• Title/Summary/Keyword: Glass-ceramic composite

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Penetration Mechanisms of Ceramic Composite Armor Made of Alumina/GFRP

  • Jung, Woo-Kyun;Lee, Hee-Sub;Jung, Jae-Won;Ahn, Sung-Hoon;Lee, Woo-Il;Kim, Hee-Jae;Kwon, Jeong-Won
    • International Journal of Precision Engineering and Manufacturing
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    • v.8 no.4
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    • pp.38-44
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    • 2007
  • Combat vehicles are frequently maneuvered in battlefields when the lives of combatants are being threatened. These vehicles are important elements that influence the consequences of a battle. Their armor must be lightweight and provide excellent protection to ensure successful operations. Ceramic composite armor has recently been developed by many countries to fulfill these requirements. We reviewed previous research to determine an effective armor design, and then fabricated a composite armor structure using $Al_2O_3$ and glass fiber-reinforced polymer. Specimens were manufactured under controlled conditions using different backing plate thicknesses and bonding methods for the ceramic layer and the backing plate. The penetration of an armor-piercing bullet was evaluated from ballistic protection tests. The bonding method between the ceramic layer and the fiber-reinforced polymer influenced the ballistic protection performance. A bonding layer using rubber provided the best protection.

Low k Materials for High Frequency High Integration Modules (고주파대응 고집적 모듈용 저유전율 소재)

  • Na, Yoon-Soo;Hwang, Jong-Hee;Lim, Tae-Young;Shin, Hyo-Soon;Kim, Jong-Hee;Cho, Yong-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.328-328
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    • 2008
  • As a low K material for high frequency high integration modules, glass/ceramic composites were investigated. Glass composition were selected from $SiO_2-B_2O_3-Al_2O_3-R_2O$-RO system which having very low dielectric constant and cordierite was used as a ceramic filler. These composites were sintered at temperature range from $850^{\circ}$ to $950^{\circ}$ and XRD, SEM microstructure analysis of sintered bodies were performed for understanding sintering behavior. Any crystallization was not occurred and dense sintered bodies were attained. Dielectric and mechanical properties of these sintered glass/cordierite composites were analysed by network analyzer and UTM. Glass/ceramic composite with 50 wt% cordierite showing a dielectric constant (${\varepsilon}_r$) of 5.4, Q${\times}f_0$ (Q) of 1600 at 1 GHz and maximum bending strength of 163 MPa was attained.

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Investigation on Lead-Borosilicate Glass Based Dielectrics for LTCC (Lead-Borosilicate Glass계 LTCC용 유전체에 대한 고찰)

  • Yoon, Sang-Ok;Oh, Chang-Yong;Kim, Kwan-Soo;Jo, Tae-Hyun;Shim, Sang-Heung;Park, Jong-Guk
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.338-343
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    • 2006
  • The effects of lead-borosilicate glass frits on the sintering behavior and microwave dielectric properties of ceramic-glass composites were investigated as functions of glass composition of glass addition ($10{\sim}50vol%$), softening point (Ts) of the glass, and sintering temperature of the composites ($500{\sim}900^{\circ}C$ for 2 h). The addition of 50 vol% glass ensured successful sintering below $900^{\circ}C$. Sintering characteristics of the composites were well described in terms of Ts. PbO addition in to the glass enhanced the reaction with $Al_{2}O_3$ to form liquid phase and $PbAl_{2}Si_{2}O_8$, which was responsible to lower Ts. Dielectric constant(${\epsilon}_r$), $Q{\times}f_0$ and temperature coefficient of resonant frequency (${\tau}_f$) of the composite with 50 vol% glass contents ($B_{2}O_{3}:PbO:SiO_{2}:CaO:Al_{2}O_3$ = 5:40:45:5:5) demonstrated 8.5, 6,000 GHz, $-70\;ppm/^{\circ}C$, respectively, which is applicable to substrate requiring a low dielectric constant. When the same glass composition was applied sinter $MgTiO_3\;and\;TiO_2,\;at\;900^{\circ}C$ (50 vol% glass in total), the properties were 23.8, 4,000 GHz, $-65ppm/^{\circ}C$ and 31.1, 2,500 GHz, $+80ppm/^{\circ}C$ respectively, which is applicable to filter requiring an intermidiate dielectric constant.

Biocompatibility of 13-93 Bioactive Glass-SiC Fabric Composites

  • Park, Jewon;Na, Hyein;Choi, Sung-Churl;Kim, Hyeong-Jun
    • Journal of the Korean Ceramic Society
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    • v.56 no.2
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    • pp.205-210
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    • 2019
  • Bioactive glass (BG) finds limited use as a bone replacement material owing to its low mechanical properties. In order to solve this problem, the micro-sized 13-93 BG was prepared as a fabric composite with SiC microfibers, and its mechanical properties and biocompatibility were investigated in this study. The tensile strengths of BG-SiC fiber-bundle composites increased in proportion to the number of SiC fibers. In particular, even when only one SiC fiber was substituted, the tensile strength increased by 81% to 1428 MPa. In the early stage of the in-vitro test, a silica-rich layer was formed on the surface of the 13-93 BG fibers. With time, calcium phosphate grew on the silica-rich layer and the BG fibers were delaminated. On the other hand, no products were observed on the SiC fibers for 7 days, therefore, SiC fibers are expected to maintain their strength even after transplantation in the body.

Effect of Glass Composition on the Properties of Glass-infiltrated Alumina(I) : Effect of Al2O3 (유리가 침투된 알루미나 복합체의 물성에 미치는 유리조성의 영향(I): Al2O3의 영향)

  • 이재희;김철영
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.301-308
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    • 2003
  • Glass-infiltrated alumina, which can be used as an all-ceramic dental crown, was prepared. The glasses in the system of SiO$_2$-B$_2$O$_3$-Al$_2$O$_3$-CaO-La$_2$O$_3$with various amount of $Al_2$O$_3$infiltrated into a porous sintered alumina. The effect of $Al_2$O$_3$on the infiltration characteristics and its mechanical strength were studied. The corrosion of the sintered alumina by infiltrated glasses was prevented by increasing the amount of $Al_2$O$_3$in the glass batches, this increased the bending strength of the glass infiltrated alumina composite. The crack like voids in the sintered alumina was a cause of the deteriorating the mechanical strength of the composite, and this can be eliminated by sintering the alumina at 130$0^{\circ}C$. Glass infiltration under the vacuum atmosphere enhanced the hording strength of the composite up to 453$\pm$31 MPa.

Effect of $Al_2O_3$ Particle Size on Thermal Properties of Glass-Ceramics for LTCC Material (저온동시소성용 결정화 유리의 필러 사이즈가 열적 특성에 미치는 영향)

  • Kim, Jin-Ho;Hwang, Seong-Jin;Lee, Sang-Wook;Kim, Hyung-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.281-281
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    • 2007
  • Low Temperature Co-fired Ceramic (LTCC) technology has been used in electronic device for various functions. LTCC technology is to fire dielectric ceramic and a conductive electrode such as Ag or Cu thick film below the temperature of $900^{\circ}C$ simultaneously. The glass-ceramic has been widely used for LTCC materials due to its low sintering temperature, high mechanical properties and low dielectric constants. To obtain the high strength, addition of filler, the microstructure should have various crystals and low pores in a composite. In this study, two glass frits were mixed with different alumina size(0.5, 2, 3.7um) and sintered at the range of $850{\sim}950^{\circ}C$. The microstructure, crystal phases, thermal and mechanical properties of the composites were investigated using FE-SEM, XRD, TG-DTA, Dilatomer. When the particle size of $Al_2O_3$ filler increased, the starting temperatures for the densification of the sintered bodies, onset point of crystallization, peak crystallization temperature in the glass-ceramic composites decreased gradually. After sintered at $900^{\circ}C$, the glass frits were crystallized as $CaAl_2Si_2O_8\;and\;CaMgSi_2O_6$. The purpose of our study is to understand the relationship between the $Al_2O_3$ particle size and thermal properties in composites.

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Fracture resistances of zirconia, cast Ni-Cr, and fiber-glass composite posts under all-ceramic crowns in endodontically treated premolars

  • Habibzadeh, Sareh;Rajati, Hamid Reza;Hajmiragha, Habib;Esmailzadeh, Shima;Kharazifard, Mohamadjavad
    • The Journal of Advanced Prosthodontics
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    • v.9 no.3
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    • pp.170-175
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    • 2017
  • PURPOSE. The aim of the present study was to evaluate the fracture resistances of zirconia, cast nickel-chromium alloy (Ni-Cr), and fiber-composite post systems under all-ceramic crowns in endodontically treated mandibular first premolars. MATERIALS AND METHODS. A total of 36 extracted human mandibular premolars were selected, subjected to standard endodontic treatment, and divided into three groups (n=12) as follows: cast Ni-Cr post-and-core, one-piece custom-milled zirconia post-and-core, and prefabricated fiber-glass post with composite resin core. Each specimen had an all-ceramic crown with zirconia coping and was then loaded to failure using a universal testing machine at a cross-head speed of 0.5 mm/min, at an angle of 45 degrees to the long axis of the roots. Fracture resistance and modes of failure were analyzed. The significance of the results was assessed using analysis of variance (ANOVA) and Tukey honest significance difference (HSD) tests (${\alpha}=.05$). RESULTS. Fiber-glass posts with composite cores showed the highest fracture resistance values ($915.70{\pm}323N$), and the zirconia post system showed the lowest resistance ($435.34{\pm}220N$). The corresponding mean value for the Ni-Cr casting post and cores was reported as $780.59{\pm}270N$. The differences among the groups were statistically significant (P<.05) for the zirconia group, as tested by ANOVA and Tukey HSD tests. CONCLUSION. The fracture resistance of zirconia post-and-core systems was found to be significantly lower than those of fiber-glass and cast Ni-Cr post systems. Moreover, catastrophic and non-restorable fractures were more prevalent in teeth restored by zirconia posts.

Preparation of Self-standing Mesoporous Bioactive Glass/biodegradable Polymer Composite thin Films using Water Casting Method (수면전개법을 이용한 메조다공성 생체활성유리-생분해성 고분자 복합체 자립박막의 제조)

  • Yun, Hui-Suk;Yoon, Jun-Jin;Park, Eui-Kyun;Kim, Seung-Eon;Hyun, Yong-Taek
    • Journal of the Korean Ceramic Society
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    • v.45 no.10
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    • pp.631-637
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    • 2008
  • Self-standing mesoporous bioactive glass/poly($\varepsilon$-caprolactone) composite thin films with good molding capability, bioactivity, and biocompatibility in vitro, which may find potential applications in tissue engineering and drug storage, were prepared using a combination of the sol-gel, polymer templating, and water casting method. The thickness of self-standing films was affected by the difference of dielectric constant between distilled water and organic solvent.

Microstructure and Processing of Bioactive Ceramic Composites as Dental Implants (치과 임플란트용 bioactive 세라믹 복합재료의 제조와 미세조직)

  • Kim, Bu-Sob
    • Journal of Technologic Dentistry
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    • v.25 no.1
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    • pp.21-28
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    • 2003
  • The purpose of this study was to process bio-active glass ceramic composite, reinforced with sapphire fibers, by hot press. Also to study the interface of the matrix and the sapphire fiber, and the mechanical properties. Glass raw materials melted in Pt crucible at 1300$^{\circ}C$ during 3.5 hours. The melt was crushed in ball mill and then crushed material, ground and sieved to $<40{\beta}{\mu}m$. Sapphire fibers cut (30mm) and aligned. Powder and fibers hot pressed. The micrographs show good bonding between the matrix and the fiber and no porosity in the glass matrix. This means ideal fracture phenomena. Glass is fractured before the fiber. This is indication of good fracture strength. EDXS showing aluminum rich phase and crystalline phase. Bright field image of the matrix showing crystalline phase. Also diffraction pattern of TEM showing the crystalline phase and more than one phase. Strength of the samples was determined by 3 point bend testing. Strength of the 10vol% sample was approximately 69MPa, while strength of the control sample is 35MPa. Conclusions through this study as follow: 1. Micrographs show no porosity in the glass matrix and the interface. 2. The interface between the fiber and the glass matrix show no gaps. 3. Fracture of the glass indicates characteristic fiber-matrix separation. 4. Presence of crystalline phase at high processing temperature. 5. Sapphire is compatible with bioactive glass.

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