• 분석과학
• /
• 제8권4호
• /
• pp.569-574
• /
• 1995

In-situ spectroelectrochemical studies have been carried out on the oxidation of Mn(II) at platinum, gold, lead dioxide, and bismuth doped lead dioxide electrodes. The Mn(III), $MnO_2$, and/or ${MnO_4}^-$ species are produced depending on experimental conditions employed during electrolysis. Mn(III) is shown to be produced from a very early stage during the anodic potential scan and undergo disproportionation-conproportionation reactions depending on the relative concentration of each species near the electrode surface. An oxidation mechanism consistent with these observations is proposed.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
• /
• pp.191-191
• /
• 2011

유체 플라즈마 공정(SPP)은 최신 나노기술과 열전달 유체 기술이 융합된 나노유체(Nanofluids)를 제조하는 공정이다. 본 연구에서는 이런 유체 플라즈마 공정에서 공정시간과 음극파워비율에 따라 금 나노유체 제조시 사용되는 전극에 미치는 영향을 알아보기 위해 특성분석을 실시하였다. 그 결과 전극의 양극에서는 염화금 이온이 전극에 증착되었고 음극에서는 부식에 의해 무게가 감소하였다.

• 대한화학회지
• /
• 제66권6호
• /
• pp.436-441
• /
• 2022

나노 다공성 구조를 가지는 전극은 매우 큰 전기화학적 표면적을 지니기 때문에 그 형성 방법에 대한 연구가 다양하게 이루어져 왔다. 본 논문에서는 정전위 양극 산화를 이용하여 초미세전극(ultramicroelectrode, UME) 표면에 나노 다공성 금(nanoporous gold, NPG) 구조를 도입하는 방법을 연구하였다. 1M KCl을 포함하는 0.1M 인산완충용액(pH 8)에서 1.3 V의 정전위를 가해 주면 잘 정의된 NPG 구조가 UME 표면에 도입되었다. NPG-UME 형성에서 인가 전위와 반응 시간, 그리고 전극의 크기가 형성된 NPG 전극의 거칠기 인자(roughness factor, R_f)에 미치는 영향을 관찰하여 양극 산화 효율을 조사하였다. 10분 정도의 짧은 시간에 2000정도의 큰 R_f 값을 가지는 NPG-UME를 만들 수 있었는데, 전기화학적 글루코오스 검출에 효과적으로 활용 가능하였다. 본 연구 결과는 적은 시료양으로 전기화학적 분석을 수행하는 경우 응용성이 클 것으로 기대한다.

• Bulletin of the Korean Chemical Society
• /
• 제34권9호
• /
• pp.2685-2690
• /
• 2013

The activities of Au-modified Cu electrodes toward glucose oxidation are evaluated according to their fabrication conditions and physico-chemical properties. The Au-modified Cu electrodes are fabricated by the galvanic displacement of Au on a Cu substrate and the characteristics of the Au particles are controlled by adjusting the displacement time. From the glucose oxidation tests, it is found that the Au modified Cu has superior activity to the pure Au or Cu film, which is evidenced by the negative shift in the oxidation potential and enhanced current density during the electrochemical oxidation. Though the activity of the Au nanoparticles is a contributing factor, the enhanced activity of the Au-modified Cu electrode is due to the increased oxidation number of Cu through the electron transfer from Cu to more electronegative Au. The depletion of electron in Cu facilitates the oxidation of glucose. The stability of the Au-modified Cu electrode was also studied by chronoamperometry.

• 센서학회지
• /
• 제25권4호
• /
• pp.247-251
• /
• 2016

Au/PDMS membranes are widely used to fabricate strain sensors which can detect input signals. An interfacial adhesion between metal films and polydimethylsiloxane (PDMS) substrates is one of the important factors determining the performance of strain sensors, in terms of robustness, reliability, and sensitivity. Here, we fabricate Au/PDMS membranes with (3-mercaptopropyl) trimethoxysilane (MPTMS) treatment. PDMS membranes were fabricated by spin-coating and the thickness was controlled by varying the spin rates. Au electrodes were deposited on the PDMS membrane by metal sputtering and the thickness was controlled by varying sputtering time. Owing to the MPTMS treatment, the interfacial adhesion between the Au electrode and the PDMS membrane was strengthened and the membrane was highly transparent. The Au electrode, fabricated with a sputtering time of 50 s, had the highest gauge factor at a maximum strain of ~0.7%, and the Au electrode fabricated with a sputtering time of 60 s had the maximum strain range among sputtering times of 50, 60, and 120 s. Our technique of using Au/PDMS with MPTMS treatment could be applied to the fabrication of strain sensors.

• KSBB Journal
• /
• 제13권1호
• /
• pp.52-57
• /
• 1998

The present work proposes a simple electrochemical method applicable to any immobilization processes of oxidase using a Clark type oxygen electrode as a base transducer. The present work suggests an optimal immobilization technique among three different methods of glucose oxidase(GOD) onto one side of $37[\mu}$mthick blend membranes, composed o 80% of cellulose triacetate and 20% of polycaprolactone, on the basis of the maximum Michaelis-Menten parameter(Vm) determined by either steady state or transient analyses. The electrode system was made of disk type gold cathode(4mm diameter) and Ag/AgCl anode. One side of the blend membrane was in contact with the cathode surface while the other side was immobilized with GOD either in covalent-bond or cross-linked forms, the latter being covered by $25{\mu}$m thick dialysis membrane of cellulose acetate. The resultant current density was on-line monitored by a potentiostat while glucose level was varied from 1 to 20 mM. The present study shows that direct cross-linking of GOD with glutaraldehyde was mostly preferred for fabrication of glucose sensor, on the basis of resultant kinetic parameters from either steady state or transient analyses.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2008년도 제39회 하계학술대회
• /
• pp.1484-1485
• /
• 2008

The control of the number and dimension of nanowires is essential for dielectrophoretic(DEP) nanoscale assembly process. However, it is difficult to control the number of nanowires assembled between the electrodes. We have developed a nanowire diluter device, which consists of a glass substrate with gold electrodes and a PDMS layer with microchannel. The diluter device is fabricated by the conventional and soft lithographies using a SU-8 mold. Nickel nanowires (30${\mu}m$-long) are fabricated by a template-directed electrodeposition process using nanoporous alumina templates. A solution containing nanowires is injected into an inlet whereby pulsed voltages are applied to 16 pairs of electrodes in this experiment. The nanowires are trapped or released depending on the pulsed electric field from inlet to outlet (the channel). Therefore, the number of nanowires can be decreased correspondingly if the fixed frequency at each electrode is decreased from electrode to electrode.

• 대한화학회지
• /
• 제17권2호
• /
• pp.126-129
• /
• 1973

회전백금전극을 지시전극으로하고 수은-요오드화수은(II)을 기준전극으로하여 암모니아수용액에서 2.5-dimercapto-1,3,4-thiadiazole에 의한 은의 전류적정법을 연구하였다. 암모니아수용액에서 EDTA를 은폐제로 사용하여 여러 가지 이온들의 존재 하에 미량의 은을 직접 적정할 수가 있었으며 백금과 금 이온만이 방해하였다. 이 방법으로 미량의 은을 상대 오차 ${\pm}3{\%}$이내 정량할 수 있다.

• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
• /
• pp.115-118
• /
• 2000

미세 가공 기술을 이용하여 제작된 IDA 전극을 활용하여 임피던스 측정방식의 cell chip으로의 응용에 대해 고찰하였다. IDA 전극은 기존의 반도체 공정으로서 손쉽게 제작할 수 있고, 대량 제작시 전극의 재현성 확보가 용이하고 소형화 할 수 있으며 낮은 단가로 제작될 수 있는 장점이 있다. IDA 전극을 채용한 cell chip을 B16-F1 melanoma 세포 배양에 적용한 결과, 세포성장과 임피던스 변화량이 상관성을 보였고, 세포의 성장을 저해하는 약물의 투과시 cell chip의 임피던스 변화 역시 기존의 방법과 유사한 결과를 보여 주었다.

• Bulletin of the Korean Chemical Society
• /
• 제15권12호
• /
• pp.1042-1045
• /
• 1994

A thin film of silver ferricyanide (Ag$_3$Fe(CN)$_6$) on a platinum or gold substrates can be reduced electrochemically to the salt of silver ferrocyanide in potassium nitrate solution. The color of these films are orange and these films are shown to be electrochromic. The voltammogram is shown the asymmetry of the oxidation compared to the reduction wave under various supporting electrolytes. The standard heterogeneous electron-transfer rate for these films and bare Pt electrode were 0.49 ${\times}$ l0$^{-2}$ and 1.30 ${\times}$ l0$^{-2}$ cm/s, respectively, obtained using a rotating disc electrode. Rough D$_0$ values, evaluated from the Levich equation, for Fe(CN)$_6^{3-/4-}$ at both SF thin film and a bare Pt disc electrode were shown as 1.2l ${\times}$ l0-6 and 0.94 ${\times}$ l0$^{-6}$ cm$^2$/s, respectively. The conductivities, as determined from the slops of the i-V curves for a ca. 1 mm sample for dried SF potassium rich and deficient bulk samples pressed between graphite electrodes, were 9.34 ${\times}$ l0$^{-9}$ and 5.80 ${\times}$ l0$^{-9}$ (${\Omega}$${\cdot}$cm)$^{-1}$, respectively.