• Title/Summary/Keyword: Graphite matrix

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The Role of Inorganic Compounds Additions on the Matrix Microtexture Control of C/C Composite (무기화합물 첨가에 의한 C/C복합재료의 매트릭스 조직제어)

  • ;安田榮
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1151-1158
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    • 1997
  • Fracture of uni-directional carbon fiber reinforced carbon matrix composite is strongly dependent on the orientation of basal plane in graphite matrix when it is limited within matrix. The orientation of basal planes are vertically stacked to carbon fiber which results in the weakness for applied tensile or shear force in thermosetting resin derived-carbon matrix composite. Microtextural control of the matrix was tried through chemical interaction between metal carbides and furan resin derived-carbon matrix. SiC and TiO2 addition made the orientation disordered. However, porosity increased due to decomposition of SiC. Interfacial bonding could be controlled by TiO2 addition, but carbon fiber was considerably reacted with TiC during thermal treatment higher than 2$600^{\circ}C$. Therefore, it is desirable to control the thermal treatment temperature at which decomposition of SiC was not serious and TiC/C was not formed eutectoid.

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Effect of Ball milling Time on Graphite Dispersion and Mechanical Properties in Rapidly Solidified 6061 Al Composite (급속응고 6061Al/Graphite 복합재료의 볼밀링 시간에 따른 흑연 분산거동 및 기계적 특성)

  • Son, Hyeon-Taek;Lee, Jae-Seol;Hong, Soon-Jik;Chun, Byong-Sun
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.209-216
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    • 2009
  • A composite of rapidly solidified Al-6061 alloy powder with graphite particle reinforcements was prepared by ball milling and subsequent hot extrusion. The microstructure and mechanical properties of these composites were investigated as a function of milling time. With increasing milling time, the gas atomized initially and spherical powders became elongated with a maximum aspect ratio after milling for 30 h. Then, refinement and spheroidization were achieved by further milling to 70 h with a homogeneous and fine dispersion of graphite particles forming between the matrix alloy layers. The best compression and wear properties were obtained in the powder milled for 70 h, associated with the increased fine and homogeneous distribution of graphite particles in the aluminum alloy matrix.

Effects of Alloying Elements on the Damping Capacities and Mechanical Properties in 3.9%C Gray Cast Iron (3.9%C 회주철의 진동감쇠능 및 기계적 성질에 미치는 합금원소 첨가의 영향)

  • Kim, J.C.;Son, Y.C.;Han, D.W.;Baik, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.1
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    • pp.47-54
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    • 1997
  • Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occuring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Ni on the damping capacities and mechanical properties are investigated in 3.9%C-0.3% Cu gray cast iron. At 0.2% Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content, Graphite continuity also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite continuity. On the other hand, the damping capacity in pearlite matrix showed superior to that in ferrite. In contrast, with increasing the Ni content, both tensile strength and hardness increased due to the decrease of graphite length and eutectic cell size.

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Phenylethynyl-terminated polyimide, exfoliated graphite nanoplatelets, and the composites: an overview

  • Cho, Donghwan;Drzal, Lawrence T.
    • Carbon letters
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    • v.19
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    • pp.1-11
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    • 2016
  • In efforts to characterize and understand the properties and processing of phenylethynyl-terminated imide (LaRC PETI-5, simply referred to as PETI-5) oligomers and polymers as a high-temperature sizing material for carbon fiber-reinforced polymer matrix composites, PETI-5 imidization and thermal curing behaviors have been extensively investigated based on the phenylethynyl end-group reaction. These studies are reviewed here. In addition, the use of PETI-5 to enhance interfacial adhesion between carbon fibers and a bismaleimide (BMI) matrix, as well as the dynamic mechanical properties of carbon/BMI composites, are discussed. Reports on the thermal expansion behavior of intercalated graphite flake, and the effects of exfoliated graphite nanoplatelets (xGnP) on the properties of PETI-5 matrix composites are also reviewed. The dynamic mechanical and thermal properties and the electrical resistivity of xGnP/PETI-5 composites are characterized. The effect of liquid rubber amine-terminated poly(butadiene-co-acrylonitrile) (ATBN)-coated xGnP particles incorporated into epoxy resin on the toughness of xGnP/epoxy composites is examined in terms of its impact on Izod strength. This paper provides an extensive overview from fundamental studies on PETI-5 and xGnP, as well as applied studies on relevant composite materials.

Determination of Arsenic, Lead and Selenium in Rice Flour by Graphite Furnace Atomic Absorption Spectrometry (흑연로원자흡수분광법에 의한 쌀분말시료중의 비소, 납, 셀레늄의 정량)

  • Cho, Kyung-Haeng;Suh, Jung-Ki
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.130-135
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    • 1999
  • A graphite furnace atomic absorption spectrometry (GFAAS) with matrix modification has been used to determine trace amounts of arsenic, lead and selenium in rice flour samples. A mixed solution of palladium and magnesium nitrate was used as a matrix modifier to convert the analyte elements into a phase of higher thermostability and to increase the volatility of concomitants in graphite furnace. Matrix modification effects by the mixed solution were investigated for several elements (As, Cd, Cu, Pb, Se, Zn). It has been found that the matrix modifier substantially increase the pyrolysis and atomization temperature, and absorbance for As, Pb and Se. The concentration of As, Pb and Se in rice flour samples were determined by standard addition method with Zeeman background correction after microwave acid digestion. In this method the characteristic concentrations of As, Pb and Se are 26 ng/g, 18 ng/g, 24 ng/g on the basis of dry sample respectively.

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Study on Prevention of Galvanic Corrosion between Carbon Steel Rivets and Graphite Used in Aluminum Matrix Automobiles (알루미늄 기지 자동차에 쓰이는 탄소강 리벳과 그라파이트간의 갈바닉 부식 방지 연구)

  • Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.128-140
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    • 2017
  • Aluminum alloy matrix may be used for manufacturing lighter automobiles. However, galvanic corrosion may occur between the rivet joint combining aluminum alloy matrix and a CFRP (carbon fiber reinforced plastic) laminate. The possibility of galvanic corrosion may be investigated by measuring galvanic couple currents. Two types of galvanic current measuring methods were used. One method is to use potentiodynamic polarization curves and the other is the ZRA (zero resistance ammeter) method. For galvanic corrosion experiments graphite, a major component of CFRP, was used with carbon steel (rivets) and 6061 aluminum alloys. Regardless of carbon steel, Ni deposited carbon steel, and 316L stainless steels we also investigated the possibility of reduction in galvanic corrosion. Results revealed that even though Ni deposited carbon steel or 316L stainless rivet may slightly increase galvanic current density between those and Al matrix, substitute rivets for carbon steel may be considerably useful for reducing overall galvanic corrosion.

The Effest of Matrix of Nodular Graphite Cast Iron on Machinability in Lathe Turning - Cutting Force, Cutting Ratio and Shear Angle- (球狀黑鉛鑄鐵의 其他組織이 切削性에 미치는 영향 I)

  • 성환태;안상욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.6
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    • pp.807-813
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    • 1986
  • The orthogonal cutting method of the nodular graphite cast iron in the lathe turning, whose matrix were formulated under two kinds of annealing conditions, has been experimentally studied and the results investigated. The various characteristics of machinabilities of the nodular cast iron, depending upon its matrix, have been obtained from the results as follows. (1) As depth of cut increases, the cutting ratio and the shear angles tend to slightly increase, and as the containing quantity of ferrite matrix increases, they slightly decrease. (2) As depth of cut increases, the cutting force increases in an approximate straight line, and as the containing quantity of ferrite matrix increases, they decreases and the decreasing rate is about 20-30%. (3) As the containing quantity of ferrite matrix increases, the friction force acting on the tool face decreases and the decreasing rate is about 34-40% in case of the lower depth of cut, but in case of the higher depth of cut the decreasing rate is very small. (4) Both shearing force and vertical force show a lineal increases, and according as ferrite matrix increases there is a decrease by 25% in shearing force and a 12-25% decrease in vertical force. (5) Shearing speed and chip flow speed keep almost a constant value irrespective of matrix.

Study on the Spheroidizing Mechanism of Graphite in Cast Iron (II) (鑄鐵에 있어서의 黑鉛球狀化 機構에 關한 硏究 (Ⅱ))

  • Choi, Hyung-Sup;Park, Won-Koo
    • Journal of the Korean Chemical Society
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    • v.8 no.2
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    • pp.57-61
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    • 1964
  • It was verified at Part Ⅰ of this investigation that there is a minimum wettability between molten iron and graphite, which was preliminarily coated with magnesium, and thus the spheroidization of graphite might have resulted from the lack of wettability between magnesium-adsorbed graphite and iron matrix. Being continued from the last work, the wettability between pure iron and graphite, coated with the various thickness of cerium, are measured at melting point of pure iron in vacuum and 200 mmHg argon gas atmosphere. The result indicates the presence of a minimum wettability at a critical thickness of cerium film as was proved in the case of magnesium. The experimental analysis shows that, the minimum wettability could be attributed entirely to a minimum work of adhesion between liquid iron and graphite at a critical concentration of cerium in the iron-graphite interface.

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Properties of Mirror-surface Grinding for Metal Matrix Ceramic Composites (금속기지 세라믹 복합소재의 경면연삭 가공 특성)

  • Kwak, Tae-Soo
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.90-94
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    • 2012
  • This study has been focused on properties of mirror surface grinding technology by ELID(Electrolytic In-process Dressing) for metal matrix ceramic composites using in high precision mirror for optics. The experimental studies have been carried out to get mirror surface by grinding for composites, Al-SiC, Al-graphite and Mg-SiC. Grinding process is carried out with varying abrasive mesh type, depth of cut and feed rate using diamond wheel. The machining result of the surface roughness and condition of ground surface, have been analyzed by use of surface roughness tester and SEM measurement system. ELID grinding technology could be applied successfully for the mirror-surface manufacturing processes in spite of ductility of metal matrix material. As the results of experiments, surface roughness of Al-SiC(45 wt%) has been the most superior in these experimental work-pieces as 0.021 ${\mu}m$ Ra.

Mechanical Properties of Spheroidal Graphite Cast Iron with Duplex Matrix. (2상혼합조직(相混合組織)을 가진 구상흑연주철(球狀黑鉛鑄鐵)의 기계적성질(機械的性質)에 관한 연구(硏究))

  • Yoon, Eui-Pak;Lee, Young-Ho
    • Journal of Korea Foundry Society
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    • v.2 no.2
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    • pp.2-9
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    • 1982
  • This paper is concerned with the improvement of impact and tensile Properties of spheroidal graphite cast iron of the following duplex matricess which were heat treated in the eutectic transformation temperature range (that is, $({\alpha}+{\gamma})$ coexisting range) ; ferrite-martensite, ferrite-bainite and ferrite-pearlite. The absorbed energy and maximum load was measured by recording the load-deflection curve with instrumented Charpy impact testing machine in the temperature range from $+100^{\circ}C$ to $-196^{\circ}C$. It was found the ferrite-bainite duplex matrix showed the highest toughness among the above matrices in the room temperature and the low temperature range. Comparison of this matrix to ferrite-pearlite matrix(that is, as cast) showed a lowering of $27^{\circ}C$ in the nil-ductility transition temperature (NDT) and a lowering of $40^{\circ}C$ in the ductile-brittle transition temperature (TrE), Which seems to result from the finner dimple pattern observed using miorofractography.

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