• 한국기계가공학회지
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• 제10권5호
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• pp.104-109
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• 2011

Bulk metallic glasses (BMG) have been greatly improved by the advance of synthesis process during last three decades. It was also found that the Glass Forming Ability (GFA) strongly depends on the glass transition temperature. When the temperature approaches to a critical value, the crystals nucleation from the supercooled liquid can be suppressed so that bulk glass formation possible. Egami and others found that the local glass transition temperature depends on the volumetric strain of each atom and suggested the critical transition temperature. In this paper, we explore the strain dependency of local glass transition temperature using the atomic strain defined by the deformation tensor for the Voronoi polyhedra.

• 한국세라믹학회지
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• 제35권12호
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• pp.1274-1279
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• 1998

The glass forming ability of the PbO-B2O3-TiO3-BaO system was investigated in relation to transitieon tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-perature differences between liquidus temperature and crystallization(or glass transition) temperature de-creased and the temperature difference between crystallization and glass transition temperature increases. The atomic ratio could be used as a criterion to deign glass systems. The interposition of B and Ba atoms between Pb and Ti atoms was one of important factors in glass formation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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• pp.30-33
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• 1994

This paper studies on the effect of DSC(Differential Scanning Calorimeter) analysis condition on the glass transition temperature of silica filled epoxy network polymer used for ultra-high voltage apparatus. The effects of temperature scanning rate specimen size and gas flow rate on measured glass transition temperature have been studied in order to select optimum thermal analysis condition.

• 대한기계학회논문집A
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• 제24권4호
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• pp.824-829
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• 2000

The industries use polymer materials for many purposes because they have many merits. But these materials' costs take up too much proportion in overall cost of products that use these materials as their major material. So it is very economical for polymer industries to reduce these costs. Microcellular foaming process appeared in 1980's to solve this problem and it proved to be quite successful. This process uses inert gases such as CO2, N2. As these gases are dissolved into polymer matrices. many properties are changed. Glass transition temperature is one of these properties. DSC, DMA are devices that measures this temperature, but these are not sufficient to measure the temperature of polymer containing gas. In this paper, we devised a new tester that uses magnetism. We used this device to acquire data of the change of glass transition temperature and made Cha-Yoon model that can predict the change of glass transition temperature. Using this model, the change of this temperature can be estimated as a function of weight gain of gas. Cha-Yoon model proved that Chow's model is inappropriate to predict the change of glass transition temperature of polymer matrices containing gas.

• 대한치과기공학회지
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• 제31권4호
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• pp.25-30
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• 2009

Zirconia($ZrO_2$) has attracted much attention in science and technology because of its high refractive index, high melting temperature, hardness, low thermal conductivity and corrosion barrier properties. And it is widely used as the dental restoration material because of its esthetic appearance. In this research, we analyzed the particle size and composition of the imported dental porcelain for zirconia. And the glass frit was produced. To decrease the glass transition temperature and softening temperature of the glass frit, $Li_2O$ was added into it and the effect of $Li_2O$ on the firing temperature was researched. Then the glass which contains leucite crystal with a high coefficient of thermal expansion(CTE) was manufactured and it was mixed with the glass frit to control the CTE. The phase composition were analyzed using the X-ray diffraction. The morphologies of the samples were observed by the scanning electron microscope. The 4wt% $Li_2O$-added glass frit has the optimal glass transition temperature and softening temperature. And 6 wt% leucite crystal was mixed with the glass frit to control the CTE. From the experimental results of crystallization, the crystal phase was found only leucite crystal.

• 전기의세계
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• 제30권7호
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• pp.441-447
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• 1981

As a preceeding work for the study on dielectric characterstics of a kind of low density polyethylene introduced morphological change by mechanical method, glass transition temperature which is regarded as a macroscopic aspect for relaxation of molecular chain segments has been observed by means of temperature dependent dilatometric measurement. The origina specimen clearly shows two knees which correspond to two peaks (.gamma. and .betha. peak) in the intenal friction measurement, suggesting the existence of separated glass transition temperatures at 150.deg.k and 260.deg.k respectively. On the specimen irradiated to 100 Mrad both glass transition temperatures tend to shift towards high temperature sides because of crosslinking by irradiation. furthemore an evidence can be seen that radiation effect, even in amorphous phase, is also slelctive depending on slight morphological differences. The specimen extended to four times in length shows a peculiar nature such as negative linear thermal expansion coefficient increasing with temperature between 220.deg.k and ambient temperature and that this fact is interpreted by considering that c axis of the lattice aligns along the extended direction by drawing, further c axis inherently possesses the characteristics of negative linear thermal expansion coefficient. For the observations that the relatively small positive linear expansion on the specimen extended to ca. two times as well as the part below 220.deg.k of the specimen extended to four times, it is considered for the reason of the facts that the incompletely oriented region indicated as the middle part of Peterlin's model tends to restore partially to orginal arrangement-a kind of phase transition-as increasing with temperature.

• 대한기계학회논문집A
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• 제25권5호
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• pp.816-822
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• 2001

The thermoforming process is widely used in the plastics industry to produce articles for the packaging, automotive, domestic construction and leisure industries. The microcellular foaming process appeared at M.I.T. in 1980s to save a quantity of polymer materials and increase their mechanical properties. The glass transition temperature of polymer materials is one of many important process variables in appling the microcellular foaming process to the conventional thermoforming process. The goal of this research is to evaluate the relation between gas absorption and glass transition temperature in batch process using microcellular foaming process. The weight gain ratio of polymer materials has a conception of gas absorption. Polymers such as acrylonitrile-butadiene-styrene(ABS), polystyrene(PS) have been used in this experiment. According to conventional Chows model and Cha-Yoon model, it was estimated with real experimental result to predict a change of glass transition temperature as a function of the weight gain ratio of polymer materials in batch process to gain microcellular foamed plastic products.

• Bulletin of the Korean Chemical Society
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• 제23권3호
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• pp.413-416
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• 2002

The dielectric responses of 10 and 40 wt% siloxane-epoxy copolymers were investigated in temperature range near the glass transition of polydimethylsiloxane at which the dielectric transitions were also observed. On the other hand, the pure epoxy did not show any dielectric transition in measurement temperature range -90 to 150 $^{\circ}C.$ The experimental data showed that for the copolymer investigated, the temperature-frequency super-position principle could be applied to the dielectric response. From the Cole-Cole equation, the dielectric relaxation of the 10 wt% siloxane near the glass transition temperature resulted in a broad distribution with ${\beta}=$ 0.19 and the relaxation time at -70 $^{\circ}C$ was 5.3 ${\times}$ $10^{-2}$s. The glass transition temperature, 188 K, was estimated by using WLF relation, which was consistent with the data presented in experiment.

• Elastomers and Composites
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• 제41권1호
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• pp.19-26
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• 2006

본 연구에서는 열화 온도가 아민 (D-230), 아마이드 (G-5022), 그리고 산무수물 (HN-2200)에 의해 경화된 에폭시 접착제의 질량변화, 유리전이온도 및 모폴로지에 미치는 영향을 고찰하였다. 실험 결과, 3가지 접착제 시편의 질량감소는 열화 온도가 증가함에 따라 증가하였다. 이는 열화 온도가 증가함에 따라 시편의 표면에서 더 많은 열화가 발생하여 시편의 질량이 감소한 것으로 판단된다. DSC 분석결과에 따르면 DGEBA/D-230과 DGEBA/G-5022 시편의 유리전이온도는 열화 온도에 따라 증가하였으며, DGEBA/HN-2200 시편의 유리전이온도는 열화온도 $150^{\circ}C$, 열화 시간 7일 이상에서 일정한 값을 나타내었다. SEM 결과에서 열화 이후의 DGEBA/G-5022 시편의 표면은 DGEBA/D-230 또는 DGEBA/HN-2200 시편보다 거친 모폴로지를 나타내었다. 이 결과는 시편의 질량 변화에서 얻은 결과와 일치하였다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2012년도 제38회 춘계학술대회논문집
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• pp.408-410
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• 2012

본 연구에서는 수지 인장시편과 스트랜드 인장시편을 적용하여 탄소섬유/에폭시 복합재의 고온에서의 특성을 조사하였다. 연구결과에 따르면 수지시편의 인장강성은 수지의 유리전이 온도에 근접해감에 따라 서서히 감소하지만 스트랜드 인장시편의 인장강성은 상온에서의 인장강성을 유지한다. 수지시편과 스트랜드 시편의 인장강도는 온도가 유리전이 온도에 근접할수록 급격한 감소를 나타내었다.