morphological and rheological properties of melt and dry mixed composites of poly ethylene (PE)/graphite (Gr), polypropylene (PP)/Gr and PP/nickel-coated carbon fiber (NCCF) were investigated as a function of filler type, filler content and processing temperature. The electrical conductivities of dry mixed PP/NCCF composites were increased with decreasing processing temperature. For the melt mixed PP/NCCF composites, the electrical conductivities were higher than those of the melt mixed PE/Gr and PP/Gr composites, which was attributed to the effect of the higher NCCF aspect ratio in allowing the composites to form a more conductive network in the polymer matrix than the graphite does. From the results of morphological studies, the fillers in the dry mixed PP/NCCF composites were more randomly dispersed compared to those in the melt mixed PP/NCCF composites. The increased electrical conductivities of the dry mixed composites were attributed to the more random dispersion of NCCF compared to that of the melt mixed PP/NCCF composites. The complex viscosities of the PP/Gr composites were higher than those of the PP/NCCF composites, which was attributed to the larger diameter of the graphite particles than that of the NCCF. Furthermore, the fiber orientation in the 'along the flow' direction during melt mixing was attributed to the decreased complex viscosities of the melt mixed PP/NCCF composites compared those of the melt mixed PP/Gr composites.

Hydrogenation Study of Mg-based Alloys by mechanical Grinding Reaction for Hydrogen Storage of Fuel Cell (연료전지의 수소저장용 마그네슘계 합금의 기계적 분쇄 반응에 의한 수소화 특성 평가)

  • Kim, Ho-Sung;Suh, Hee-Seok;Cha, Jae-Sang
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.6
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    • pp.69-74
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    • 2006
  • The effects of mechanical grinding(MG) treatment on the hydrogen storage of $Mg_2Ni$ alloy and $Mg_2Ni$ composite alloy($Mg_2Ni+graphite$) were investigated by pressure-composition-temperature(PCT) measurement, the micro-electrode technique of electrochemistry and etc, in which PCT was measured at high temperature(around $300[^{\circ}C]$) of gas phase and a carbon-filament micro-electrode for electrochemical evaluation was manipulated to make electrical contact with the particle in 1M KOH aqueous solution. It was found that the hydrogenation properties of $Mg_2Ni$ and graphite composite particle were greatly improved by the mechanical grinding treatment by which the $Mg_2Ni$ and graphite composite alloys could be changed into microstructure and nano-level particles. namely; the hydrogen dissociation pressure of PCT measurement was decreased from 0.55[MPa] to 0.42[MPa] and hydrogenation peaks by micro-electrode were also observed more clearly on the same sample.

High Coulombic Efficiency Negative Electrode(SiO-Graphite) for Lithium Ion Secondary Battery (리튬이온이차전지용 고효율 음극(SiO-Graphite))

  • Shin, Hye-Min;Doh, Chil-Hoon;Kim, Dong-Hun;Kim, Hyo-Seok;Ha, Kyung-Hwa;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Kim, Ki-Won;Oh, Dae-Hui
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.47-50
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    • 2008
  • A new anode composition material comprising of SiO and Graphite has been prepared by adopting High energy ball milling (HEBM) technique. The anode material shows high initial charge and discharge capacity values of 1139 and 568 mAh/g, respectively. The electrode sustains reversible discharge capacity value of 719 mAh/g at 30th cycle with a high coulombic efficiency${\sim}99%$. Since the materials formed during initial charge process the nano silicon/$Li_4SiO_3$ and $Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversibility$(Li_2O)$ will deliver higher reversible capacity. In this study, constant current-constant voltage (CC-CV) charge method was employed in place of usual constant current (CC) method in order to convert efficiently all the SiO particles which resulted high initial discharge capacity at the first cycle. We improved considerably the initial discharge specific capacity of SiO/G composite by pretreatment(CC-CV).

Nanodispersion-Strengthened Metallic Materials

  • Weissgaerber, Thomas;Sauer, Christa;Kieback, Bernd
    • Journal of Powder Materials
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    • v.9 no.6
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    • pp.441-448
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    • 2002
  • Dispersions of non-soluble ceramic particles in a metallic matrix can enhance the strength and heat resistance of materials. With the advent of mechanical alloying it became possible to put the theoretical concept into practice by incorporating very fine particles in a flirty uniform distribution into often oxidation- and corrosion- resistant metal matrices. e.g. superalloys. The present paper will give an overview about the mechanical alloying technique as a dry, high energy ball milling process for producing composite metal powders with a fine controlled microstructure. The common way is milling of a mixture of metallic and nonmetallic powders (e.g. oxides. carbides, nitrides, borides) in a high energy ball mill. The heavy mechanical deformation during milling causes also fracture of the ceramic particles to be distributed homogeneously by further milling. The mechanisms of the process are described. To obtain a homogeneous distribution of nano-sized dispersoids in a more ductile matrix (e.g. aluminium-or copper based alloys) a reaction milling is suitable. Dispersoid can be formed in a solid state reaction by introducing materials that react with the matrix either during milling or during a subsequent heat treatment. The pre-conditions for obtaining high quality materials, which require a homogeneous distribution of small dis-persoids, are: milling behaviour of the ductile phase (Al, Cu) will be improved by the additives (e.g. graphite), homogeneous introduction of the additives into the granules is possible and the additive reacts with the matrix or an alloying element to form hard particles that are inert with respect to the matrix also at elevated temperatures. The mechanism of the in-situ formation of dispersoids is described using copper-based alloys as an example. A comparison between the in-situ formation of dispersoids (TiC) in the copper matrix and the milling of Cu-TiC mixtures is given with respect to the microstructure and properties, obtained.

Preparation and Characterization of $Fe_3O_4$/MWNTs Composites (산화철이 혼입된 다중벽탄소나노튜브 복합체의 제조 및 특성)

  • Park, Soo-Jin;Kim, Young-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.406-409
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    • 2009
  • In this work, the magnetite ($Fe_3O_4$)/multi-walled carbon nanotubes (MWNTs) composites for lithium secondary battery were prepared. Nano-$Fe_3O_4$ was deposited by chemical coprecipitation of $Fe^{2+}$ and $Fe^{3+}$ in the presence of MWNTs in alkaline solutions. Transmission electron spectroscopy (TEM) and X-ray diffraction (XRD) analyses indicated that nano-$Fe_3O_4$ particles had a good crystallinity of cubic specimens and many tiny particles attached on the surfaces of the MWNTs. The electrochemical properties of $Fe_3O_4$/MWNTs composites as anodes in lithium-secondary batteries were evaluated by cyclic voltammetry and galvanostatic charge/discharge techniques. The as-prepared $Fe_3O_4$/MWNTs composites showed an initial lithium storage capacity of 1120 mAh/g and a reversible capacity of 394 mAh/g after 100 cycles, demonstrating better performance than that of the commercial graphite anode materials.

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Synthesis of CNFs(Carbon Nanofibers)/DAAQ electrode for Supercapacitor (슈퍼커패시티용 DAAQ/CNFs 전극의 제조)

  • Lee, Tae-Soo;Lee, Yun-Hee;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1220-1223
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    • 2003
  • A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. A crystalline supramolecular oligomer of 1,5-diaminoanthraquinone(DAAQ) was successfully prepared as a thin film by electrochemical oxidation from an acidic non-aqueous medium. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M $H_2SO_4$. Its electrochemical characteristics were investigated by cyclic voltammetry. And compared with different electrolyte of aqueous type. During ultrasonic irradiation CNFs was to disperse in 0.1M $H_2SO_4$. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors.

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Formation of Nanoparticles by Spark Discharge in Liquid (용액 내 스파크 방전을 이용한 나노입자 제조 및 특성 평가)

  • Choi, Hoomi;Kim, Jangah;Jung, Seungkyo;Yoon, Juho;Kim, Taesung
    • Particle and aerosol research
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    • v.8 no.1
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    • pp.37-43
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    • 2012
  • In this study, we designed a 'spark in liquid' system. The spark discharge between two electrodes were used to generate particles by using sufficient temperature to evaporate a part of electrodes. The power supply system provides a continuous spark discharge by discharging of the capacitor to ionize the electrodes in liquid. The DC spark discharge system operates with 1-10 kV voltage. Processed copper and graphite rods were used to both electrodes with 1-3 mm diameter. There are several variables which can control the particle size and concentration such as gap distance between electrodes, applied voltage, operating liquid temperature, electrode type and liquid type. So we controlled these variables to confirm the change of particle size distribution and concentration of particles contained in liquid as wt%. 'spark in liquid' system is expected to apply nanoink by control of concentration with analysis of characteristics.

The Modelling of Carbon Plume by Pulsed-laser ablation Method (PLAD법에 의한 탄소 플라즈마의 모델링)

  • So, Soon-Youl;Chung, Hae-Deok;Lee, Jin;Park, Gye-Choon;Kim, Chang-Sun;Moon, Chae-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.41-45
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    • 2006
  • The study on laser-ablation plasmas has been strongly interested in fundamental aspects of laser-solid interaction and consequent plasma generation. In particular, this plasma has been widely used for the deposition of thin solid films and applied to the semiconductors and insulators. In this paper, we developed and discussed the generation of carbon ablation plasmas emitted by laser radiation on a solid target, graphite. The progress of carbon plasmas by laser-ablation was simulated using Monte-Carlo particle model under the pressures of vacuum, 1 Pa, 10 Pa and 66 Pa. At the results, carbon particles with low energy were deposited on the substrate as the pressure becomes higher. However, there was no difference of deposition distributions of carbon particles on the substrate regardless of the pressure.

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Preparation and Characterization of Lubricating Oil-based Nanofluids Containing Carbon Nanoparticles (탄소 나노소재를 이용한 윤활유 기반 나노유체의 제조 및 평가)

  • Choi, Cheol;Jung, Mi-Hee;Oh, Jae-Myung
    • Korean Journal of Materials Research
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    • v.19 no.3
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    • pp.156-162
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    • 2009
  • Lubricant-based nanofluids were prepared by dispersing carbon nanoparticles in gear oil. In this study, the effects of the particle size, shape and dispersity of the particles on the tribological properties of nanofluids were investigated. Dispersion experiments were conducted with a high-speed bead mill and an ultrasonic homogenizer, and the surfaces of the nanoparticles were simultaneously modified with several dispersants. The effective thermal conductivity of the nanofluids was measured by the transient hot-wire method, and the tribological behaviors of the nanofluids were also investigated with a disk-on-disk tribo-tester. The results of this study clearly showed that the combination of the nanoparticles, the deagglomeration process, the dispersant and the dispersion solvent is very important for the dispersity and tribological properties of nanofluids. Lubricant-based nanofluids showed relatively low thermal conductivity enhancement, but they were highly effective in decreasing the frictional heat that was generated. For nanofluids containing 0.1vol.% graphite particles in an oil lubricant, The friction coefficient in the boundary and fluid lubrication range was reduced to approximately 70% of the original value of pure lubricant.

Electrochemical Characteristics of DAAQ/CNFs electrode for Supercapacitor (슈퍼커패시터용 DAAQ/CNFs 전극의 전기화학적 특성)

  • Kim, Hong-Il;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1184-1187
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    • 2003
  • Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M $H_2SO_4$. We established Process Parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured CNFs electrodes using controlled solution chemistry. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

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