• Title/Summary/Keyword: Grain structure

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Preparation of Gas Sensors with Nanostructured SnO2 Thick Films with Different Pd Doping Concetrations by an Ink Dropping Method

  • Yoon, Hee Soo;Kim, Jun Hyung;Kim, Hyun Jong;Lee, Ho Nyun;Lee, Hee Chul
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.243-248
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    • 2017
  • Pd-doped $SnO_2$ thick film with a pure tetragonal phase was prepared on patterned Pt electrodes by an ink dropping method. Nanostructured $SnO_2$ powder with a diameter of 10 nm was obtained by a modified hydrazine method. Then the ink solution was fabricated by mixing water, glycerol, bicine and the Pd-doped $SnO_2$ powder. When the Pd doping concentration was increased, the grain size of the Pd-doped $SnO_2$ thick film became smaller. However, an agglomerated and extruded surface morphology was observed for the films with Pd addition over 4 wt%. The orthorhombic phase disappeared even at a low Pd doping concentration and a PdO peak was obtained for a high Pd doping concentration. The crack-free Pd-doped $SnO_2$ thick films were able to successfully fill the $30{\mu}m$ gap of the patterned Pt electrodes by the optimized ink dropping method. The prepared 3 wt% Pd-doped $SnO_2$ thick films showed monoxide gas responses ($R_{air}/R_{CO}$) of 4.0 and 35.6 for 100 and 5000 ppm, respectively.

Structural and Electrical Properties of Co-evaporated Cu(In1-x,Gax)Se2 Thin Film Solar Cells with Varied Ga Content (Ga 함유량에 따른 Co-evaporation 방법에 의해 제조된 Cu(In1-x,Gax)Se2 박막 태양전지의 구조 및 전기적 특성)

  • Lim, Jong-Youb;Lee, Yong-Koo;Park, Jong-Bum;Kim, Min-Young;Yang, Kea-Joon;Lim, Dong-Gun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.9
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    • pp.755-759
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    • 2011
  • $Cu(In_{1-x},Ga_x)Se_2$ thin films have been considered as an effective absorber material for high efficient solar cells. In this paper, the CIGS thin films with varied Ga content were prepared using a co-evaporation process of three stage. We carry out structure and electrical optical property on the thin film in varied Ga content. CIGS thin films have been characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), energy-dispersive spectroscopy(EDS), four-point probe measurement, and the Hall measurement. To optimize Ga contents, Ga/(In+Ga) ratio were changed from 0.13 to 0.72. At this time the carrier concentrations were varied from $1.22{\times}10^{11}\;cm^{-3}$ to $5.07{\times}10^{16}\;cm^{-3}$, and electrical resistivity were varied from $1.11{\times}10^0\;{\Omega}-cm$ to $1.08{\times}10^2\;{\Omega}-cm$. A strong <220/204> orientation and a lager grain size were obtained at a Ga/(In+Ga) of 0.3. We were able to achieve conversion efficiency as high as 15.95% with a Ga/(In+Ga) of 0.3.

Characterization of structural and field emissive properties of CNTs grown by ICP-CVD method as a function of Ni and Co catalysts thickness (ICP-CVD 방법에 의해 성장된 탄소나노튜브의 Ni 및 Co 촉매 두께에 따른 구조적 물성 및 전계 방출 특성 분석)

  • Kim, Jong-Pil;Kim, Young-Do;Park, Chong-Kyun;Uhm, Hyun-Seok;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1574-1576
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    • 2003
  • Carbon nanotubes (CNTs) were grown on the TiN-coated silicon substrate with different thickness of Ni and Co catalysts layer at $600^{\circ}C$ using inductively coupled plasma-chemical vapor deposition (ICP-CVD). The Ni and Co catalysts were formed using the RF magnetron sputtering system with various deposition times. It was found that the growth of CNTs was strongly influenced by the surface morphology of Ni and Co catalysts. With increasing deposition time, the thickness of catalysts increased and the grain boundary size of catalysts increased. The surface morphology of catalysts and CNTs were elucidated by SEM. The Raman spectrum further confirmed the graphitic structure of the CNTs. The turn-on field of CNTs grown on Ni and Co catalysts was about 2.7V/pm and 1.9V/pm respectively. Field emission current density of CNTs grown on Ni and Co catalysts was measured as $11.67mA/cm^2$ at $5.5V/{\mu}m$ and $1.5mA/cm^2$ at $5.5V/{\mu}m$ respectively.

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Dielectric Properties of K(Ta0.6Nb0.4)O3 Thin Films Prepared by Sol-Gel Method for Microwave Applications (마이크로웨이브 응용을 위한 솔-젤법으로 제작한 K(Ta0.6Nb0.4)O3 박막의 유전 특성)

  • Kwon, Min-Su;Lee, Sung-Gap;Kim, Kyeong-Min;Lee, Sam-Haeng;Kim, Young-Gon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.403-407
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    • 2018
  • In this study, double layer KTN/STO thin films were fabricated on $Pt/Ti/SiO_2/Si$ substrate, their structural and electrical properties were measured according with the number of STO coatings, and their applicability to microwave materials was investigated. The average grain size was about 80~90 nm, the average thickness of the 6-coated KTN thin film was about 320 nm, and the average thickness of the STO thin film coated once was about 45~50 nm. The dielectric constant decreased with increasing frequency, and as the number of STO coatings increased, the rate of change of the dielectric constant with the applied electric field decreased. The tunability of the KTN thin film showed a maximum value of 19.8% at 3 V. The figure of merit of the KTN/1STO thin film was 9.8 at 3 V.

Study of the organic characteristics between Korean traditional aesthetic of architecture and the natural beauty being intrinsic in traditional furniture (한국 전통건축미(美)와 전통가구에 내재된 자연미(美)의 유기적 특징 연구)

  • Rim, Kwang-Soon
    • Journal of the Korea Furniture Society
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    • v.20 no.5
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    • pp.504-516
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    • 2009
  • Korean traditional architecture has been carried out in the manner that it harmonized surrounding natural environments and never disturbed them in the scale which did not overwhelm the nature, based on the view of architecture predicated on Yin Yang School. The exposed grain of the wood like pillar, hinge and house rafte, the linear expression of the construction material and the formation between the window and door monopolizing the front side presented a harmony with the nature showing the linear structure. Furthermore the ceiling is low due to the sit life style thanks to the ondol (Korean under-floor heating system and the furniture was made in simple manner to utilize the space as large as possible, for the interior was narrow and close, and also the furniture placing in the middle of the room was movably manufactured to improve the room space. Like this Korean traditional furniture was close associated with the low height and simplicity and harmonized with the blank of the wall accordingly, and it characterized linear & planar natural beauty focusing on the simple and refined unique beauty, because it was made in a good harmony with the interior utensils. This study has presented that the organic characteristics of Korean traditional aesthetic of architecture and the natural beauty being intrinsic in traditional furniture have a mutual relation on the basis of not only the visual recognition, also the aesthetic of naturalism made of the natural material, the constructional naivety as a frame method and the linear & planar formative beauty shown in appearance.

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Assessment of benthic environment conditions of oyster and mussel farms based on macrobenthos in Jinhae bay (저서생물상을 이용한 진해만 수하식 양식장의 저서환경 평가)

  • Park Heung-Sik;Yi Soon-Kil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.1
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    • pp.68-75
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    • 2002
  • This study were observed to the conditions of organic pollution applying to tile environmental assessments based on macrobenthos around the raft culture ground which became an issue by organic matter input in Jinhae Bay. Three stations, mussel farm, oyster farm and the control station on which rarely culture activities were fixed and have analyzed to the sediment characteristics and macrobenthic communities. Muddy substrates between 6.0 and 6.60 on mean grain size have prevailed to the bottom layer in all stations. The highest organic matter content of 2.8% was observed to the mussel farm while the lowest one of 1.5% was recorded on the control area. As a total, 79 species from seven phyla were identified. Comparing to shell farms, the control station have composed to more diversified community structure. In the mussel and the oyster farm, opportunistic species, living in high organic contents area, Lumbrineris longifolia, Heteromastus. filiformis in polychaetes and Corophium sinense in amphipod were dominated. As results on environmental assessment, in spite of changing to the species composition and densities seasonally, the mussel farm have recorded only to moderately polluted condition.

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진해만 안골 바지락 양식장 대형저서동물 군집의 구조

  • Park Yeong Min;Yun Byeong Seon;Kim Gu Hwan;Yun Seong Gyu
    • Proceedings of the Korea Society of Environmental Biology Conference
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    • 2003.11a
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    • pp.92-97
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    • 2003
  • Community structure of macrobenthos was studied on Angol clam farming ground of Chinhae Bay in the southern coast of Korea. Macrobenthos samples were collected monthly using a quadrate at each station from March 1998. Macrobenthos samples were seived by 1.0mm mesh seive. Mean grain size was 0.267 mm. A total of 111 macrobenthos species were sampled with a mean density of 1,651ind/m$^2$and biomass of 1466.7wwt.g/m$^2$. Annelida was density-dominant faunal group with a mean density of 818ind/m$^2$, comprising of 49.6% of the total density of the macrobenthos. It was followed by Mollusca with 660ind/m$^2$(40.0%). Mollusca was biomass-dominant faunal group. Major dominant species in the number of individual were Ruditapes philippinarum (375ind/m$^2$), Batillaria cumingi (208ind/m$^2$), Cirrformia tentaculata (167ind/m$^2$), Ceratonereis erithraeensis (151ind/m$^2$), Capitella capitata (111ind/m$^2$) and Sigambra tentaculata (91ind/m$^2$). Major dominant species in the biomass were Ruditapes philippinarum (1156.6wwt.g/m$^2$), Batillaria cumingi (111.0wwt.g/m$^2$) and Cyclina sinenis (106.2wwt.g/m$^2$). The species diversity was increased gradually during the study period. Increasing of species diversity was due to not only increasing of number of species but also decreasing of dominance of some polycheates. Contents of silt-clay was increased gradually in the intertidal zone.

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The Effect of Temperature on Tensile Properties in Conventionally Cast Ni-based Superalloy CM247LC (다결정 니켈기 초내열 합금 CM247LC의 온도에 따른 인장특성 변화)

  • Choi, Baig-Gyu;Kim, In Soo;Do, Jeonghyeon;Jung, Joong Eun;Seok, Woo-Young;Lee, Yu-Hwa
    • Journal of Korea Foundry Society
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    • v.40 no.4
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    • pp.118-127
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    • 2020
  • Microstructural evolution during a heat treatment and high-temperature tensile properties have been investigated in conventionally cast CM247LC. In as-cast specimens, MC carbides with high amounts of Ta, Ti, Hf, and W were found to exist in the interdendritic regions, and γ' was observed in the form of cubes and octocubes prior to decomposition into cubes. In the heat-treated condition, some portion of eutectic γ-γ' remained, and uniform cubic γ' was observed in both interdendritic regions and dendrite core. Three types of carbides with different stoichiometries and compositions were found at the grain boundaries. MC carbides with high Hf contents were observed in the vicinity of eutectic γ-γ'. The highest tensile strength value was found at 750℃, whereas the greatest ductility appeared at 649℃. The effect of the temperature on the tensile properties was closely related to the dislocation structure. With increase in the test temperature, the density of dislocations inside γ' decreased, whereas that in the γ matrix increased. Stacking faults generated in γ' at 750℃ had a strengthening effect, whereas thermally activated dislocation motion at a high temperature was considered to have the opposite effect.

Properties of $CuInS_2$ thin film Solar Cell Fabricated by Electron beam Evaporator (전자빔 증착기로 제작한 태양전지용 $CuInS_2$ 박막특성)

  • Yang, Hyeon-Hun;Kim, Young-Jun;Jeong, Woon-Jo;Park, Joung-Yun;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.379-380
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    • 2005
  • Single phase $CuInS_2$ thin film with a highest diffraction peak (112) at a diffraction angle ($2\Theta$) of $27.7^{\circ}$ was well made by SEL method at annealing temperature of $250^{\circ}C$ and annealing hour of 60 min in vacuum of $10^{-3}$ Torr or in S ambience for an hour. And the peak of diffraction intensity at miller index (112) of $CuInS_2$ thin film annealed in S ambience was shown a little higher about 11 % than in only vacuum. Single phase $CuInS_2$ thin films were appeared from 0.85 to 1.26 of Cu/In composition ratio and sulfur composition ratios of $CuInS_2$ thin films fabricated in S ambience were all over 50 atom%. Also when $CuInS_2$ composition ratio was 1.03, $CuInS_2$ thin film with chalcopyrite structure had the highest XRD peak (112). The largest lattice constant of a and grain size of $CuInS_2$ thin film in S ambience was 5.63 ${\AA}$ and 1.2 ${\mu}m$ respectively. And the films in S ambience were all p-conduction type with resistivities of around $10^{-1}{\Omega}cm$.

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Ferroelectric properties of $Y_2O_3$ and $MnO_2$ doped $SrBi_2Nb_2O_9$ ceramics ($Y_2O_3$$MnO_2$를 첨가한 $SrBi_2Nb_2O_9$ 세라믹스의 강유전 특성)

  • Suk, Jong-Min;Lee, Yong-Hyun;Noh, Jong-Ho;Cho, Jeong-Ho;Chun, Myoung-Pyo;Kim, Byung-Ik;Ko, Tae-Gyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.346-347
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    • 2006
  • 기계적 품질계수(Qm)를 향상시키기 위해 $Y_2O_3$$MnO_2$를 첨가함에 따른 $SrBi_2Nb_2O_9$ 세라믹스의 강유전 특성을 알아보았다. 합성분말의 입도를 분석 한 결과 $SrBi_2Nb_2O_9$의 경우 781.27nm였고, $Y_2O_3$$MnO_2$를 첨가한 경우 각 각 830.4nm와 981.1nm로 particle size는 증가하였고, 소결 후 소결밀도는 차이가 거의 없었으며, grain size는 $SrBi_2Nb_2O_9$$Y_2O_3$를 첨가했을 경우 $1{\mu}m$이하이며 반면, $MnO_2$를 첨가하였을 때 결정립이 성장하여 $3{\sim}4{\mu}m$로 나타났다. 또한, 모두가 $450^{\circ}C$ 이상의 상전이온도를 갖았다.

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