• Title/Summary/Keyword: Glass Transition

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Study of thin film transition liquid crystal display (TFT-LCD) optical waste glass applied in early-high-strength controlled low strength materials

  • Wang, Her-Yung;Chen, Jyun-Sheng
    • Computers and Concrete
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    • v.5 no.5
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    • pp.491-501
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    • 2008
  • The present study verifies compressive strength, ultrasonic pulse velocity, electrical resistance,permeable ratio, and shrinkage from waste glass controlled low strength materials (WGCLSM) and early-high-strength WGCSLM specimens, by replacing the sand with waste glass percentages of 0%, 10%,20%, and 30%. This study reveals that increasing amounts of waste LCD glass incorporated into concrete increases WGCLSM fluidity and reduces the setting time, resulting in good working properties. By increasing the glass to sand replacement ratio, the compressive strength decreases to achieve low-strength effects. Furthermore, the electrical resistance also rises as a result of increasing the glass to sand replacement ratio. Early-high-strength WGCSLM aged 28 days has twice the electrical resistance compared to general WGCSLM. Early-high-strength WGCSLM aged 7 days has a higher ultrasonic pulse velocity similar to WGCSLM aged 28 days. The variation of length with age of different compositions is all within the tolerance range of 0.025%. This study demonstrates that the proper composition ratio of waste LCD glass to sand in early-high-strength WGCSLM can be determined by using different amounts of glass-sand. A mechanism for LCD optical waste glass usage can be established to achieve industrial waste minimization, resource recycling, and economic security.

Effect of an Additive on the Physical and Electrical Properties of the B2O3-ZnO-Bi2O3 Glass System for a Sheath Heater Module (Sheath Heater 모듈 실링용 B2O3-ZnO-Bi2O3계 유리소재 및 첨가제에 따른 물성 변화)

  • Choi, Jinsam;Shin, Dong Woo;Bae, Won Tae
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.57-62
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    • 2013
  • We investigated the thermal and electrical properties of the $B_2O_3-ZnO-Bi_2O_3$ glass system as a sealing material in sheath heater modules. A composition with over 90 wt% $Bi_2O_3$ in the $B_2O_3-ZnO-Bi_2O_3$ system was glassified by controlling the cooling rate. The glass transition temperature and thermal expansion coefficient in bismate glass could be controlled by the minor ingredients of ZnO, $SiO_2$, $BaO_2$, and $K_2O$. The $B_2O_3-ZnO-Bi_2O_3$ glass system bonded well to metal, and bismate glass insulating properties were comparable to those of bismate glass $B_2O_3-ZnO-PbO$ glass system in a sheath heater module.

Evaluation of Glass-forming Ability in Ca-based Bulk Metallic Glass Systems (칼슘기 벌크 비정질 합금에서 비정질 형성능 평가)

  • Park, Eun-Soo;Kim, Do-Hyang
    • Journal of Korea Foundry Society
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    • v.29 no.4
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    • pp.181-186
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    • 2009
  • The interrelationship between new parameter ${\sigma}$ and maximum diameter $D_{max}$ is elaborated and discussed in comparison with four other glass forming ability (GFA) parameters, i.e. (1) super-cooled liquid region ${\Delta}T_x (=T_x - T_g)$, (2) reduced glass transition temperature $T_{rg} (=T_g/T_l)$, (3) K parameter $K (=[T_x-T_g]/[T_l -T_x])$, and (4) gamma parameter ${\gamma}(=[T_x]/[T_l+T_g])$ in Ca-based bulk metallic glass (BMG) systems. The ${\sigma}$ parameter, defined as ${\Delta}T^*{\times}P^'$, has a far better correlation with $D_{max}$ than the GFA parameters suggested so far, clearly indicating that the liquid phase stability and atomic size mismatch dominantly affect the GFA of Ca-based BMGs. Thus, it can be understood that the GFA of BMGs can be properly described by considering structural aspects for glass formation as well as thermodynamic and kinetic aspects for glass formation.

Thermal Instability of Natural Convection in a Glass Melting Furnace (유리 용융로에서 자연대류의 열적 불안정성)

  • Lim, Kwang-Ok;Lee, Kwan-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.12
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    • pp.1774-1783
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    • 1998
  • The transition from steady laminar to chaotic convection in a glass melting furnace specified by upper surface temperature distribution has been studied by the direct numerical analysis of the two and three-dimensional time dependent Navier-Stokes equations. The thermal instability of convection roll may take place when modified Rayleigh number($Ra_m$) is larger than $9.71{\times}10^4$. It is shown that the basic flows in a glass melting furnace are steady laminar, unsteady periodic, quasi-periodic or chaotic flow. The dimensionless time scale of unsteady period is about the viscous diffusion time, ${\tau}_d=H^2/{\nu}_0$. Through primary and secondary instability analyses the fundamental unsteady feature in a glass melting furnace is well defined as the unsteady periodic or weak chaotic flow.

The Study on Optical Properties by Adding $La_2O_3$ in Multicomponent Glass Fiber (다성분계 Glass Fiber의 $La_2O_3$ 첨가에 따른 광학적 특성에 관한 연구)

  • 김용호;강원호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.21-23
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    • 1994
  • By adding La₂O₃ to optical multicomponent glass composition, after making mother glass and core fiber that enable to enlarge the infrared transmittance region, then surveyed the optical properties. Through thermal analysis of the glass abstained by melt-quenching after selecting stable basic composition on devitrification and replace SiO₂ by 4-12wt% La₂O₃. As La₂O₃ increases up to l2wt% transition temperature, refractive index, density, deformation temperature increased, whereas thermal expansion coefficient decreased. As a result of inspectig transmittance in UV/VIS/IR region, visable region indicated the decrease of transmittance by increasing the La₂O₃ and transmittance region was enlarged by increasing the La₂O₃ in IR region. Also, fabricate core fiber at 820℃ and severy the optical loss we could fact that La₂O₃ composition added 12wt% showed the minimum optical loss.

PZTN Sintered at the Low Temperature by the Glass Phase Transient Processing (글래스 천이 공정에 의해 저온소결된 PZTN)

  • Kim Chan Young
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.3
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    • pp.97-102
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    • 2005
  • This research was a fundamental study for the low temperature sintering of PZTN by glass phase transient processing. To lower the sintering temperature, the glass phase Processing was used. Also to improve the electrical properties, the transient processing was utilized. After characterization, the various analytic techniques, such as Archimedes method for the measuring densification, x-ray diffraction patterns for the quantitative analysis of crystalline phases were utilized. Also the dielectric constant, dissipation factor, and piezoelectric coefficients were measured to evaluate the PZTN sintered at the $950^{\circ}C$ and $1050^{\circ}C$. This was confirmed that the sintering temperature of PZTN was reduced by $950^{\circ}C$ and the electrical properties were improved by the transition processing. Therefore, the glass phase transient processing can be applicable to low the sintering temperature with the dielectric and piezoelectric properties.

Physical Properties of Elastic Epoxies for High Voltage

  • Lee, Kwan-Woo;Park, Yong-Sung;Park, Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.2
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    • pp.51-54
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    • 2004
  • In this paper, the thermal and mechanical properties of elastic epoxy for the application of high voltage products were investigated. Glass transition temperature (Tg) of elastic epoxies cannot be found from room temperature to 20$0^{\circ}C$ by DSC (Differential Scanning Calorimetry). Weight reduction occurred at 285$^{\circ}C$ and 451$^{\circ}C$ according to a thermogravimeter. The first temperature was affected by addictives and the second by epoxies characteristic. Maximum tensile strain showed 28.3kgf/$\textrm{cm}^2$/$\textrm{cm}^2$ at 20% of mechanical stress in addictives 35 (phr). The SEM (Scanning electron microscope) micrograph of the fracture surface observed void and tearing of elastic epoxy at addictives 35 (phr). On the other side, the SEM micrograph of the rigid epoxy showed a broken trace.

Transition of Femtosecond Laser Ablation Mechanism for Sodalime Glass Caused by Photoinduced Defects

  • Jeoung, Sae-Chae;Choi, Jun-Rye;Park, Myung-Il;Park, Mi-Ra;Choi, Dae-Sik
    • Journal of the Optical Society of Korea
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    • v.7 no.3
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    • pp.150-155
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    • 2003
  • Femtosecond laser ablation mechanism was systematically investigated on sodalime glass in ambient conditions. The ablation crater diameter was measured for varying numbers of laser pulses as for varying well as the laser fluence. The analysis of the results with a one dimensional spatial Gaussian fluence distribution reveals that the inherent ablation mechanism has been altered from a multi-photon process to a single photon excitation due to defect sites that have been accumulated by successive laser pulses. Furthermore, the transition between the two regimes was found to be a function of both the laser fluence and the number of laser shots.

Fabrication of Ni-Nb-Ti-Zr Amorphous Alloys with Wide Supercooled Liquid Region (넓은 과냉각 액체영역을 가지는 Ni-Nb-Ti-Zr계 비정질 합금의 제조)

  • Kim, Sung-Gyoo
    • Journal of Korea Foundry Society
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    • v.22 no.5
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    • pp.252-256
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    • 2002
  • Ni-Nb-Ti-Zr amorphous alloys were manufactured using melt-spinning methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The value of the reduced glass transition temperature and the supercooled liquid region of $Ni_{62}Nb_{10}Ti_{13}Zr_{15}$ alloy were relatively high and were 0.612 and 76 K respectively. However, amorphous bulk alloy rod was not formed using the Cu-mold die casting. The mechanical properties were in the range of $800{\sim}900DPN$ of hardness and $2.5{\sim}2.8$ GPa of tensile strength in the whole composition range.

Dielectric Properties of Bisphenol-A Based Epoxy Resin Composite with Varying Temperature (비스페놀-A를 기반으로 제작한 에폭시 복합체의 온도 변화에 따른 유전특성)

  • Lee, Ho-Shik
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.25-32
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    • 2017
  • Such electrical properties (dielectric permittivity and dielectric loss of epoxy resin with the variations of frequency (30 ~ 300k Hz) and temperature ($20{\sim}160^{\circ}C$) have been measured. Dielectric dissipation of three specimen did not occurred below the glass transition temperature (Tg) regardless of frequency, but occurred above its temperature.