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Mercury Emission Control in Japan

  • Takiguchi, Hiroaki;Tamura, Tomonori
    • Asian Journal of Atmospheric Environment
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    • v.12 no.1
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    • pp.37-46
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    • 2018
  • The Minamata Convention on Mercury entered into force on August 16, 2017. It requires Parties to the Convention to control and, where feasible, reduce mercury emissions from the listed sources. To implement the Convention, Japan amended the Air Pollution Control Law and added clauses that force operators to control their mercury emissions below emission limit values (ELVs). The ELVs have been established separately for new and existing sources, targeting the source categories listed in the Convention: coal-fired boilers, smelting and roasting processes used in the production of non-ferrous metals (lead, zinc, copper and industrial gold), waste incineration facilities and cement clinker production facilities. The factors used to establish the ELVs include the present state of mercury emissions from the targeted categories as well as the mercury content in fuels and materials, best available techniques (BATs) and best environmental practices (BEPs) to control and reduce mercury emissions and ELVs or equivalent standards to control mercury emissions in other countries. In this regard, extensive data on mercury emissions from flue gas and the mercury content of fuels and materials were collected and analyzed. The established ELVs range from $8{\mu}g/Nm^3$ for new coal-fired boilers to $400{\mu}g/Nm^3$ for existing secondary smelting processes used in the production of copper, lead and zinc. This paper illustrates the ELVs for the targeted source categories, explaining the rationales and approaches used to set the values. The amended Law is to be enforced on April 1, 2018. From future perspectives, checks of the material flow of mercury, following up on the state of compliance, review of the ELVs and of the measurement and monitoring methods have been noted as important issues.

Effect of medis composition on the Cordycepin and content Nutritional Components of Cordyceps militaris (배지 조성이 번데기 동충하초의 영양성분 및 Cordycepin 함량에 미치는 영향)

  • Cho, Soo-Muk;Park, Hong-Ju;Seo, Geon-Sik;Hong, Jong-Deok
    • The Korean Journal of Mycology
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    • v.37 no.2
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    • pp.161-166
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    • 2009
  • The purpose of the present study is to develop a simple, fast and sensitive LC/MS method for simultaneous separation and the determination of an active component in the oriental medicinal mushroom Cordyceps militaris. Based on this work, the contents of cordycepin in Cordyceps militaris fruiting cultivated on various media were determined and compared. And also, the nutritional components such as minerals and vitamins were determined in order to provide useful information to consumer as a food material. The analysis methods of nutritional components were chosen on the basis of AOAC. The optimum separation for cordycepin was achieved using a solvent gradient consisting of the mixture of 0.1% formic acid in methanol (solvent B) in a background of 0.1% formic acid in water (solvent A) as a mobile phase and a 3.0${\times}$150 Waters XTera column. Selective ion monitoring (SIR) mode ([M+H]+ at m/z 252) was used for quantitative analysis of cordycepin. The cultivated Cordyceps militaris on various media contained 1~14 /g of cordycepin, 0.65~1.08% of thiamine, 0.86~7.17% of riboflavin, and 3.01~5.26% of niacin. The content of mineral components varied on categories, especially contained 500~3500% of potassium as a major mineral. Cordycepin, niacin and potassium were found much higher in the fruiting cultivated with soy power media (gold 10) than other media.

Selection of Low Lignin-high Biomass Whole Crop Silage Rice Elite Line for the Improvements of Forage Digestibility and Fermentation

  • Eok-Keun Ahn;Jeom-Ho Lee;Hyang-Mi Park;Yong-Jae Won;Kuk-Hyun Jeong;Ung-Jo Hyun;Yoon-Sung Lee
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.277-277
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    • 2022
  • Lignin modification has been a breeding target for the improvements of forage digestibility and fermentation in whole crop silage(WCS) rice. In rice, gold hull and internode 2 (gh2) was identified as a lignin-deficient mutant. gh2 exhibits a reddish-brown pigmentation in the hull and the internode is located on the short arm of chromosome 2 and codes for cinnamyl-alcohol dehydrogenase (CAD). To develop WCS rice variety improved digestibility and fermentation, we measured acid detergent fiber (ADF), lignin and total digestible nutrient (TDN) calculated from ADF (TDN=88.9-(0.79% × ADF) and performed marker-assisted selection using CAD(Os2g0187800) gene first intron region specific marker with 55 Jungmo1038/J.collection lines. Those lines had lignin content range from 0.82 to 6.61%, ADF from 15.8 to 45.8%, TDN from 52.7 to 78.8 compared to 'Jungmo1038'(1.53,20.7,72.6), 'J.collection'(0.98,12.8,78.8%) and gh2 were introgressed into 44 lines. Considering on these genotype and low-lignin phenotype, we finally selected 2 elite lines(Suweon668, Suweon669). Suweon668 and Suweon669 line are high biomass-low lignin lines that the ADF content is relatively low, even though the dry matter weight is high. Also they have lodging and shattering resistance and glabrous leaf and hull important to improve cattle palatability. Our results will provide that rice can be improved for forage digestibility and fermentation with low lignin concentration.

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Capacitive Humidity Sensor Using Reactive Methacrylate Copolymers (반응성이 있는 메타크릴레이트 공중합체를 이용한 정전용량형 습도센서)

  • 공명선;이임렬
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.4
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    • pp.21-27
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    • 2003
  • The copolymers with various composition of methyl methacrylate (MMA), ethyl methacrylate (EMA), methacrylic acid (MA) and hydroxyethyl methacrylate (HEMA) were synthesized for capacitive humidity sensitive materials. The capacitive humidity sensor consisted of a polymethacrylate film coated on both sides with gold electrode. Capacitance versus relative humidity increased with HEMA content in the copolymer. In the case of self-crosslinkable MMA/MA/HEHA= 40/10/10, the average capacitance at 30%RH, 60%RH and 90%RH are 102, 134 and 166 pF, respectively. And also, the hysteresis, temperature cycle and long-term stability were evaluated as a capacitance humidity sensor.

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Gas and Solute Compositions of Fluid Inclusions in Quartz from Some Base-metal ore Deposits, South Korea (남한의 주용 금속광상산 석영내의 유체포유물의 가스성분과 용존성분의 화학조성)

  • Kim, Gyu-Han;Jeong, Hae-Ran
    • Economic and Environmental Geology
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    • v.32 no.5
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    • pp.421-434
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    • 1999
  • Gas and chemical compositions of fluid inclusions in quartz some of Au-Ag, Pb-Zn-Cu and W-Mo mineral deposits in South Kores were analyzed to interpret the sources of ore fluid and the depositional condition of ore minerals in base-metal ore deposits. Fluid inclusions in quartz from the gold and silver mines are characterized by $CO_2$ rich fluids which have a wide range in $CH_4 \;and\; CO_2$ contents ($CH_4/CO_2$=0.001-0.225). The $CO_2$ rich but $CH_4$-poor nature of the fluid reflects the high fo2 condition during the mineral precipitation. The C2H6 is detected in hydrothermal quartz vines in metasedimentary rocks from the Jeonjoo-il, Youngbokari and Taechang mines. The $CH_4 /CO_2$ rations in W-Mo bearing quartz veins range from 0.005 to 0.214, which is similar with those in Au-Ag mines. However, skarn formation stage. Fluid inclusions, A relatively good correlation between Na and Cl contentrations reflects varible salinity in the fluid inclusion, it is suggested that the chemistry of promary magmatic hydrothermal fluids has changed during post-magmatic alteration and/or wall rock alteration processes. The content of gas compositions also depends on the kinds of country rocks, supporting above conclusion.

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Electrocatalytic Oxidation of HCOOH on an Electrodeposited AuPt Electrode: its Possible Application in Fuel Cells

  • Uhm, Sung-Hyun;Jeon, Hong-Rae;Lee, Jae-Young
    • Journal of Electrochemical Science and Technology
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    • v.1 no.1
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    • pp.10-18
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    • 2010
  • Controlled electrodeposition of dendritic nano-structured gold-platinum (AuPt) alloy onto an electrochemically pretreated carbon paper substrate was conducted in an attempt to improve catalyst utilization and to secure an electronic percolation network toward formic acid (FA) fuel cell application. The AuPt catalysts were obtained by potentiostatic deposition. AuPt catalysts synthesized as bimetallic alloys with 60% Au content exhibited the highest catalytic activity towards formic acid electro-oxidation. The origin of this high activity and the role of Au were evaluated, in particular, by XPS analysis. Polarization and stability measurements with 1 mg $cm^{-2}$ AuPt catalyst (only 0.4 mg $cm^{-2}$ Pt) showed 52 mW $cm^{-2}$ and sustainable performance using 3M formic acid and dry air at $40^{\circ}C$.

Review on Reliability and Validity of Questionnaire of Pattern Identification in Traditional Chinese Medicine -Using China National Knowledge Infrastructure- (중의 변증 설문도구의 신뢰도 및 타당도 고찰 -China National Knowledge Infrastructure를 이용하여-)

  • Yeo, Min Kyung;Dong, Sang Oak;Lee, Young Seop;Jang, Eun Su
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.29 no.3
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    • pp.246-255
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    • 2015
  • The purpose of this study is to investigate the reliability and validity of the questionnaire of pattern identification (PI) in traditional chinese medicine (TCM), through the systematic review of china national knowledge infrastructure (CNKI) database. We searched the articles related with reliability and validity of the questionnaire of PI and published from January 1994 to December 2013. Seventeen questionnaires were analyzed in this study. The twelve (70.6%) questionnaires were developed on the base of specific disease, and five (29.4%) ones were developed on the base of non-specific disease. Three of PI questionnaires showed low inter-item consistency reliability. Exploratory factor analysis of construct validity, content validity, and criterion validity analysis were commonly used on the assessment of validity, but none of them was analysed at the same study. There was only one questionnaire of the ischemic stroke that examined the sensitivity and specificity of both training and test groups in spite of the absence of a gold standard.

Estimation of Alkali Overdosing in a Lime Neutralization Process for Acid Mine Drainage

  • Cheong, Young-Wook;Cho, Dong-Wan;Lee, Jin-Soo;Hur, Won
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.109-112
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    • 2022
  • Lime has been used for the neutralization of acidic waste because it is cheap and available in large quantities. The resulting sludge often contains a considerable amount of unreacted lime due to alkali overdosing, even during automatic neutralization processes, which mainly arises from the poor solubility of lime. The sludge cake from lime neutralization of Ilkwang Mine also contained high percentages of calcium and magnesium. The elemental content of the sludge cake was compared with those obtained from a simulation of the lime neutralization facility installed at Ilkwang Mine. A Goldsim® model estimated the degree of lime overdosing to be 19.1% based on the fractions of ferrous oxide. The analysis suggests that resolubilization of aluminum hydroxide could occur in the settling basin, in which pH exceeded 10 due to the continued dissolution of the overdosed lime. The present study demonstrated that chemical analysis of sludge combined with process simulation could provide a reasonable estimate of mass balance and chemistry in a neutralization facility for acid mine drainage.

Effect of cultivars on hairy root induction and glucosinolate biosynthesis in a hairy root culture of Kimchi cabbage (Brassica rapa L. ssp. Pekinensis

  • Sang Un Park;Sook Young Lee
    • Korean Journal of Agricultural Science
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    • v.49 no.1
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    • pp.51-60
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    • 2022
  • Cruciferous vegetables are rich in biologically active compounds such as glucosinolates and have various health benefits. Among these vegetables, Kimchi cabbage (Brassica rapa L. ssp. Pekinensis) is one of the most popular leafy vegetables due to the presence of the highest amounts of numerous vital phytonutrients, minerals, vitamins, and antioxidants. This study aims to investigate the effects of six cultivars (Chundong 102, Asia No Rang Mini, Hwimori Gold, Asia Seoul, Wol Dong Chun Chae, and Asia Bbu Ri) on hairy root induction and glucosinolate biosynthesis in the hairy root cultures of Kimchi cabbage. Seven different glucosinolates, in this case sinigrin, gluconapin, glucoerucin, glucobrassicin, 4-methoxyglucobrassicin, gluconasturtiin, and neoglucobrassicin, were detected in the hairy root cultures of Kimchi cabbage. Among the different cultivars, Asia No Rang Mini was the most promising candidate for hairy root stimulation, as it achieved the highest values for the growth rate, root number, root length, transformation efficiency, and total glucosinolate content. Overall, the Asia No Rang Mini cultivar of Kimchi cabbage performed best as a promising cultivar hairy root culture for glucosinolate production.

Revaluation of Strategic Metallic Commodities in the Metallic Mines within Taebaeksan-Hwanggangri Metallogenic Belt (태백산-황강리 광화대 금속광산의 전략금속광종 재평가)

  • Lee, Jae-Ho;Heo, Chul-Ho;Chi, Se-Jung
    • Economic and Environmental Geology
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    • v.41 no.3
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    • pp.287-297
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    • 2008
  • In order to estimate the preliminary development feasibility according to the commodity, the content of 8 strategic metallic commoditites(Pb, Zn, Cu, Fe, Mo, W, Au, U) in 68 ore specimens obtained from 34 metallic mines within the Taebaegsan-Hwanggangri mineralized zone were analyzed. Analytical results are as follows. The ore specimen of Sangdong mine contained 23% copper(cut-off grade=0.7%) and those of Cheongil and Samhwanghak mines contained average 5% zinc(cut-off grade=2.0%). Especially, the detailed investigation on the above-mentioned mines is required. And, in case of molybdenum(cut-off grade=0.02%) content in Yeonhwa No. 2(0.04%) and Hong-cheon mine(0.02%), and lead(cut-off grade=0.58%) content in Wongasa mine(0.70%), and gold(cut-off grade=10ppm) content in Dongmyoung(279ppm) and Samhwanghak mine(251ppm), it is required to elastically carry out the revaluation on reopening of mines in terms of the international metal price. On the other hand, in case of uranium, iron and tungsten, it is thought that there are no mines with the development potential value in this study.