• Journal of Korean Society of Environmental Engineers
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• v.22 no.2
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• pp.217-229
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• 2000

Adsorption equilibrium experiments for the phenol on granular activated carbon(16~25 mesh) and powder activated carbon(325 mesh) were carried out at $25{\pm}1^{\circ}C$ and the results were expressed with Freundlich isotherm. Adsorption rate experiments were executed in batch adsorption system under the condition that can be neglecting mass transfer resistance at the external surface of the particle. The results were analysed with the Miller's method to evaluate the linear driving force(LDF) adsorption rate constant. Fixed bed adsorption experiments were performed by adopting different flow rates in the activated carbon-phenol system at $25{\pm}1^{\circ}C$. The theoretical breakthrough curves were estimated with the simple constant pattern solution. The adsorption rate constant of LDF model was not a fixed value but variable with adsorption amount. The experimental results were better agreed with the estimation of breakthrough curve using the variable adsorption rate constant than the results estimated using the average fixed adsorption rate constant.

• Journal of the Korean Geosynthetics Society
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• v.15 no.3
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• pp.27-37
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• 2016

Although many studies on the Granular Compaction Pile (GCP) have been done by many researchers, the GCP design has not been systematically done due to the absence of the rational design methodology. As the GCP design has been mostly done by engineers' own experiences, some failure cases have been reported to occur. For this reason, it is very difficult to confirm definite causes of the failure and establish the prevention plans for the failure. Therefore, this study aims to investigate the optimal mixing ratio of gravel and sand, the effects of the internal friction angle of the GCP on the stress concentration ratio and the vertical and horizontal settlements. In order to analyze the behavior of the soft ground reinforced with the GCP depending on the different design parameters such as the stress concentration ratio and the internal friction angle, a number of finite element (FE) analyses were performed. From the direct shear test, the optimal mixing ratio of gravel to sand was found to be 70:30. Based on the numerical analyses, as the internal friction angle increased, the stress concentration ratio increased and it converged to a constant value. In addition, the larger the internal friction angle, the smaller the settlements. Consequently, the use of the optimal mixing ratio of gravel and sand can lead to reducing both the lateral flow and the heaving phenomenon.

• KSBB Journal
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• v.16 no.3
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• pp.286-289
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• 2001

A beterotrophic Pseudomonas putida B2 was used to treat of hydrogen sulfide containing gas. The experimental approach involved operating two indentical bench-scale biofilters with media consisting of a mixture of peatmoss, perlite and granular activated carbon(GAC). One column was seeded with Pseudomonas putida B2 and the other was left unseeded. The biofilter was operated for 16 days under EBRT for 20-40 sec, at a temperature of 25-30$^{\circ}C$ and a hydrogen sulfide concentration of 40-190 ppm. The biofilter inocculated with P.putida B2 exhibited high hydrogen sulfide removal efficiency, average of 95%, at a gydrogen sulfide concentration of 40-190 ppm (flow rate 3.6 L/min). However, at a shock loading of 190 ppm the biofiter showed a removal efficiency of 78.9% and the control only showed a removal efficiency of 31.6%. The critical load of this biofilter was 14.83 g/㎥hr, and the critical load of the control column was 4.93 g/㎥hr. These results suggest that P. putida B2 has the potential to be used as a $H_2S$ removal agent in a biofilter.

• Journal of Navigation and Port Research
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• v.38 no.3
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• pp.239-246
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• 2014

A study on the elution characteristics of biostimulating agents (sulfate and nitrate) from biostimulants which are used for in-situ bioremediation for the coastal sediment contaminated with organic matter was performed. The biostimulating agents were mixed with the coastal sediment, and then massed the mixture into ball. Two kinds of ball type biostimulant were prepared by coating the ball surface with two different polymers, cellulose acetate and polysulfone. A granular type biostimulant (GTB) was also prepared by impregnating a granular activated carbon in the biostimulating agent solution. The image of scanning electron microscopy for the biostimulant coated with cellulose acetate (CAB) showed that the inner side of the coating layer consisted of irregular and bigger size of pores, and the surface layer had tight structure like beehive. For the biostimulant coated with polyfulfone (PSB), the whole coating layer had a fine structure without pore. The elution rate of the biostimulating agents for the CAB was higher than that for the PSB, and the elution rate for the GTB was considerably higher than that for the PSB in distilled water as well as in sea water. The elution rate of the biostimulating agents in turbulent water flow was about 3 times higher than that in standing water, and the elution rate of nitrate was higher than that of sulfate from the stimulating agents.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.11-31
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• 1999

Removal of hexavalent chromium from artificial groundwater (AGW) by granular activated carbon (GAC) was investigated in batch and continuous-flow column studies. Experimental parameters that were examined included solution pH, presence of dissolved oxygen (DO), and GAC pretreatment with Fe(II). As the solution pH increased from 4 to 7.5, the amount of Cr(VI) removed by both GACs decreased significantly. Exclusion of DO from the experimental systems resulted in greater removal of Cr(VI) from solution, possibly as a result of reduction to Cr(III). However, pretreatment of the GAC with a reductant (Fe(II)) did not improve Cr(VI) removal. Equilibration With 0.01 M $K_2$$HPO_4$[to extract adsorbed Cr(VI)] followed by a wash with 0.02 N $K_2$$HPO_4$[to remove precipitated/sorbed Cr(III)] proved to be a viable approach for the regeneration of carbons whose Cr(VI) removal capacities had been exhausted. The performance of the regenerated carbons exceeded that of the virgin carbons, primarily because of the favorable adsorption of Cr(VI) at lower pH values and the reduction of Cr(VI) to Cr(III), The presence of Cr(III) in acid wash solutions provides direct evidence that Cr(VI) is reduced to Cr(III) in GAC systems under relatively acidic conditions. GAC performance over five complete cycles was consistently high, which suggests that such a system will be able to function over many operation cycles without deleterious effects.

• Journal of the Korean Geosynthetics Society
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• v.9 no.1
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• pp.47-57
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• 2010

Granular soils having a large particle size have been used as a filling material in the construction of foundation, harbor, dam, and so on. Consequently, the shear behavior of this granular soil plays a key role in respect of stability of structures. For example, soil particle crushing occurring at the interface between structure and soil and/or within soil mass can cause a disturbance of ground characteristics and consequently induce issues in respect of stability of structures. In order to investigate the shear behavior according to an existence and nonexistence of particle crushing, numerical analyses were conducted by using the DEM (Discrete Element Method)-based software program PFC2D (Particle Flow Code). By dividing soil particle bonding model into crushing model and noncrushing model, total four particle bonding models were simulated and their results were compared. Noncrushing model included one ball model and clump model, and crushing model included cluster model and Lobo-crushing model. The combinations of soil particle followed the research results of Lobo-Guerrero and Vallejo (2005) which were composed of eight circles. The results showed that the friction angle was in order of clump model > cluster model > one ball model. The particle bonding model compared to one ball model and noncrushing model compared to crushing model showed higher shear strength. It was also concluded that the model suggested by Lobo-Guerrero and Vallejo (2005) is not appropriate to simulate the soil particle crushing.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.6C
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• pp.267-274
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• 2012

The conventional approach to evaluate the contaminant transport in soils adopts the macro-scale implementation while the pore configuration and network is a dominant factor to determine the fate of contaminant. However, the observation of fate and transport at pore scale may not be readily approachable because of the computational expenses to solve Navier-Stokes equation. We herein present the 2D Lattice-Boltzmann method that enables to assess the local fluid velocity and density efficiently for the case of single phase and multi-components. The solute fate spatio-temperal space is explicitly determined by the advection of fluid flow. Two different types of idealized pore space provides the path of fluid. Also, solute transport, the velocity field and average concentration of solute are computed in steady state. Results show that the pore geometry such as tortuosity mainly affect the solute fate. It highlights the significance of the pore configuration and shape in granular soils and rock discontinuity in spite of the equivalent porosity.

• Journal of the Korean Geotechnical Society
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• v.30 no.2
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• pp.33-42
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• 2014

The shear strength and deformation characteristics of granular soils at low confining stresses differ from those with high confining stresses. Thus, the clear understanding of geotechnical problems related to the low confining stress state such as the stability of shallow foundations, embankments, slope failure, debris flow characteristics and liquefaction as well as the various laboratory model tests is needed. In this study, drained triaxial compression tests with the cell pressures from 5 kPa to 300 kPa were performed on dry Jumunjin sand. The results show that the internal friction angle and deformation modulus are dependent on the confining stress. Also, the correlations between them on the dense and loose sand were established.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.3
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• pp.265-276
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• 2007

The primary objective of this study is to investigate the effect of media on the performance of biofilters. Two types of experiments were carried out in this study. The first type of experiment used a biofilter with the media composed of three different packing materials of compost, peatmoss and GAC(granular activated carbon), whereas the second type used a biofilter with the media composed of compost only. It was found from the two experiments that the biofilter composed of compost, peatmoss and GAC showed better performance than the one composed of compost only with the higher toluene removal efficiency, lower pressure drop, and more uniform media moisture content. In particular, no appreciable media compression occurred for the biofilter composed of compost, peatmoss and GAC, whereas significant media compression took place in the biofilter composed of compost only. As suggested by the other researchers, it is likely that GAC may be responsible for the higher toluene removal efficiency in the case of the biofilter composed of mixed media especially for the early stage of biofiltration due to its adsorption capability of toluene of such high concentration as 300 ppm. It was also regarded that GAC may playa major role in maintaining lower media pressure drop in the case of the mixed media than the media with compost only because of its mechanical strength resisting to the compression. Nonetheless, further refined experiments may need to draw more accurate conclusion. The results of the additional test run using the same mixed media showed that the biofilter system using the mixed media can be consistently operated for more than 100 days very stably despite sudden change in operating conditions of temperature and flow rate.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.131-134
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• 2000

Increased temperature adversely affects the reliability of a device. So, package material should have high thermal diffusion, i.e., high thermal conductivity. And, there are several other physical properties of polymeric materials that are important to microelectronics packaging, some of which are a low dielectric constant, a low coefficient of thermal expansion (CTE), and a high flexural strength. In this study, to get practical maximum packing fraction of AIN (granular type) filled EMC, the properties such as the spiral flow, thermal conductivity, CTE, and water resistance of AIN-filled EMC (65-vol%) were evaluated according to the size of AIN and the filler-size distribution. Also, physical properties of AIN filled EMC above 65-vol% were evaluated according to increasing AIN content at the point of maximum packing fraction (highly loading condition). The high loading conditions of EMC were set $D_L/D_S$=12 and $X_S$=0.25 like as filler of sphere shape and the AIN filled EMC in this conditions can be obtained satisfactory fluidity up to 70-vol%. As a result, the AIN filled EMC (70-vol%) at high loading condition showed improved thermal conductivity (about 6 W/m-K), dielectric constant (2.0~3.0), CTE(less than 14 ppm/$^{\circ}C$) and water resistance. So, the AIN filled EMC (70-vol%) at high loading condition meets the requirement fur advanced microelectronic packaging materials.