• 제목/요약/키워드: Gradual Transition

검색결과 105건 처리시간 0.022초

5V급 고전압 양극 LiNi0.5Mn1.5O4 Spinel의 제조와 전기화학적 특성에 관한 연구 (Electrochemical Characteristics of LiNi0.5Mn1.5O4 Spinel as 5 V Class Cathode Material for Lithium Secondary Batteries)

  • 전상훈;오시형;이병조;조원일;조병원
    • 전기화학회지
    • /
    • 제8권4호
    • /
    • pp.172-176
    • /
    • 2005
  • 차세대 5V급 양극활물질로 각광받고 있는 $LiNi_{0.5}Mn_{1.5}O_4$는 기존의 $LiMn_2O_4$ spinel 물질의 $Mn^{3+}$$Ni^{2+}$으로 치환하여 5V 영역에서 $Ni^{2+}/Ni^{4+}$ 산화/환원 반응이 가능하게 한 물질이다. 기존의 $LiMn_2O_4$는 낮은 초기 용량과 충 방전에 따른 빠른 용량감소를 보이는 단점을 가지고 있어 이 문제를 극복하기 위해 Mn의 일부를 다른 금속으로 치환하여 $LiM_yMn_{2-y}O_4$ (M=Cr, Al, Ni, Fe, Co, Cu, Ca)을 만드는 방법이 활발히 연구되고 있다. 본 연구에서는 기계 화학적 합성법을 이용하여 합성한 $LiNi_{0.5}Mn_{1.5}O_4$의 전기화학적 특성에 대해 연구하였다. 이 물질은 기존의 $LiMn_2O_4$보다 에너지 밀도가 높으며 저가 및 친환경성 등으로 앞으로 HEV 등에서 그 활용성이 크게 기대된다. 볼밀을 이용하여 여러가지 조건(출발물질 조건, 볼밀조건, 열처리조건 등)에서 $LiNi_{0.5}Mn_{1.5}O_4$을 합성한 결과 기계화학적 방법으로는 $Ni^{2+}$$Mn^{3+}$를 완전히 치환하지 못하여 $4.0{\sim}4.1V$의 전압에서 $Mn^{3+}/Mn^{4+}$의 산화/환원과 관련된 peak가 발생하였다. Ni 원료 물질로써 수산화 물질을 사용하고 열처리 온도를 $800^{\circ}C$로 하였을 때 최상의 성능을 나타내었다.

경기도지방(京畿道地方) 적송림(赤松林)의 식물사회학적(植物社會學的) 연구(硏究) (Phytosociological Changes of Pinus densiflora Forest Induced by Insect Damage in Kyonggi-do Area)

  • 임경빈;박인협;이경재
    • 한국산림과학회지
    • /
    • 제50권1호
    • /
    • pp.56-71
    • /
    • 1980
  • 경기도지방(京畿道地方) 적송림(赤松林)의 천이(遷移)를 연구(硏究)하기 위(爲)하여 솔잎혹파리의 피해지속기간(被害持続期間)에 따라 무피해지(無被害地)로서 안성(安城), 피해선단지(被害先端地)로서 용인(龍仁), 피해극심지(被害極甚地)로서 광주(広州) 피해지속지(被害持続地)로서 가평지역(加平地域)을 설정(設定)하고, 각조사지역별(各調査地域別) 환경요인(環境要因)과 식생상태(植生状熊)를 조사(調査)하여 (1) 환경요인(環境要因)과 식생상태(植生状熊)와의 관계(関係) (2) 삼림군집(森林群集) 구조(構造)의 비교(比較) (3) 식물상(植物相)의 변화(変化) 등(等)을 분석(分析)하였던 바 그 결과(結果)를 요약(要約)하면 다음과 같다. 1. 솔잎혹파리의 피해(被害)에 의(依)하여 소나무의 낙엽량(落葉量)이 증가(増加)하고 광조건(光條件), 토양조건(土壤條件) 등(等)의 환경요인(環境要因)에 변화(変化)가 오게 되면 다른 수종(樹種)이 집래(集來)하게 되고 대상수종(代償樹種)인 참나무류(類)의 발달(発達)에 의(依)하여 다음 천이단계(遷移段階)로 안정화(安定化)되는 경로(経路)를 밟는다. 본(本) 조사지역내(調査地域內)에서는 참나무류중(類中) 특(特)히 신갈나무 상대우점식(相状優占植)의 증가(増加)가 유의적(有意的)이었다. 2. 솔잎혹파리의 피해(被害)가 심(甚)해질수록 조사지역별(調査地別), 조사구별(調査区別) 종구성상태(種構成状態)는 점차 다양(多樣)해지며 동일지역내(同一地域內) 조사(調査) 구간(区間) 종구성상태(種構成状態)의 차이(差異)도 커지는 경향(傾向)을 보였다. 그 후(後) 피해(被害)가 지속(持続)되어 식생상태(植生状態)가 재구성(再構成)됨에 따라 종구성상태(種構成状態)는 단순화(單純化)되는 것으로 나타났다. 3 이상(以上)과 같은 결과(結果)와 상대밀도(相対密度) 및 상대우점치(相対優占値)에 의한 식생천이(植生遷移)를 종합분석(綜合分析)한 결과(結果)소나무가 우점종(優占種)을 이루는 본조사지역내(本調査地域內)에서는 솔잎혹파리의 피해(被害)가 지속(持続)됨에 따라 참나무류(類)가 우점종(優占種)으로 되며 잔달래류(類), 싸리류(類) 등(等)이 하층식생(下層植生)을 형성(形成)하는 임목군집(森林群集)으로 변화(変化)해가는 것으로 나타났다.

  • PDF

소나무(Pinus densiflora S. et Z.) 압축이상재(壓縮異常材)의 방사조직(放射組織) 특성(特性)에 관한 해부학적(解剖學的) 연구(硏究) (Anatomical Studies on the Features of Rays in Compression Wood of Korean Red Pine(Pinus densiflora S. et Z.))

  • 정연집;이필우
    • 한국산림과학회지
    • /
    • 제78권2호
    • /
    • pp.119-131
    • /
    • 1989
  • 본(本) 실험(實驗)은 압축이상재(壓縮異常材)가 잘 형성(形成)된 소나무(Pinus densiflora S. et Z.)의 굽어진 수간(樹幹)과 곧은 지재(枝材) 및 지면(地面)에 노출된 측근(測根)에서 압축이상재율(壓縮異常材率)과 편심율(偏心率)변이에 따른 압축이상재(壓縮異常材)와 대응재(對應材) 및 측면재(側面材)의 조직학적(組織學的) 특성(特性)과 방사조직(放射組織)의 수량적(數量的) 특성(特性)을 조사(調査) 검토(檢討)하고자 실시(實施)하였다. 본(本) 시험(試驗)에서 수간(樹幹)은 지상(地上)에서 수고방향(樹高方向)으로 상승함에 따라, 지재(枝材)는 수간(樹幹)에서 가지방향으로 멀어짐에 따라, 압축이상재율(壓縮異常材率)과 편심율(偏心率)이 줄어드는 경향을 나타내었으므로 20cm간격으로 각각 4개씩의 원판(圓板)을 채취(採取)하여 시편(試片)으로 사용(使用)하였다. 또한 근재(根材)는 압축이상재(壓縮異狀材)가 가장 양호(良好)하게 형성(形成)된 부위(部位)에서 한 개의 원판(圓板)을 채취(採取)하여 사용(使用)하였다. 압축이상재(壓縮異常材)의 조직학적(組織學的) 특성(特性)은 횡단면상(橫斷面上) 가도관(假導管)의 둥근형태(形態), 춘재(春材)로 부터 추재(秋材)로의 매우 점진적(漸進的)인 가도관이행(假導管移行), 가도관선단부의 뒤얽힘 및 나선강(螺旋腔)과 세포간극의 존재 등 측면재(側面材) 및 대응재(對應材)와 다른 특성(特性)을 나타냈으며, 압축이상재율(壓縮異常材率)과 편심율(偏心率)이 작아짐에 따라 압축이상재(壓縮異常材)와 대응재(對應材) 및 측면재간조직학적(側面材間組織學的) 특성(特性)의 차이(差異)가 다소 줄어드는 경향을 보였지만 그 특성(特性)은 유지(維持)됨을 알 수 있었다. 또한 압축이상재(壓縮異常材)의 단위면적 당 수직 수지구수는 대응재(對應材)다 적었으나 단위연륜당 수직수지구의 수는 압축이상재(壓縮異常材)가 대응재(對應材)보다 많았으며 단위면적당 방추형방사조직(紡錘形放射組織)(평균수지구(水平樹脂溝)의 수(數와) 단열방사조직(單列放射組織)의 수(數)는 압축이상재(壓縮異常材)와 대응재(對應材) 및 측면재간(側面材間)에 차이(差異)가 없였다. 그렇지만 압축이상재(壓縮異常材)의 방추형방사조직(紡錘形放射組織)과 단열방사조직(單列放射組織)의 폭(幅)은 대응재(對應材) 및 측면재(側面材)보다 넓으나 이들의 세포고(細胞高)는 낮은 경향(傾向)을 나타내어 이들 방사조직(放射組織)의 폭(幅)과 세포고(細胞高)는 압축이상재(壓縮異常材)의 고유한 특성(特性)이라 생각되었다.

  • PDF

A Study of Segmental and Syllabic Intervals of Canonical Babbling and Early Speech

  • Chen, Xiaoxiang;Xiao, Yunnan
    • 비교문화연구
    • /
    • 제28권
    • /
    • pp.115-139
    • /
    • 2012
  • Interval or duration of segments, syllables, words and phrases is an important acoustic feature which influences the naturalness of speech. A number of cross-sectional studies regarding acoustic characteristics of children's speech development found that intervals of segments, syllables, words and phrases tend to change with the growing age. One hypothesis assumed that decreases in intervals would be greater when children were younger and smaller decreases in intervals when older (Thelen,1991), it has been supported by quite a number of researches on the basis of cross-sectional studies (Tingley & Allen,1975; Kent & Forner,1980; Chermak & Schneiderman, 1986), but the other hypothesis predicted that decreases in intervals would be smaller when children were younger and greater decreases in intervals when older (Smith, Kenney & Hussain, 1996). Researchers seem to come up with conflicting postulations and inconsistent results about the change trends concerning intervals of segments, syllables, words and phrases, leaving it as an issue unresolved. Most acoustic investigations of children's speech production have been conducted via cross-sectional designs, which involves studying several groups of children. So far, there are only a few longitudinal studies. This issue needs more longitudinal investigations; moreover, the acoustic measures of the intervals of child speech are hardly available. All former studies focus on word stages excluding the babbling stages especially the canonical babbling stage, but we need to find out when concrete changes of intervals begin to occur and what causes the changes. Therefore, we conducted an acoustic study of interval characteristics of segments and words concerning Canonical Babble ( CB) and early speech in an infant aged from 0;9 to 2;4 acquiring Mandarin Chinese. The current research addresses the following two questions: 1. Whether decreases in interval would be greater when children were younger and smaller when they were older or vice versa? 2. Whether the child speech concerning the acoustic features of interval drifts in the direction of the language they are exposed to? The female infant whose L1 was Southern Mandarin living in Changsha was audio- and video-taped at her home for about one hour almost on a weekly basis during her age range from 0;9 to 2;4 under natural observation by us investigators. The recordings were digitized. Parts of the digitized material were labeled. All the repetitions were excluded. The utterances were extracted from 44 sessions ranging from 30 minutes to one hour. The utterances were divided into segments as well as syllable-sized units. Age stages are 0;9-1;0,1;1-1;5, 1;6-2;0, 2;1-2;4. The subject was a monolingual normal child from parents with a good education. The infant was audio-and video-taped in her home almost every week. The data were digitized, segments and syllables from 44 sessions spanning the transition from babble to speech were transcribed in narrow IPA and coded for analysis. Babble was coded from age 0;9-1;0, and words were coded from 1;0 to 2;4, the data has been checked by two professionally trained persons who majored in phonetics. The present investigation is a longitudinal analysis of some temporal characteristics of the child speech during the age periods of 0;9-1;0, 1;1-1;5, 1;6-2;0, 2;1-2;4. The answer to Research Question 1 is that our results are in agreement with neither of the hypotheses. One hypothesis assumed that decreases in intervals would be greater when children were younger and smaller decreases in intervals when older (Thelen,1991); but the other hypothesis predicted that decreases in intervals would be smaller when children were younger and greater decreases in intervals when older (Smith, Kenney & Hussain, 1996). On the whole, there is a tendency of decrease in segmental and syllabic duration with the growing age, but the changes are not drastic and abrupt. For example, /a/ after /k/ in Table 1 has greater decrease during 1;1-1;5, while /a/ after /p/, /t/ and /w/ has greater decrease during 2;1-2;4. /ka/ has greater decrease during 1;1-1;5, while /ta/ and /na/ has greater decrease during 2;1-2;4.Across the age periods, interval change experiences lots of fluctuation all the time. The answer to Research Question 2 is yes. Babbling stage is a period in which the children's acoustic features of intervals of segments, syllables, words and phrases is shifted in the direction of the language to be learned, babbling and children's speech emergence is greatly influenced by ambient language. The phonetic changes in terms of duration would go on until as late as 10-12 years of age before reaching adult-like levels. Definitely, with the increase of exposure to ambient language, the variation would be less and less until they attain the adult-like competence. Via the analysis of the SPSS 15.0, the decrease of segmental and syllabic intervals across the four age periods proves to be of no significant difference (p>0.05). It means that the change of segmental and syllabic intervals is continuous. It reveals that the process of child speech development is gradual and cumulative.

한국(韓國)에 있어서의 장내기생충감염(腸內寄生虫感染)의 현황(現況)과 추이(推移) (Current Status and Transition of the Prevalence of Intestinal Parasitic Infections in Korea)

  • 김동찬
    • 농촌의학ㆍ지역보건
    • /
    • 제9권1호
    • /
    • pp.83-108
    • /
    • 1984
  • Out of a total of 58 species of helminthic and protozoan parasitic infections in Korea, so far 38 species were reported as intestinal parasites of man. Quite a few species of the intestinal parasitic infections have long been prevalent throughout the country and this has been a significant public health problem. In this paper, current status and transition of the intestinal parasitic infections in the past years were presented. Chronological reviewing of data show background and prospects of change in the prevalence of infections. In the national prevalence survey on parasitic infections conducted once every five years since 1971, stool examinations were done by both cellophane thick smear and brine flotation techniques. Every egg positive case of Ascaris lumbricoides and Clonorchis sinensis was further examined by Stoll's dilution egg counting technique. In 1981, perianal swab using adhesive cellulose tape was added for Enterobius infection. For protozoan cyst examination conducted by province and city in '81, fecal specimens were fixed in SAF solution and examined by the formalin-ether concentration technique. High prevalence of parasitic infection in ana before the 1960s can be easily understood from the data given by the Ministry of Health and Social Affairs in 1967. From a parasite control point of view, the 1960s was the preparatory period particularly for control of soil-transmitted helminthiasis. Several organizations which have contributed to parasite control were founded in this period and the prevention law of parasitic infections was passed in '66. In the '70s, overall prevalence rates of the common intestinal parasitic infections, which were highly prevalent in the past were turned into reduction phase for the first time. The '80s can be said to be an active control period of parasitic infections. Intestinal helminths According to the reports of the national prevalence survey on parasitic infections, the prevalence of helminthic infections was 84.3%(number of person examined:24,887) in '71, 63.2%(27,178) in '76, and 41.1%(35,018) in '81. By area, the prevalence rate in '81 was 35.1%(20,569) in urban areas and 49.6%(14,447) in rural areas. Intestinal nematodes Ascaris lumbricoides The prevalence of Ascaris infection has decreased significantly in recent years. Among students, the prevalence was 55.4%, in '69 and decreased to 4.7% in '83. In the national prevalence surveys, the prevalence decreased to 13.0% in '81 from 54.9% in '71. By area, the prevalence decreased to 8.5% in '81 from 46.4% in '71 in urban area and 19.4% in '81 from 59.6% in '71 in rural area. By age, the prevalence has become in recent years relatively even in all age groups, although higher prevalence used to be seen in young age groups of around 10 years old, particulary in the highly prevalent rural areas. By sex, the prevalence was higher in the female than in the male. Unfertilized egg positive rates among the ascariasis cases increased gradually up to 55.4% on the average in '81. The intensity of the infection was also significantly decreased. Trichuris trichiura Trichuris infection had also decreased to 23.4% in '81 from 65.4% in '71. By area, the decreasing tendency of the prevalence became faster in urban areas than in the rural areas. The prevalence in urban and rural areas in '71 was 69.7%, and 63.1% respectively and decreased to 19.5% and 29.0% respectively in '81. By age, the prevalence reached a peak at the 10-14 age group and showed relatively even distribution throughout all age groups. By sex, the prevalence was close in young age groups, but in the 30s or over age group, especially in rural area, the prevalence was significantly higher in the female than in the male. The prevalence has much fluctuated depending in the area. The prevalence in rural areas surveyed in the '80s shows a range between 20.9% and 73.7% by locality. It is anticipated that the prevalence of Trichuris infection will drop more rapidly, when mass treatment is conducted. Hookworms Hookworm infection by mostly Ancylostoma duodenale and a few by Necator americanus has decreased to a negligible levels in recent years. In the national prevalence surveys, the prevalence was 10.7% in '71, 2.2% in '76, and 0.5% in '81. The prevalence was higher in rural areas than in urban areas. Wide application of multi-specific anthelminthics in the ascariasis control programmes conducted in the past decade appear to have been effective against hookworm infection. Trichostrongylus orientalis As in the case with hookworm infection, the prevalence of Trichostrongylus infection has reached a negligible levels. In the national prevalence surveys, the prevalence was 7.7% in '71, 1.0% in '76 and 0.2% in '81. Enterobius vermicularis In the national prevalence survey in '81, the egg positive rate was 12.0%. Higher prevalence is expected when examined repeatedly. The prevalence rate was 10.3% in urban area and 14.6% in rural area. In recent surveys conducted in rural areas among schoolchildren, the prevalence was 32.4% in Gimhae Gun in '82 and 64.1% in Yeongyang Gun in '83. By age, the egg positive rate was higher in young age groups of around 10 and sharply decreased in age groups of around 20 and then somewhat increased again in middle age groups. By sex, the prevalence was higher in the female than in the male. Strongyloides stercoralis Strongyloides stercoralis infection has rarely been found in Korea. Three cases were reported in 1914. And 0.1-0.5% were found infected out of 2,642 persons examined at the prisoner-of-war camp on Geojedo in 1956. One case was reported in '54 and '82, respectively. Anisakis spp. No systematic survey has been conducted for anisakiasis In Korea. So far, only several cases have been found 1 case in Seoul in '71, 5 cases in Busan in '81 and 1 case in Busan in '84. Intestinal trematodes Metagonimus yokogawai In the national prevalence survey conducted in 1981, the egg positive rate was 1.24% on the average. High endemic areas are located in the southwestern part of Korea. The prevalence in Hadong Gun was 29.1% on the average in '79. In a survey conducted in 76, the prevalence was 44.0% in Gwangyang, 55.0% in Gogseung and 29.0% in Gurye. The infection is closely correlated with raw sweetfish consumption in these areas. Other intestinal trematodes A human case of Heterophyes heterophyes was reported in 1914. Several species were reported in the '80s : 17 cases of Fibricola seoulensis, 9 cases of Pygidiopsis summa, 8 cases of Heterophyes heterophyes nocens, 1case of Heterophyopsis continua, 2 cases of Stellantchasmus falcatus, 1 case of Stictodora sp., 1 case of Echinostoma hortense, and 4 cases of Echinochasmus japonicus. As the intermediate hosts, snakes and frogs play a role for F.seoulensis and fish for the rest of the species. Intestinal cestodes Taenia saginata and T. solium Egg positive rates in the national prevalence survey were 0.7% in '76 and 1.1% in '81. The prevalence in '81 was 0.6% in urban area and 1.8% in rural area. The proglottid positive rate in Jeju Do was 19.2% on the average. On Udo, Jeju Do in 1983, the egg positive rate among the inhabitants was 2.9%. Hymenolepis nana In the national prevalence survey, egg positive rates were 0.6% in '76 and 0.4% in '81. No difference was seen in the prevalence by area and sex. Hymenolepis diminuta Infected cases were reported : 3 in '64 and I in '66. Egg positive rate in '81 was 0.01% in the national prevalence survey. Diphylobothrium latum So far, about 30 cases have been reported. The cases have been reported more frequently in recent surveys. Mesocestoides sp. A case was reported from a hospitalized patient in Seoul in '67. Spirometra erinacei Two cases were reported in '84 following reidentification of the adult worms collected in '74. Intestinal protozoa Out of a total of 23 species of human protozoan infections in Korea, 13 species were reported as intestinal protozoa : Entamoeba histolytica, E coli, Endolimax nana, Iodamoeba b$\ddot{u}$tschlii, Dientamoeba fragilis, Giardia lamblia, Chilomastix mesnilii, Embadomonas sp., Enteromonas hominis, Trichomonas hominis, Isospora belli, I. Hominis(Sarcocystis hominis), and Balantidium coli. Since the first report on intestinal protozoan infections in 1925, there have been quite a few survey data on the prevalence of the infection. It was found reviewing the data chronologically that up to the early '70s the infection was prevalent around a 30-50%. After that, the protozoan cyst positive rate has shown the tendency of gradual decrease throughout the country. Protozoan cyst survey conducted in Seoul and several provinces in 1981 revealed infection rates of 8.9%(1,310) in Gangweondo, 10.7%(1,703) in Gyenggi Do, 11.7%(1,032) in Jeonra Buk Do, 9.1%(4,116) in Jeonra Nam Do, and 1.4%(5,275) in Seoul. Entamoeba histolytica In the survey conducted by province in '81, the cyst positive rate was 0.8% in Gangweon-do, 0.3% in Gyeonggi Do, 1.4% in both Jeonra Buk Do and Jeonra Nam Do, and 0.2% in Seoul. Giardia lamblia In the survey by province in '81, cyst positive rates were 2.2% in both Gyeonggi Do and Jeonra Buk Do, 1.9% in Jeonra Nam Do, 0.5% in Gangweon Do, and 0.9% in Seoul. Balantidium coli Two cases were reported. One in 1930 and the other in '74. Isospora belli and I. Hominis(Sarcocystis hominis) Isospora belli was reported : 1 case in '56 and 3 cases in '66. I. Hominis, recently identified to be synonymous with Sarcocystis hominis, was reported : 3 cases in '66. Other intestinal protozoa The protozoan parasites other than the above mentioned are generally treated as commensal, although some of them are considered to be pathogenic. The data of '81 show that about 10% of the inhabitants are still infected with protozoa.

  • PDF