• Proceedings of the KIEE Conference
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• 1993.07b
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• pp.1162-1164
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• 1993

The Thermally Stimulated Current(TSC) spectroscopy has been applied to study the influence of the structual cahange and interface on the electrical properties of epoxy composites. Three DGEBA-MeTHPA matrix model samples mixed different ratios and silica($SiO_2$) filled sample and silaln treating-filled sample has been studied. Above room temperature, the relaxation mode $\alpha$ peak associated with Tg has been located at $110^{\circ}C$. Below glass transition temperature(Tg), three relaxation modes are observed in all samples: a $\beta$ mode situated at $10^{\circ}C$, a $\gamma$ mode located at $-40^{\circ}C$ and a $\delta$ mode appeared in $-120^{\circ}C$. The analysis of its fine structure indicates that constitution of elementary processes is characterized by the activation energy and relaxation time. Also the dielectric relaxation properties have been investigated to compare the the change of the molecular structure and motion to the relaxation properties and conduction mechanism in TSC spectra.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.1
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• pp.62-67
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• 2008

Biocomposite was fabricated with biodegradable polymer and natural fiber that has potential to be used as replacement for glass fiber reinforced polymer composite with the benefits of low cost, low density, acceptable specific strength, biodegradability, etc. Until now, mostly natural cellulosic fibers on land have been used as reinforcement for biocomposite. The present study focused on investigating the fabrication and the characterization of biocomposite reinforced with red algae fibers from the sea. The bleached red algae fiber (BRAF) showed very similar crystallinity to the wood cellulose. It has high stability against thermal degradation (maximum thermal decomposition temperature of 359.3$^{\circ}C$) and thermal expansion. Biocomposites reinforced with BRAF have been fabricated by a compression molding method and their mechanical and thermal properties have been studied. The storage modulus and the thermomechanical stability of PBS (polybuthylenesuccinate) matrix are markedly improved by reinforcing with the BRAF. These results indicate that red algae fiber can be used as an excellent reinforcement of biocomposites, which are sometimes called as "green-composites" or "eco-composites".

• Journal of the Korean Society of Safety
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• v.38 no.3
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• pp.20-26
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• 2023

Fiber-reinforced composite materials with carbon, glass, and aramid fibers are widely applied to industrial field structures due to their excellent properties. However, carbon fibers are vulnerable to external impacts, whereas aramid fibers degrade when exposed to water. This study evaluated carbon/aramid fiber composites degraded and damaged by high-temperature saline environments using acoustic emission (AE). The test specimen was molded using an autoclave and immersed in seawater at 70 ℃ for 224 days. In order to imitate the damage, a 3-mm-diameter hole was drilled using a diamond drill. Additionally, the specimen with the perforation was repaired by patch attachment processing. Three-point bending was used to conduct the flexural experiment, and an AE sensor with a 150-kHz resonance frequency was attached to evaluate the damage and the effect of patch attachment. AE accumulative counts obtained at the maximum load were 69.2, 67.1, and 91.2 for a high-temperature seawater deteriorated condition, a hole specimen, and a repaired patch specimen, respectively. Furthermore, the maximum amplitude of AE was detected at low values of 28 dB, 31.3 dB, and 30.3 dB.

• Applied Chemistry for Engineering
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• v.26 no.1
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• pp.53-58
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• 2015

Polycarbonate (PC)/graphene oxide (GO) composites with 3 phr of GO were prepared by using a twin screw extruder at 240, 260, and $280^{\circ}C$ after mixing the solution with chloroform. It was confirmed by DSC and TGA that the glass transition temperature ($T_g$) of PC/GO composites were not changed and the thermal stability was the best in case of the extrusion temperature at $260^{\circ}C$. Thermo mechanical properties of PC/GO composites according to extrusion temperatures were measured by dynamic mechanical analysis (DMA). Storage moduli of PC/GO composites were higher than that of pure PC and there was no detectable changes at varying the extrusion temperature. Based on these results, the extrusion temperature of PC/GO composites was fixed at $260^{\circ}C$. The degree of the chemical reaction of PC/GO composites with respect to the GO reduction time was confirmed by the C-H stretching peak at $3000cm^{-1}$ and the degree of the chemical reaction was similar to that of GO when the reduction time was 1 h. A decrease in the complex viscosity as a function of the GO reduction time was detected by dynamic rheometer, which may be originated from the enhancement of GO dispersion by PC-GO reaction. The GO dispersion was confirmed by scanning electron microscope (SEM).

• Journal of Adhesion and Interface
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• v.17 no.1
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• pp.7-14
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• 2016

Epoxy composites with concentrations of 5-70 wt% of silica particles were prepared in order to improve mechanical property and poor thermal stability. The mechanical and thermal properties were investigated and compared to the corresponding properties of neat epoxy composite. Furthermore, the effects of silane compound treatment on silica particles were observed by the experimental results of the tensile strength, glass transition temperature, and thermal stability of epoxy composite. Tensile strength of epoxy composites was measured by universal testing machine (UTM) and after that, the structure and morphology analysis of epoxy nanocomposites were analyzed by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). The increased solid content of CA0030 particle improved the tensile strength of epoxy/ modified composites to give 30-50 MPa. The thermal expansion coefficients (CTE) of neat epoxy resin and epoxy/silica composites measured with a thermomechanical analyzer (TMA) showed that the incorporation of silica particles was helpful to reduce the CTE of neat epoxy resin.

• Steel and Composite Structures
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• v.18 no.1
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• pp.51-69
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• 2015

In recent years, the use of fiber reinforced polymer composites has increased because of their unique features. They have been used widely in the aircraft and space industries, medical and sporting goods and automotive industries. Thanks to their beneficial and various advantages over traditional materials such as high strength, high rigidity, low weight, corrosion resistance, low maintenance cost, aesthetic appearance and easy demountable or moveable construction. In this paper, it is aimed to determine and compare the geometrically nonlinear static and dynamic analysis results of footbridges using steel and glass fiber reinforced polymer composite (GFRP) materials. For this purpose, Halgavor suspension footbridge is selected as numerical examples. The analyses are performed using three identical footbridges, first constructed from steel, second built only with GFRP material and third made of steel- GFRP material, under static and dynamic loadings using finite element method. In the finite element modeling and analyses, SAP2000 program is used. Geometric nonlinearities are taken into consideration in the analysis using P-Delta criterion. The numerical results have indicated that the responses of the three bridges are different and that the response values obtained for the GFRP composite bridge are quite less compared to the steel bridge. It is understood that GFRP material is more useful than the steel for the footbridges.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.22 no.5
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• pp.806-811
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• 2013

In this study, to prevent the nonhomogeneity of fiber orientation during the molding of GFRP composites, GFRP prepreg was fabricated using roving fiber and polypropylene resin. Analyses on the degree of impregnation, tensile strength, and microstructure were conducted on the fabricated prepregs. A lower pulling speed, higher resin temperature, and longer die length showed a greater degree of impregnation of the prepreg. The scanning electron microscope (SEM) micrograph showed, a homogeneous fiber orientation. As a result, fundamental techniques for improved productivity were suggested for the manufacturing field.

• Elastomers and Composites
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• v.43 no.4
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• pp.221-229
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• 2008

Starch as matrix polymer was used to do graft copolymerization with 2-ethylhexylacrylate, methyl methacrylate and acrylic acid. The polymerization was carried out by radical emulsion polymerization with increasing contents of starch. When 0.174% of $\alpha$-amylase as enzyme for starch was added, it was found that it made the best stable emulsion. The glass transion temperature of the polymerized material was increased with starch contents. The particle size and viscosity of the emulsion increased with starch contents due to the increased hydroxy group. Peel strength also increased with contents of starch because the enhanced hydroxy group caused to increase affinity between substrate surface and polymer materials. However, the initial tackiness decreased with starch contents owing to film hardness by higher glass transion temperature.

• Composites Research
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• v.15 no.2
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• pp.1-10
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• 2002

The strength of glass/epoxy fabric joints under pin-loading is estimated based on the characteristics length method and experiment. To investigate the effect of finite element idealization for the contact between pin and laminate, three modeling cases are analyzed; assuming the cosine load distribution around the contact area, constraining the radial displacement at the hole boundary, and using the contact element. To study the effect of failure criteria, Tsai-Wu and Yamada-Sun methods are applied on the characteristic curve. The results of the nonlinear analysis using the contact element showed good agrements with experimental data in both laminates made of uni-directional prepreg tapes and fabrics. In terms of failure criteria, Tsai-Wu method showed better agreement with experimental results than the one by Yamada-Sun laminate.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.22 no.3
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• pp.414-420
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• 2013

Research on decreasing the weight of composite sandwich panels is in progress. This paper reports the experimental results for the mechanical behavior of a composite sandwich panel. The skins of sandwich panels were made of glass fiber sheets and plywood matrix composites. Their interior layers consisted of glass fiber pultrusion pipes and gold foam. Experimental tests were performed to obtain the mechanical properties and complex mechanical behavior. Before fatigue tests, tensile tests and 3-point bending tests were carried out to obtain the optimal design and determine their strength and failure mechanisms in the flat-wise position. After the static test, a fatigue test were conducted at a load frequency of 5 Hz, stress ratio (R) of 0.1, and endurance limit for the S-N curve. It showed that the failure modes were related to both the core design and skin failure.