• Title/Summary/Keyword: Granular formulation

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MULTISCALE MODELLING FOR THE FISSION GAS BEHAVIOUR IN THE TRANSURANUS CODE

  • Van Uffelen, P.;Pastore, G.;Di Marcello, V.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • v.43 no.6
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    • pp.477-488
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    • 2011
  • A formulation is proposed for modelling the process of intra-granular diffusion of fission gas during irradiation of $UO_2$ under both normal operating conditions and power transients. The concept represents a simple extension of the formulation of Speight, including an estimation of the contribution of bubble motion to fission gas diffusion. The resulting equation is formally identical to the diffusion equation adopted in most models that are based on the formulation of Speight, therefore retaining the advantages in terms of simplicity of the mathematical-numerical treatment and allowing application in integral fuel performance codes. The development of the new model proposed here relies on results obtained by means of molecular dynamics simulations as well as finite element computations. The formulation is proposed for incorporation in the TRANSURANUS fuel performance code.

Incorporation of CrusHed Sands and Tunisian Desert Sands in the Composition of Self Compacting Concretes Part I: Study of Formulation

  • Rmili, Abdelhamid;Ouezdou, Mongi Ben;Added, Mhamed;Ghorbel, Elhem
    • International Journal of Concrete Structures and Materials
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    • v.3 no.1
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    • pp.3-9
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    • 2009
  • This paper examines the incorporation of the crushed sand (CS) and desert sand (DS) in the formation of self compacting concrete (SCC). These sands have been substituted for the rolled sand (RS), which is currently the only sand used in concretes and which is likely to run out in our country. DS, which comes from the Tunisian Sahara in the south, is characterized by a tight distribution of grains size. CS, a by-product of careers containing a significant amount of fines up to 15%, is characterized by a spread out granulometry having a maximum diameter of around 5mm. These two sands are considered as aggregates for the SCC. This first part of the study consists in analyzing the influence of the type of sand on the parameters of composition of the SCC. These sands consist of several combinations of 3 sands (DS, CS and RS). The method of formulation of the adopted SCC is based on the filling of the granular void by the paste. The CS substitution to the RS made it possible, for all the proportions, to decrease the granular voids, to increase the compactness of the mixture and to decrease the water and adding fillers proportioning. These results were also obtained for a moderate substitution of DS/CS (< 40%) and a weak ratio of DS/RS (20%). For higher proportions, the addition of DS to CS or RS did not improve the physical characteristics of the SCC granular mixture.

Worker Exposure and Volatilization Pattern of Cadusafos, Ethoprophos and Probenazole after Applying Granular Type Formulation on Soil in Greenhouse (시설재배지에서 토양처리농약 Cadusafos, Ethoprophos와 Probenazole 입제 처리 후 휘산 양상과 농작업자 노출)

  • Park, Byung-Jun;Lee, Ji-Ho
    • Korean Journal of Environmental Agriculture
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    • v.30 no.2
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    • pp.160-165
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    • 2011
  • BACKGROUND: This study carried out to fate of pesticide and investigate worker exposure of pesticide in air after applying granular type pesticide formulation on soil in greenhouse for preventing farmer's pesticide intoxication. METHODS AND RESULTS: The recovery of pesticide, cadusafos, ethoprophos and probenazole on absorbent in air were ranged 80.9~121.1% in charcoal and 90.6~99.0% in XAD-4, respectively. Emission rate of in lysimeter was higher 3~5 times than that of pesticides from topsoil not added water at $35^{\circ}C$ plot after applying a mixture of granular formulation and soil. The ethoprophos concentration in air, 50 cm high from soil surface at greenhouse, was reached the highest 186.4 ${\mu}g/m^3$ within 13 hours and were ranged 17.8~186.4 ${\mu}g/m^3$ during 46 hours after applying granular formulation at dose rate 150 g a.i./245 $m^2$. The cadusafos concentration in air at greenhouse was reached the highest 37.3 ${\mu}g/m^3$ within 39 hours and were ranged 10.0~37.3 ${\mu}g/m^3$ during 46 hours after applying granular formulation at dose rate 180 g a.i./245 $m^2$. The probenazole concentration in air at greenhouse was reached the highest 1.45 ${\mu}g/m^3$ within 37 hours and were ranged 0.23~1.45 ${\mu}g/m^3$ during 46 hours after applying granular formulation at dose rate 144 g a.i./245 $m^2$. CONCLUSION(s): The result of the reentry interval study demonstrated that reentry intervals for ethoprophos and cadusafos are longer than 48 hours.

Short-term Sustained Release Formulation of KC-6620 with Porous Carrier (다공성 증량제를 이용한 KC-6620 단기용출지연입제의 제제)

  • Yu, Ju-Hyun;Park, Chang-Kyu;Lee, Byung-Hoi;Cho, Kwang-Yun
    • Korean Journal of Environmental Agriculture
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    • v.11 no.2
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    • pp.155-162
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    • 1992
  • In order to extend the releasing period of granular formulation to approximately 20 days, the KC-6620-adsorbed granules were formulated with carriers and polyethylene glycol as adjuvant. The releasing rates of active ingredient from the formulations were evaluated in aqueous medium. The baked bentonite was found most effective carrier to sustain the release of KC-6620. Due to, however, low releasing rate of active ingredient after 20 days, bentonite formulation appeared to be of no practical for the short-term sustained release of KC-6620. The increased pore volume of bentonite granular formulation by adding pyrophyllite increased remarkably the released amount of KC-6620 from bentonite-pyrophyllite(4 : 6) granule up to 85% of total active ingredient incorporated. Addition of polyethylene glycol to the bentonite-pyrophyllite granule further increased the releasing rate of KC-6620. With KC-6620 content in the bentonite-pyrophyllite(4 : 6) granule, the releasing rate of active ingredient was markedly reduced.

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Physicochemical properties of granular formulation using Paenibacillus sp. AC-1 as a microbial fungicide (미생물 살균제 Paenibacillus sp. AC-1 입제의 물리화학적 특성)

  • Oh, Kyeong-Seok;Lee, Young-Kee;Lee, Jae-Kook;Kim, Jin-Hwa
    • The Korean Journal of Pesticide Science
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    • v.9 no.3
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    • pp.262-267
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    • 2005
  • In order to commercialize Paenibacillus sp. AC-1 and to minimize its harmful side effects, four granular formulations were prepared using AC-1 powder, adjuvant, and carrier and then their physicochemical properties of the formulations were investigated. Out of the carriers tested, the best one was talc for the formulation. Viable cells was stabilized during the formulating process. Viable cells in the granules formulated with Paenibacillus sp. AC-1 powder were stabilized at storage temperature range ($4{\sim}50^{\circ}C$) after 12 weeks. The release rate of viable cells from granules into water under a static condition were eluted over 90% in 7 hours and breakdown rates of particle were 100% in 1 day. Among the tested formulations, granular formulation comprising of 20% of Paenibacillus sp. AC-1 powder, 7% of polycarboxylate as surface active agent, 1% of sodium polyacrylate as adjuvant, the rest as carrier showed to be best.

Enhancement of Biological Control of Botrytis cinerea on Cucumber by Foliar Sprays and Bed Potting Mixes of Trichoderma harzianum YC459 and Its Application on Tomato in the Greenhouse

  • Lee Sun-Kug;Sohn Hwang-Bae;Kim Geun-Gon;Chung Young-Ryun
    • The Plant Pathology Journal
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    • v.22 no.3
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    • pp.283-288
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    • 2006
  • Trichoderma harzianum YC459 (Th 459), isolated from sawdust compost, was effective in controlling cucumber and tomato gray mold caused by Botrytis cinerea under controlled and plastic film tunnel conditions. A water suspension of the wettable powder formulation of Th 459 significantly $(P\leq0.05)$ reduced the severity of cucumber gray mold by foliar spraying at all tested concentrations from $10^5\;to\;10^8$ colony forming unit (cfu)/ml in repeated experiments. The control efficacy was maintained at least seven days with the average control value of 70% in cucumber pot tests. Mixing one to eight grams of the granular formulation ($10^8cfu/g$ dry weight) of Th 459 into one liter nursery potting mix at seeding also significantly $(P\leq0.05)$ reduced the severity of cucumber gray mold by suppression of lesion formation three weeks after treatment. Application of mixing granular formulation at seeding in combination with foliar spraying during cultivation provided a more significant reduction $(P\leq0.05)$ of cucumber gray mold than granule mixing or leaf spray alone. The foliar spraying of the formulated wettable powder of Th 459 significantly $(P\leq0.05)$ reduced the infection of tomato fruits by B. cinerea as effective as the chemical fungicide, dichlofluanid, in three plastic film tunnel experiment trials. It is suggested that effective control of gray mold of cucumber and tomato can be provided by both treatment of Th 459 into potting mix and foliar spray through induction of systemic resistance and direct inhibition of the pathogen.

The Stability of BPMC(O-sec-Butylphenyl-N-Methylcarbamate) Formulations (BPMC(O-sec-Butylphenyl-N-Methylcarbamate)제(劑)의 안정성(安定性)에 관(關)한 연구(硏究))

  • Park, Hyeon-Suk;Hong, Jong-Uck
    • Applied Biological Chemistry
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    • v.21 no.1
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    • pp.31-34
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    • 1978
  • The stability of active ingredient of BPMC formulation under ultraviolet lights and sunlights was investigated using dust, emulsifiable concentrate and granular. The active ingredient of BPMC dust was more rapidly degraded by irradiation with ultraviolet lights than emulsifiable concentrate or granular tested. In the case of BPMC emulsions, the degree of degradation was increased in the order of granular, emulsifiable concentrate, dust by irradiation with ultraviolet lights. BPMC was unstable in alkaline solution and ultraviolet lights had highly significant relation to the decomposition of its active ingredient.

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Elastic-plastic Micromechanics Modeling of Cross-anisotropic Granular Soils: I. Formulation (직교 이방적 사질토의 미시역학적 탄소성 모델링: I. 정식화)

  • Jung, Young-Hoon;Chung, Choong-Ki
    • Journal of the Korean Geotechnical Society
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    • v.23 no.3
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    • pp.77-88
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    • 2007
  • A micromechanics-based model to simulate the elastic and elastic-plastic behavior of granular soils is developed. The model accounts for the fabric anisotropy represented by the statistical parameter of the spatial distribution of contact normals, the evolution of fabric anisotropy as a function of stress ratio, the continuous change of the co-ordination number relating to the void ratio, and the elastic and elastic-plastic microscopic contact stiffness. Using the experimental data for metallic materials, the elastic-plastic contact stiffness is derived as a power function of the normal contact force as well as the contact force initiating the yielding of contact bodies. To quantitatively assess microscopic model parameters, approximate solutions of cross-anisotropic elastic moduli are derived in terms of the micromechanical parameters.

Effect of Molinate Granular Formulations on Weed Control Efficacy and Growth of Rice Plants (Molinate 혼합입제(混合粒劑)의 제형별(劑型別) 살초효과(殺草效果) 및 벼의 생장(生長)에 미치는 영향(影響))

  • Pyon, J.Y.;Kim, M.H.;Oak, H.S.;Park, S.H.
    • Korean Journal of Weed Science
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    • v.7 no.3
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    • pp.316-320
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    • 1987
  • In order to determine effects of molinate mixture granular formulations on release rate and weed control efficacy of herbicides and growth of rice plants, zeolite impregnation, slurry, and sand-coating granules were tested in laboratory and greenhouse. Release rate of molinate and simetryn was faster in sand-coating granule than in zeolite impregnation and slurry type granules. Mixture granular formulations of molinate/simetryn or molinate/simetryn/MCPB showed good weed control efficacy and this trend was more remarkably shown in sand-coating granule. Sand-coating granule more inhibited growth of rice plants compared to zeolite impregnation and slurry type granules.

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Physico-chemical properties and biological activity of controlled-release granular formulations for the herbicide dicamba (방출조절형 dicamba 입제의 물리화학성 및 생물효과)

  • Oh, Kyeong-Seok;Oh, Byung-Youl;Park, Seung-Soon;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.3 no.1
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    • pp.37-45
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    • 1999
  • Dicamba (3,6-dichloro-o-anisic acid) granular formulations for controlled release (DGFCRs) were prepared with biodegradable polymers, corn starch and pregelatinized starch, to minimize harmful side effects, extend weed control performance, and control the releasing rate of the active ingredient. Physico-chemical properties and biological activity of DGFCRs were studied. Six different granules were formulated by applying two processes, granulation and extrusion. Formulation efficiencies of active ingredient (A.I.) in the granules prepared by granulating and extruding were $90.0{\sim}96.3%$. Incorporation ratios of A.I. in the granules prepared by granulating and extruding showed $89.5{\sim}94.5%$ and $46.7{\sim}82.0%$, respectively. The highest swellability was DG-2 formulation prepared with corn starch. Whereas, the lowest floatability in water was DG-2 formulation, while the highest one was DG-1 formulation prepared with pregelatinized starch, Miragel 463. The degradation rates of dicamba in the granules under the elevated temperature of $50^{\circ}C$ were less than 5% for DG-1 and DG-2 formulations even after 90 days, meanwhile, those of DE-1 formulations prepared with pregelatinized starch, Mirasperse, were more than 5%. The release rates of A.I. from the granules into water under a static condition were about 100% after 2 weeks. Weeding effects of the granules on broad leaf weeds tested in greenhouse were more than 90% after 30 days.

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