• Journal of Korea Foundry Society
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• v.24 no.1
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• pp.40-44
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• 2004

The influence of Pd and Ag additions on the thermal stability, the glass forming ability (GFA) and mechanical property of $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_{(5-x)}Ag_x$ (x = $0{\sim}5at%$) alloys obtained by melt spun and injection casting method have been investigated by using of X-ray diffraction, thermal analysis (DTA, DSC) and micro-Vickers hardness(Hv) testing. The thermal properties of melt-spun $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_{(5-x)}Ag_x$ (x = $0{\sim}5at%$) alloys exhibit a supercooled liquid region(${\Delta}T_x$) exceeding 91 K before crystallization. The largest ${\Delta}T_x$ reaches as large as 126 K for the $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_5$ alloy. The reduced glass transition temperature, $T_{rg}$ increased with increasing Ag content. The largest $T_{rg}$ is obtained for the $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ alloy. The $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ bulk amorphous alloy rod with 3 mm in diameter was fabricated by injection casting. Hv increased with increasing Ag content and the largest value was obtained for the $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ bulk amorphous alloy.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.6 no.2
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• pp.144-148
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• 2005

At the previous papers, we showed that ${K_2}O$-CaO-${P_2}{O_5}$ glasses had a solubility in air so that they could be used for glass fertilizer. In this work, we fabricated the Eco-glass fertilizer containing trace elements of B, Mg, Zn, Fe, Cu, Co, Mo, the needed micronutrients for plants to grow, by a melt-quenching process. The dissolution properties in these glasses were investigated with a pH meter and an ICP analyzer. The trace elements doped glasses showed similar behavior in dissolutions and stability properties with the mother glass without containing trace elements. In addition, the dissolution amount of each trace elements depends on the mother glass composition and the quantity of each trace elements, which determine the dissolving velocity of chemical elements.

• Journal of Microbiology and Biotechnology
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• v.6 no.6
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• pp.432-438
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• 1996

Native crystalline chitin was hydrolyzed in an agitated bead reaction system using crude chitinase excreted from Aspergillus fumigatus JC-19. The reaction was enhanced significantly, and the concentration and yield of reducing sugar after 48 hours were measured to be 35.42 g/I (w/v) and 0.64, respectively, around 1.86 times higher than those of the conventional system that was carried out without glass beads. The effect of reaction conditions, such as the amounts of chitin, chitinase and glass beads, and the size of glass bead, were examined. Ball milled chitin was also hydrolyzed in the agitated bead reaction system, the conversion yield and reaction rate of ball milled chitin for 24 hours increased up to 0.87 and 48.02 g/I, respectively. Chitinase showed relatively high stability in the agitated bead reaction system, particularly in the presence of enzyme stabilizer, $Ca^{++}$, which played a critical role in preventing the deactivation of chitinase by the physical impact of glass beads. The variations of the structural features of chitin during the reaction were followed by SEM and X-ray diffraction, and the enhanced hydrolysis reaction was caused by both the fragmentation of chitin particles and the destruction of the crystalline structure owing to the synergic effects of the attrition of glass beads and the hydrolytic action of chitinase.

• Bulletin of the Korean Chemical Society
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• v.28 no.5
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• pp.783-790
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• 2007

The immobilization of proteins and their molecular interactions on various polymer-modified glass substrates [i.e. 3-aminopropyltriethoxysilane (APTS), 3-glycidoxypropyltrimethoxysilane (GPTS), poly (ethylene glycol) diacrylate (PEG-DA), chitosan (CHI), glutaraldehyde (GA), 3-(trichlorosilyl)propyl methacrylate (TPM), 3'-mercaptopropyltrimethoxysilane (MPTMS), glycidyl methacrylate (GMA) and poly-l-lysine (PL).] for potential applications in a nanoarray protein chip at the single-molecule level was evaluated using prismtype dual-color total internal reflection fluorescence microscopy (dual-color TIRFM). A dual-color TIRF microscope, which contained two individual laser beams and a single high-sensitivity camera, was used for the rapid and simultaneous dual-color detection of the interactions and colocalization of different proteins labeled with different fluorescent dyes such as Alexa Fluor® 488, Qdot® 525 and Alexa Fluor® 633. Most of the polymer-modified glass substrates showed good stability and a relative high signal-to-noise (S/N) ratio over a 40-day period after making the substrates. The GPTS/CHI/GA-modified glass substrate showed a 13.5-56.3% higher relative S/N ratio than the other substrates. 1% Top-Block in 10 mM phosphate buffered saline (pH 7.4) showed a 99.2% increase in the blocking effect of non-specific adsorption. These results show that dual-color TIRFM is a powerful methodology for detecting proteins at the single-molecule level with potential applications in nanoarray chips or nano-biosensors.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.15 no.2
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• pp.51-56
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• 2016

High brittleness is a characteristic of glass, and in many cases it is broken during the process of machining due to processing problems, such as scratches, chipping, and notches. Machining defects occur due to the vibration of the equipment. Therefore, design techniques are needed that can control the vibration generated in the equipment to increase the strength of tempered glass. The natural frequency of the machine tool via vibration analysis (computer simulation) must be accurately understood to improve the design to ensure the stability of the machine. To accurately understand the natural frequency, 3D modeling, which is the same as actual apparatus, was used and a constraint condition was also applied that was the same as that of the actual apparatus. The maximum speeds of ultrasonic and high frequency, which are 15,000 rpm and 60,000 rpm, respectively, are considerably faster than those of typical machine tools. Therefore, an improved design is needed so that the natural frequency is formed at a lower region and the natural frequency does not increase through general design reinforcement. By restructuring the top frame of the glass processing, the natural frequency was not formed in the operating speed area with the improved design. The lower-order natural frequency is dominant for the effects that the natural frequency has on the vibration. Therefore, the design improvement in which the lower-order natural frequency is not formed in the operating speed area is an optimum design improvement. It is possible to effectively control the vibrations by avoiding resonance with simple design improvements.

• Elastomers and Composites
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• v.45 no.1
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• pp.32-39
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• 2010

The mechanical properties of PTFE 100%, PTFT 90% + carbon black 10%, PTFE 85% + glass fiber 15%, PTFE 80% + glass fiber 15% + molybdenum disulfide ($MoS_2$) 5%, PTFE 75% + glass fiber 25%, and PTFE 75% + carbon black 18% + graphite 7% composites were investigated in this study. The differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to examine the heat of fusion(${\Delta}H_f$) and thermal stability of the composites. Also, the wear surface and wear volume of PTFE lip seal were examined using the durability test. Wear surface was observed using scanning electron microscope (SEM). It was found that the hardness, wear resistance and durability were enhanced by adding glass fiber and molybdenum disulfide into pure PTFE, but tensile strength and elongation were decreased. According to the experimental results, the composite (PTFE + 15% glass fiber + 5% molybdenum disulfide) showed the best properties for applying to oil-seal among six types of PTFE composites.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.06a
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• pp.173-179
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• 2000

The friction and wear characteristics of brake friction materials reinforced with aramid fiber, carbon fiber, glass fiber, and potassium titanate whiskers were investigated using a pad-on-disk type friction tester. In particular, the morphology of rubbing surfaces was carefully investigated to correlate the friction performance and properties of transfer films. The aramid fiber reinforced specimen showed severe oscillation of friction coefficient at low speed and low applied pressure. The carbon fiber reinforced specimen showing better friction stability exhibited uniform and stable transfer film than any other specimens. The glass fiber reinforced specimen showed unstable friction changes at high speed and high-applied pressure and the non-uniform transfer film was observed in both friction material and rotor surface. The potassium titanate whiskers reinforced specimen showed stable coherent transfer film. The wear test exhibited the potassium titanate whiskers reinforced specimen was lowest in wear amount and glass fiber reinforced specimen showed the severe wear.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.9
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• pp.1416-1422
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• 2001

The objective of this work was to characterize mechanical properties of thermoplastic composites with various forming conditions in compression molding. Randomly oriented long glass fiber reinforced polypropylene(PP) was used in this work. The composite materials contained 20%, 30%, and 40% glass fiber by weight. Compression molding was conducted at various mold temperatures and charge sizes. The temperatures on the mold surface and at the material in the mid-plain were monitored during the molding. Differential Scanning Calorimeter was used to measure crystallinity at both in-side and out-side of the sheet material. Crystallinity at each temperature was also measured by X-ray diffractometer. Dimensional stability was studied at various conditions with the spring forward angle. Among the processing parameters, the crystallization time at the temperature above 130$^{\circ}C$, was found to be the most effective. Spring-forward angle was reduced and the tensile modulus was increased as the mold temperature increased.

• Journal of the Korean Vacuum Society
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• v.14 no.3
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• pp.159-164
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• 2005

Indium tin oxide (ITO) films were deposited on a glass slide at a thickness of 280 nm by radio frequency(rf) magnetron sputtering from a ceramic target composed of $In_2O_3\;(90\%)\;+\;SnO_2\;(10\%)$. We investigated the effects of the annealing temperature (Ta) between 200 and 350'E for 30 min in air on such properties as thermal stability, surface morphology, and crystal structure of the films. X-ray diffraction spectra revealed that all the films were oriented preferably with [222] direction and [440] direction and the peak intensity increased with increasing annealing temperature. X-ray photoelectron spectroscopy (XPS) showed that the sodium was out-diffused from the glass substrate at the annealing temperature of $350^{\circ}C$. The sodium composition of the ITO film amlealed at $350^{\circ}C\;for\;30\;min\;was\;2.5\%$ at the surface. Also the sodium peak almost disappeared after 3 keV $Ar^+$sputtering for 6 min. The visible transmittance of all ITO films was over $77\%$.

• Journal of the Institute of Convergence Signal Processing
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• v.5 no.1
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• pp.40-45
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• 2004

This paper presents the parallel distributed control scheme for shaping of the bent glass. The designed system consists of a PC, a main controller and 11 servo-controllers, the precision motion controllers. Each elements are connected by using RS-232C and 8-bit data bus. In order to guarantee the stability and the control performance, we use a precision PID motion controller and a H-bridge on the servo-drivers. PC calculates position values of 11 DC motors by using the pre-determined curvature value and offers the user interface environment operator. The main controller provides the control instructions and parameter values to 11 servo-controllers by chip enable signal, simultaneously. Using the received commands and parameter values, the servo-controllers control the positions of the DC motors based on PID control scheme.