• Title/Summary/Keyword: Grafting

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MODIFICATION OF OIL PALM EMPTY FRUIT BUNCH FIBER BY GRAFT COPOLYMERIZATION

  • Wan Yunus Wan Md Zin;Ibrahim NorAzowa;Rahman Mohd Zaki Ab.;Ahmad Mansor B.;M. Dahlan Khairul Zaman
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.358-358
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    • 2006
  • The graft copolymerization of methyl methacrylate (MMA), butyl acrylate (BA) and acrylamide (AAm) onto oil palm empty fruit bunch (OPEFB) fiber were successfully carried out in aqueous solution using $H_{2}O_{2}/Fe^{2+}$ as initiator. For all monomers the percentage of grafting increases with the amount of monomer and can be controlled by setting the appropriate reaction conditions. The optimum reaction period were found to be 120 minutes for all monomers whereas the optimum temperature and the amount of initiator needed for grafting depend on the type of the monomer used. The mechanisms of grafting vinyl monomer onto OPEFB were proposed. The grafted products were characterized by gravimetric analysis, FTIR and SEM.

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Fuctionalization of SBA-16 Mesoporous Materials with Cobalt(III) Cage Amine Complex

  • Han, Sang-Cheol;Sujandi, Sujandi;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1381-1384
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    • 2005
  • Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the $[Co(diAMsar)]^{3+}$ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.

Wrapping of an Ascending Aortic Aneurysm with the Multiple Boot-Straps Technique in a Patient Undergoing Off-Pump Coronary Artery Bypass Grafting

  • Na, Kwon Joong;Kim, Jun Sung;Park, Kay-Hyun;Lim, Cheong
    • Journal of Chest Surgery
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    • v.48 no.3
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    • pp.206-209
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    • 2015
  • Ascending aortic aneurysms are usually treated with graft replacement under cardiopulmonary bypass. However, if a candidate for off-pump coronary artery bypass grafting has an enlarged ascending aorta, surgeons may consider wrapping it without cardiopulmonary bypass. Here, we report a 78-year-old female who underwent successful wrapping of the ascending aorta concomitant with off-pump coronary artery bypass grafting, using a new wrapping technique that involves multiple bootstraps.

Extra-anatomic Bypass Grafting after Endovascular Embolization for the Treatment of Mycotic Aneurysm - 2 case reports -

  • Kim, Kwan-Wook;Kim, Jung-Hwan;Youn, Young-Nam
    • Journal of Chest Surgery
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    • v.44 no.2
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    • pp.189-192
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    • 2011
  • Mycotic aneurysm is a disease requiring immediate treatment because of the high risk of rupture. A difficult surgical approach, especially in the case of occurrence on the iliac artery, involving endovascular embolization and extra-anatomic bypass grafting, is known to be a suitable treatment. We performed extra-anatomic bypass grafting after endovascular embolization successfully in two patients. The postoperative computed tomography of both patients showed complete exclusion of the mycotic aneurysm.

TECHNETIUM-99m BONE SCAN FOR EVALUATING AUTOLOGOUS ILIAC BONE GRAFT AND FREEZE-DRIED BONE ALLOGRAFT IN DOG'S MANDIBLE (Technetium-99m 골주사를 이용한 하악골의 자가골 및 동종골 이식의 평가에 대한 실험적 연구)

  • Jin, Sung-Bark;Kim, Soo-Kyung
    • The Journal of the Korean dental association
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    • v.22 no.1 s.176
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    • pp.37-48
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    • 1984
  • Clinical assessment of bone-graft healing in the maxillofacial region is generally limited to clinical evaluation, radiographs, and biopsy. Sequential interpretation of osseous repair, more sensitive than with conventional radiography is possible with a non-invasive, non-destructive radionuclide method. Technetium-99m radionuclide bone scan was used in the evaluation of the progress of osteogenic activity in autologous iliac bone graft and freeze-dried bone allograft of dog's mandible. Bone scan was performed at 1wk, 2wk, 4wk, 6wk, and 8wk after grafting. In autologous graft the activity ratio for the graft bone remained greater than that of the host since 2자 after grafting; however, in lyophilized allograft the activity ratio for graft bone was greater than that of the host at 6자 after grafting.

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Studies on the Graft Polymerization-Graft Polymerization of Styrene to Polyvinyl Alcohol by Ultraviolet Light (Graft 重合에 關한 硏究-紫外線 照射에 依한 Polyvinyl alcohol 과 Styrene 의 Graft 重合에 關하여)

  • Shim, Jyong-Sup;Jun, Kyong-Chul
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.64-68
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    • 1962
  • The graft polymerization of styrene to polyvinyl alcohol using a photosensitizer(benzophenone) and ultraviolet light was studied. Styrene was grafted onto polyvinyl alcohol up to when polyvinyl alcohol was pre-immersed in water and irradiated by ultraviolet light for 24 hours styrene solution of benzophenone(0.01 molarity). The highest percentage of graft obtained in the grafting which was proceeded in the presence of water added immediately before irradiation was 29%. The grafting was proportional to irradiation time within a certain limit of time, i.e., 24 hours, and presumably was initiated at the surface. After a certain degree of grafting a definite maximum was reached. Graft polymer prepared in this experiment showed high resistance to various solvents.

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Graft Copolymerization of Poly(Methyl Methacrylate) onto Natural Rubber Latex (천연고무 Latex에 Poly(Methyl Methacrylate)의 그라프트 공중합)

  • Kim, K.S.;Shin, M.H.;Choi, S.K.;Keum, K.M.
    • Elastomers and Composites
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    • v.28 no.3
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    • pp.191-197
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    • 1993
  • The graft copolymerization of methyl methacrylate(MMA) onto natural rubber latex(NRL) initiated by t-butyl hydroperoxide(t-BHPO) was investigated in aquous medium. The grafting percentage, grafting efficiency and total conversion were observed in various reaction conditions such as monomer, initiator and emulsifier concentration, reaction temperature, reaction time and agitation speed. The optimum conditions for the graft copolymerization onto natural rubber latex were as follows ; At given monomer concentration of $3{\times}10^{-2}mole/l$, the maximum grafting percentage was appeared in the case of grading in initiator concentration of $4{\times}10^{-2}mo1e/l$ and emulsifier concentration of 0.2wt.% at $40^{\circ}C$ for 5hrs.

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Preparation of Modified Hollow Polypropylene Membrane and Their Adsorption Properties of ${\gamma}$-Globulins

  • Hwang, Taek-Sung;Park, Jin-Won
    • Macromolecular Research
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    • v.11 no.5
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    • pp.347-351
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    • 2003
  • The hydrophobic ligand-containing hollow polypropylene (PP) membranes were synthesized by the mutual radiation induced graft copolymerization with glycidylmethacrylate (GMA) onto hollow PP membrane followed by the subsequent functionalization with L-phenylalanine. FT-IR, elemental analysis and UV spectroscopy were utilized to characterize copolymer composition, and degree of grafting, functionalization conversion and ${\gamma}$-globulins adsorption. The degree of grafting on the PP surface increased with the reaction time and total dose of E-beam. In the subsquent functionalization, the amount of L-phenylalanine increased with the increase in the degree of grafting and the degree of conversion was about 30%. The ${\gamma}$-globulins adsorption experiments showed that adsorption capacity had a maximum value at pH 8. The ${\gamma}$-globulins adsorption capacity in the basic pH region was higher than in the acidic pH region.

Electron Beam -Induced Graft Polymerization of Acrylic Acid on Polypropylene Nonwoven Fabrics(II) (전자빔 가속기를 이용한 폴리프로필렌섬유의 개질(II) - 전자빔의 흡수선량 및 중합조건이 그라프트 공중합에 치는 영향 -)

  • ;N.I. Shtanko
    • Textile Coloration and Finishing
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    • v.15 no.3
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    • pp.154-160
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    • 2003
  • Polypropylene nonwoven fabrics were grafted with acrylic acid by a preirradiation method by using electron beam accelerator. The effect of irradiation dose, storage time, concentration of acrylic acid, reaction temperature, reaction time and Mohr's salt concentration on the degree of grafting were investigated in detail. The grafted Polypropylene nonwoven fabrics were characterized using IR spectroscopy and SEM. The results showed that the degree of grafting increased with increasing absorbed dose and the Mohr's salt in the acrylic acid solution promoted grafting efficiency.

Polyethylene Film Surface Metallization Modified by Radiation Grafting of N-vinyl Pyrollidone

  • Aal, A.A.;Khutoryanskiy, V.V.;Nurkeeva, Z.S.;Mun, G.A.;Soh, D.W.
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05a
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    • pp.110-112
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    • 2004
  • Poyethylene films can be modified by radiation grafting of N-vinyl pyrollidone using y-radiation. FTIR spectra were used to confirm the modification of PE films. The modified films were activated by two-step and one step methods for electroless Cu plating. Morphology of metallized films has been investigated. Electroless Cu plating onto the modified films depends mainly on the grafting degree and activation type. The conductivity of the metallized films has been investigated.

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