• Journal of Korea Foundry Society
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• v.23 no.2
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• pp.77-85
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• 2003

Some alloying elements such as Cr, B, Ti and Si were added individually or as a mixture to Fe-30 at.%Al alloys. The alloys were melted using an arc furnace and then heat-treated for homogenization at 1000$^{\circ}C$ for 7 days and followed by rolling at 1000$^{\circ}C$. The alloying elements on rolling characteristics were investigated by the microstructures and fracture mode before and after rolling. The microstructures before rolling showed that all of the alloys had equiaxed grains. On the other hand, the microstructures of rolling plane as well as its perpendicular plane became elongated after rolling. The alloys such as Fe-30Al, Fe-30Al-3Ti, Fe-30Al-0.5B, Fe-30Al-5Cr and Fe-30Al-3Ti-0.5B revealed better rolling behaviour from the point that intergranular and cleavage fractures were not fundamentally occurred. But the addition of 5Ti or 3Si to Fe-Al alloys had detrimental effects. The Ti-added alloy system such as Fe-30Al-5Ti, Fe-30Al-5Ti-5Cr, Fe-30Al-3Ti-5Cr and Fe-30Al-5Ti-0.5B were cracked through grain and showed cleavage fracture. The Si-added alloy system such as Fe-30Al-5Si, Fe-27Al-3Si and Fe-27Al-5Cr-3Si were cracked along the grain boundary and showed intergranular fracture. $DO_3{\leftrightarrow}B_2$ transition temperature of Fe-30at.%Al alloy was 520$^{\circ}C$, whereas the addition of 3Ti and 3Ti+0.5B comparably increased the temperature to 797 and 773$^{\circ}C$, respectively.

• Proceedings of the KWS Conference
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• 2006.05a
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• pp.140-142
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• 2006

The bend ductility of Type 410S ferritic stainless steel overlay weld on carbon steel was investigated. Overlay weld that was stabilized with Nb had large columnar ferrite grain and Nb precipitate on grain boundary. And that caused fracture when bend test without concern of PWHT condition. Proper bend ductility at as-welded condition was achieved by refining ferrite grain with addition of $0.04{\sim}0.09%$ Al and $0.2{\sim}0.5%$ Ti that make oxide, carbide and nitride at high temperature.

• Journal of the Korean Ceramic Society
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• v.22 no.5
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• pp.76-84
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• 1985

Mechanical property enhancing mechanisms of $Al_2O_3-ZrO_2$ two phase ceramic composites were studied for several compositions of different $ZrO_2$/$Al_2O_3$ ratio. Microstructural analysis of $Al_2O_3-ZrO_3$(pure) composites indicated that pre-existing microcrack due to larger $ZrO_2$ particle at grain boundary extended along alumina grain boundaries within process zone. Microcracks also nucleated when very small $ZrO_2$ particles at the grain boundaries transformed to monoclinic phase at near of main crack tip. These types of microcracks could contribute to the toughening achieved by creating additional crack surface area during crack propagation. Microstructural analyses also showed that the average grain size and abnormal grain size of $Al_2O_3$ were decreased with increasing $ZrO_2$ vol% in $Al_2O_3$ matrix. As a result it could be concluded as follows In TEX>$Al_2O_3-ZrO_3$(pure) system 1. Microcrack nucleation (stress-induced microcracking) and extension was effective mechanism for absorpiton of fracture energy 2, More narrow distribution and smaller grain size of $Al_2O_3$ due to $ZrO_2$particles mainly contributed to main-tatin the strength and hardness.

• Korean Journal of Materials Research
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• v.9 no.8
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• pp.768-774
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• 1999

Yttia-doped ceria-stabilized ziconia polycrystals(Ce-TZP) was prepared by dipping method and its microstructure was investigated. By controlling doped-yttria content and annealing condition, yttria-doped Ce-TZP showed the microstructure with irregular grain shape and undulated grain boundary. Irregularity of grain shape increased with the amount of yttria doped, and severe undulated grain boundary was observed mainly at the surface region. In the case of yttria-doped Ce-TZP annealed at 1$650^{\circ}C$ for 2h after two dipping times into yttrium nitrate solution of 0.2M, it showed irregular grain shape both at the surface and at the interior region as well as the most severe irregularity. Hot pressed specimen had mean grain size of 0.3$\mu\textrm{m}$ and undulated grain boundary. All specimens with irregular grain shape were retained the tetragonal phase. The fracture toughness of yttria-doped Ce-TZP with irregular grain shape was over the value of 17.6MPa.m(sup)1/2.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.2
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• pp.97-103
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• 1984

Post weld heat treatment(PWHT) of weldment of the low alloy steel is carried out to remove residual stress existing in weldment and to improve fracture toughness, but it is often observed that there occurs grain boundary failure and that fracture toughness decreases in weld heat affected zone(HAZ)because of PWHT. In this paper, the effect of heating rate and holding time of PWHT on fracture toughness were evaluated by crack opening displacement (CDD)test and micro-hardness test under the constant stress simulated residual stress in HAZ of Cr-Mo steel. The experimental results are as follow; (1)Transition temperature of weld HAZ after PWHT was dependent upon heating rate greater than holding time, and fracture toughness was decreased with an increase of the heating rate. (2)Softening ration of the notch tip was increased with holding time within one hour and saturated after one hour, but under applied stress it was increasing continuously. (3)The average hardness value in weld HAZ was increased with heating rate of PWHT.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.15 no.1
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• pp.16-20
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• 2005

In order to improve electrical conductivity and mechanical properties of 8YSZ SOFC electrolyte material, we used Al₂O₃ as an additive and applied the spark plasma sintering (SPS) method. The sintered bodies were densified above 96 ％ of theoretical density at 1200℃ and possessed microstructures composed of homogeneous grains less than 1 ㎛ in size. The addition of Al₂O₃ improved fracture toughness and bending strength by inhibiting grain growth of 8YSZ and increased total ionic conductivity because grain interior conductivity appeared to remain constant and grain boundary conductivity increased. It was assumed that the dissolution of Al₂O₃ into 8YSZ which was inevitable problem at commercial sintering method was effectively prohibited by the SPS technique with a relatively low sintering temperature and the reaction between Al₂O₃ and SiO₂ present at grain boundary to produce the crystalline Al/sub 2-x/Si/sub l-y/O/sub 5/ phase, resulting in the increase of grain boundary conductivity.

• Journal of Korea Foundry Society
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• v.10 no.2
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• pp.144-153
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• 1990

Ductile cast iron has good ductility and toughness, for the graphite morphology is spheroidal. It has been reported that the strengthening and toughening of the ductile cast iron was resulted from the modification of matrix structure by the heat treatment or the addition of alloying elements. In this study, effects of various special heat treatments (cyclic heat treatment and intermediate heat treatment) and Ni addition on the toughness and strength of the austempered ductile cast iron were studied. The results obtained from this study were as follows : 1. The amount of fine pearlite was increased with the Ni content and the number of cycle in cyclic heat treatment. 2. When the specimens treated and not by special heat treatment at 820 was austempered, in the former the austenite was formed on grain boundary entirely, but in the latter on grain boundary partially. 3. The impact energy was decreased with the Ni content, because the coarisen austenite pools formed with the Ni content was transformed into martensite during quenching. 4. The mechanical properties of austempered ductile cast iron containing 2%Ni treated cyclic heat treatment(5 cycles)was very excellent in handness 99(HRB), impact energy 12(kg-m) maximum fracture load 1500(kg-f).

• Journal of Welding and Joining
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• v.28 no.2
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• pp.79-83
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• 2010

In this study, newly developed welding consumables for EGW were welded in EH 36 TM steel plates and their welded joints were evaluated in point of mechanical properties and microstructures compared with imported consumables. Newly developed welding consumables were evaluated as good arc stability and slag fluidity, substantially the same with imported products. The tensile strength of all welded joints were sufficient to meet the requirements specified in a ship’s classification(490~640MPa) and all areas of fracture were heat affected zone(HAZ). Charpy absorbed energy values of all EG welded metals were sufficient to meet the requirements of classification(min. 34J) and those of newly developed wires were evaluated to be better than those of imported wires. As a result observing microstructures of single and tandem EG welded metals through optical and scanning electron microscope (OM&SEM), no grain boundary ferrite(PF(G)) were created in a prior austenite grain boundary and a volume fraction of a fine acicular ferrite were observed very high.

• Korean Journal of Materials Research
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• v.17 no.4
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• pp.192-197
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• 2007

The effects of immersion time in the liquid nitrogen on the behavior of aluminum alloys used for the hydrogen storage tank of auto-mobile at cryogenic temperature were investigated. With increasing immersion time in the liquid nitrogen, the elongation of AI 5083 alloy at cryogenic temperature decreased because of non-uniform fracture of precipitates on the grain boundary, and the serration also occurred because of discontinuous slip due to rapid decreasing of the specific heat. The mechanical properties of AI 6061 alloy at cryogenic temperature were characterized by uniformed yield strength, tensile strength and elongation regardless of the immersion time in the liquid nitrogen. These mechanical properties of aluminum alloys at cryogenic temperature were interpreted by the strength of grain boundary and the slip deformation behavior.

• Journal of Welding and Joining
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• v.22 no.3
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• pp.69-76
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• 2004

Effects of friction stir welding parameters such as tool rotation speed and welding speed on the joints properties of 5052 Al alloys were studied in this study. A wide range of friction stir welding conditions could be applied to join 5052 AA alloy without defects in the weld zone except for certain welding conditions with a lower heat input. Microstructures near the weld zone showed general weld structures such as stir zone (SZ), thermo-mechanically affected zone (TMAZ) and heat affected zone (HAZ). Each zone showed the dynamically recrystallized grain, transient grain and structure similar to base metal's, respectively. Hardness distribution near the weld zone represented a similar value of the base metal under wide welding conditions. However, in case of 800 rpm of tool rotation speed, hardness of the stir zone had a higher value due to the fine grain with lots of dislocation tangle, a higher angle grain boundary and some of Al3Fe particles. Except joints with weld defects, tensile strength and elongation of the joints had values similar to the base metal values and fracture always occurred in the regions approximately 5mm away from the weld center.