• Applied Chemistry for Engineering
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• v.34 no.1
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• pp.30-35
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• 2023

The glass bead surface was coated using a TiO₂ sol, after which dry-treated (TB) and calcined (TBc) samples were prepared. Photocatalytic degradation of methylene blue and toluene, as well as characterization of the TiO₂ thin films, were carried out. The TiO₂ thin film of the TB sample had the same shape as the sponge foam, according to FE-SEM, XPS, and FTIR analyses, and contained both amorphous and crystalline TiO₂. On the other hand, crystalline TiO₂ was mainly present in the TiO₂ thin film of the TBc sample, and needle-shaped particles and tiny ones were mixed. The adsorption capacity for methylene blue and the degradation rate of the TBc sample were less than 10 % compared with those of the TB sample, and the adsorption capacity and degradation rate of the TBc sample decreased similarly as the amount of TiO₂ coating increased. The amount of toluene adsorption for the TBc sample (46 mg/g) was smaller than that of the TB sample with the same coating amount, but the degradation rate was similar. In the case of the TB sample, the degradation rate for toluene decreased less than the adsorption capacity as the amount of TiO₂ coating increased. This result is considered to be because, in the non-calcined TB sample, the active site reduction of the crystalline particles occurred less and the specific surface area of the amorphous texture decreased as the amount of TiO₂ coating increased.

• Analytical Science and Technology
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• v.11 no.2
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• pp.112-119
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• 1998

A Siemens SemiQuant (SSQ) 3000 program, a precalibrated 'standardless' analytical program handling up to 90 elements, was evaluated for the fast analysis of various types of reference materials using a wavelength dispersive X-ray spectrometer. Various types of standard reference materials such as metal discs, metal chips, and geological materials in powder form were analysed and it took 23 minutes of measuring time for 75 elements. Measurements of geological reference materials using different sampling methods were carried out and their data were interactively evaluated. The analysis of materials of a known matrix concentration such as stainless steels provided higher precision value compared to totally unknown samples. The analyses of materials prepared as pressed pellets or fused glass beads provided higher precision values compared to the measurement of loose powders with a foil on the sample surface and helium operation, though their sampling procedures were more complicate and took more time. Since very light elements such as boron, carbon, and oxygen have a strong influence on the matrix effects and also on the calculation of effective matrix corrections, the rhodium Compton check was applied to verify the reliability of the defined light element concentrations of light matrix materials and the defined major sample compounds. Failure of defining correct matrix resulted in an unoptimized matrix correction and therefore in the wrong calculation of the element concentration.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.1
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• pp.207-217
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• 1992

In this study, isolated and cultured nitrogen fixed microbes were seeded in the three-phase fluidized bed in which gas, solid and liquid were contacted directly. Input velocity was varied from 8.12 cm/hr to 16.32 cm/hr. And upflow gas pressure was fixed to 80 psi. Return ratios were from 0.2 to 0.6 with the each experimental condition. According to these condition, movement of media, growth of biofilm and removal efficiency were measured. As the results, in case of briquette ash, biofilm was developed to $170{\mu}m$ when velocity was 8.12 cm/hr and return ratio was 0.6. In this condition, COD removal efficiency was 97% and $NH_4$-N removal efficiency was 83%. At the same condition, biofilm thickness of glass bead was $17.59{\mu}m$ and its COD and $NH_4$-N removal efficiency was 83% and 72%. Nitrogen fixed microbes have following characters: it formed dark-brownish sludge, excellent adhesive force, easy solid-liquid separation and low oxygen uptake ratio, but sensitive to DO concentration. Not only it endured shock loading, but required short time to steady state.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.E1
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• pp.29-36
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• 2002

The selective catalytic reduction (SCR) reaction of promoter catalysts was investigated in this study. A pure anatase type of TiO$_2$ was used as support. Activation measurement of prepared catalysts was practiced on a fixed reactor packing by the glass bead after filling up catalysts in 1/4 inch stainless tube. The reaction temperature was measured by K-type thermocouple and catalyst was heated by electric furnace. The standard compositions of the simulated flue gas mixture in this study were as follows: NO 1,780ppm, NH$_3$1,780ppm, $O_2$1% and $N_2$ as balance gas. In this study, gas analyzer was used to measure the outgassing gas. Catalyst bed was handled for 1hr at 45$0^{\circ}C$, and the reactivity of the various catalyst was determined in a wide temperature range. Conversion of NH$_3$/NO ratio and of $O_2$ concentration was practiced at 1,1.5 and 2, respectively. The respective space velocity were as follows . 10,000, 15,000 and 17,000 hr-1. It was found that the maximum conversion temperature range was in a 5$0^{\circ}C$. It was also found toi be very sensitive at space velocity, $O_2$ concentration, and NH$_3$/NO ratio. We also noticed that the maximum conversion temperature of (W, Mo, Sn) -V$_2$O$_{5}$/TiO$_2$ catalysts was broad. Specially WO$_3$-V$_2$O$_{5}$TiO$_2$2 catalyst appeared nearly 100% conversion at not only above 30$0^{\circ}C$ ut also below 25$0^{\circ}C$. At over 30$0^{\circ}C$, NH$_3$ oxidation decreased with decrease of surface excess oxygen. In addition, WO$_3$-V$_2$O$_{5}$TiO$_2$ catalyst did not appear to affect space velocity, $O_2$ concentration, and NH$_3$/NO ratio.ratio.

• 한국생물공학회:학술대회논문집
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• 2005.10a
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• pp.651-654
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• 2005

Analysis of extra- and intra- cellular metabolites is very important to study cell metabolish. Intracellular amino acids in yeast are of great interest as precursors of desired products in biomass production of the feed industries and the production of glutamate. In this study, the fermentations of P. pastoris X-33 and KM71H were carried out in shake flasks. After centrifugation, the harvested cells were mechanically disrupted by using glass bead. The supernatants were used to analyze intracellular amino acid by HPLC system. For HPLC analysis, Resolve C18 column was used with Fluorescence detector. The OPA(o-phthalaldehyde) derivation reaction was employed for analysing amino acids at 30 $^{\circ}C$, 1 ml/min and gradient mode. The concentration of intracellular protein was measured by spectrophotometer.

• The Journal of Korean Academy of Prosthodontics
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• v.33 no.4
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• pp.693-704
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• 1995

This study was performed to evaluate effective surface conditioning method of In-Ceram core to improve bonding with resin cement. The surface of each sample was avraded with glass bead for 20 seconds and then subjected to one of the following conditions : no modification, sandblasting with $50{\mu}m$ slumimum oxide powders for 20 seconds, etching with 20% hydrofluoric acid for 5, 10, and 15 minutes(half of the etched samples were coated with silane), and sandblasting with $250{\mu}m$ aluminum oxide powders and silica coating whith Silicoater MD system(Kulzer, Germany). The surface morphology changes were examined with scanning electronic microscope(SEM. and the shear bond strength of In-Ceram core samples to resin cement(Panavis 21, Kurayay, Japan) were measured. It was concluded that : 1. By SEM observation, 20% HF acid etching did not create clear microretentive structure and surface roughness diminished with increace in etching time. Sandblasting was more effective than 20% hydrofluoric acid etching in producing microretentive structure. 2. The bond strengths of all In-Ceram core samples surface conditioned were increased that that of control group. 3. Silica coating showed higher bond strength than etching with 20% hydrofluoric acid. 4. The use of silane coating was more effective in improving bond strength than lengthening etching time.

• Korean Journal of Microbiology
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• v.38 no.4
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• pp.281-286
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• 2002

Detection of Vibrio vulnificus in fish farm and searching for the bactericidal methods on this bacteria were studied. To detect this microorganism in sea water, mud, fish and mussels, selective isolation methods and detection of vvhA gene were used from January to October,2000. V. vulnificus was detected from May when the water temperature was over $17^{\circ}C$. From June to September, higher than $19^{\circ}C$, this bacteria could be isolated from most of the samples. Freezing and refrigerating did not inhibit the growth of V. vulnificus. Citric acid did not show the bactericidal effect, but more than 500 mg/l of EDTA did. With the aid of UV and photocatalyst, $TiO_{2}$ showed bactericidal effect after 15 minute treatment. Photocatalytic system consisted of glass bead coated with $TiO_{2}$ and UV illumination showed bactericidal effect on V. vulnificus at the turnover rate of 0.2/min.

• KSBB Journal
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• v.4 no.3
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• pp.215-220
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• 1989

To develop an attrition coupled enzyme reactor with high efficiency-low energy consumption for saccharification of insoluble biomass, a 5L horizontal paddle type bioreactor was constructed and its performance was evaluated. The optimal condition for saccharification of 50g $\alpha$ -cellulose/L was found to be 200rpm with 500g of 3mm glass bead. Especially, the horizontal paddle type bloreactor was very effective for saccharification of high concentration of insoluble cellulose, in which around 72% of $\alpha$ -cellulose was saccharified for 75g $\alpha$ -cellulose/L, and even up to 70% for 100g of $\alpha$ -cellulose/L after 24hours. Under the optimal condition, the power consumption was measured to be around 1.7watth/g. Horizontal paddle type bioreactor seems to have an appropriated structural feature for industrial scale operation and to be an effective and energy saving attrition coupled enzyme reactor.

• Journal of the Korean Chemical Society
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• v.34 no.1
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• pp.63-68
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• 1990

The chemical ingredients such as $SiO_2,\;Al_2O_3,\;MgO,\;Fe_2O_3,\;CaO$ and $TiO_2$in silica minerals were determined by X-ray fluorescence spectrometry using a matrix correction method. The synthesized standards mixed with reagent grade oxides and the sample were diluted by fusing with 16 times $Li_2B_4O_7$. The matrix effects correlated among the ingredients were corrected by the empirical coefficient method based on the Lucas-Tooth and Pyne model. The analytical results showed relatively good agreement between the different sets of coefficients but were improved with increasing the number of standard. The accuracy of this method was also examined with the standard reference material of NIST.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.1
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• pp.485-492
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• 2013

The effect on collection efficiency with 2-stage vortex finder diameter and back mixing of solid flow due to swirling intensity, turbulence eddies, wall bouncing using the residence time distribution of particle flow in a common and modified cyclone. Higher collection efficiencies of fly ash in a modified cyclone(S = 13, 15cm) are showed than common cyclone. Collection efficiency in modified cyclone was highest at 2-stage vortex finder diameter, S = 13 cm. Variances of residence time distribution and average residence times of glass bead were increased with a diameter(S) of 2-stage vortex finder due to swirling intensity and turbulence eddies. Back mixing of solid flow in a modified cyclone were increased with a gas inlet velocity and showed higher than a common cyclone.