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Using a Bismuth-film Glassy Carbon Electrode Based on Anodic Stripping Voltammetry to Determine Cadmium and Lead in a Standard Rice Flour (양극벗김전위법 비스무스막 유리탄소전극을 이용한 표준 쌀 분말 내 카드뮴과 납 측정)

  • Kim, Hak-Jin;Son, Dong-Wook;Mo, Chang-Yeon;Han, Jae-Woong;Kim, Gi-Young;Park, Sang-Won;Om, Ae-Son
    • Journal of Biosystems Engineering
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    • v.34 no.5
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    • pp.377-381
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    • 2009
  • Excessive presence of heavy metals in environment may contaminate plants and fruits grown in that area. Rapid on-site monitoring of heavy metals can provide useful information to efficiently characterize heavy metal-contaminated sites and minimize the exposure of the contaminated food crops to humans. This study reports on the evaluation of a bismuth-coated glassy carbon electrode for simultaneous determination of cadmium (Cd) and lead (Pb) in a NIST-SRM 1568a rice flour by anodic stripping voltammetry (ASV). The use of a supporting electrolyte 0.1 M $HNO_3$ at a dilution ratio (sample pretreated with acid digestion in a microwave oven: supporting electrolyte) of 1:1 provided well-defined, sharp and separate peaks for Cd and Pb ions, thereby resulting in strongly linear relationships between Cd and Pb concentrations and peak currents measured with the electrode ($R^2\;=\;0.97$, 0.99 for Cd and Pb, respectively). The validation test results for spiked standard solutions with different concentrations of Cd and Pb gave acceptable predictability for both spiked Cd and Pb ions with mean prediction errors of 6 to 30%. However, the applicability of the electrode to the real rice flour sample was limited by the fact that Cd concentrations spiked in the rice flour sample were overly estimated with relatively high variations even though Pb ion could be quantitatively measured with the electrode.

대맥(大麥)의 불임실(不稔實)과 붕소(硼素)의 효과에 관하여 - 제1보(第一報)-

  • Han, Gi-Hak;O, Wang-Geun;Park, Cheon-Seo
    • Applied Biological Chemistry
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    • v.2
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    • pp.5-7
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    • 1961
  • 근년(近年) 경기도(京畿道)및 충청남북도(忠淸南北道) 일부지방(一部地方)에 ‘벌보리’ (대맥불임중(大麥不稔症)의 발생(發生)이 알려졌고 4293년(年) 봄에는 본장(本場)의 신개간지(新開墾地)에서도 不稔麥이 생겼으므로 이 토양(土壤)을 공시(供試)하여 석회(石灰)를 시용(施用)하고 붕소(硼素)와 용성인비(熔性燐肥), 퇴비(堆肥) 및 저니토등(底泥土等)을 시용(施用)하여 시험(試驗)을 실시(實施)하였다. 한편 같은 현상(現狀)이 산성(産生)된 충청북도(忠淸北道) 농사원(農事院) 의 원내포장(院內圃場) 석회전시(石灰展示) 포적지(圃跡地)에서 이의 방제(防除)를 시도(試圖)코 붕소(硼素)를 대맥생육중(大麥生育中)에 엽면시비(葉面施肥)하여 좋은 결과(結果)를 얻었다. 여기서는 이들 처리(處理)로 얻어진 임실도(稔實度)와 맥간중(麥桿中)의 붕소량(硼素量)을 조사분석(調査分析)하였고 그 결과(結果)는 다음과 같다. 1. 붕소(硼素)의 토양시용(土壤施用)은 추파대맥(秋播大麥)의 총생(叢生)을 억제(抑制)할 뿐만아니라 인실도증가(引實度增加)에 유효(有效)하였으며 붕소(硼素)의 엽면시비(葉面施肥)도 대맥붕실도(大麥硼實度)를 증가(增加)시켰다. 2. 부임도(不稔度)가 높은 각구(各區)의 식물체중(植物體中) 붕소함량(硼素含量)은 1ppm내외(內外)였으며 임실(稔實)이 잘된 붕소구(硼素區)에서는 10mm이였다. 그러나 시용(施用)한 붕소량(硼素量)은 대맥(大麥)의 생육기간중(生育期間中), 엽면(葉面)에 흑색반점(黑色斑點)이 나타날 정도(程度)의 과량(過量)이었다. 붕소(硼素)의 엽면시비(葉面施肥)는 상기(上記)와 같은 현상(現象)이 나타나지 않았으며 붕소함량(硼素含量)은 3.5ppm이였다.

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The Three-Stage Stratified Unrelated Question Model (층화 3단계 무관질문모형)

  • Lee, Gi-Sung;Hong, Ki-Hak;Son, Chang-Kyoon
    • Communications for Statistical Applications and Methods
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    • v.18 no.4
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    • pp.423-431
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    • 2011
  • For procuring more sensitive information and estimating stratum target population proportion as well as an overall one form a sensitive population composed of several strata we suggest a two-stage stratified unrelated question model that uses stratified random sampling instead of simple random sampling in the two-stage unrelated question model by Kim et al. (1992) and extend it to the three-stage stratified unrelated question model. We also deal with the proportional and optimal allocation problems in each suggested model, compare the relative efficiency of the suggested two models, and show that the three-stage stratified unrelated question model is more efficient than the two-stage one in view of the variance.

Development of Digital Gas Metal Arc Welding System and Welding Current Control Using Self-tuning Fuzzy PID

  • Doan, Phuc Thinh;Pratama, Pandu Sandi;Kim, Suk-Yoel;Kim, Hak-Kyeong;Yeun, Hwang-Yeong;Byun, Gi-Sig;Kim, Sang-Bong
    • Journal of Ocean Engineering and Technology
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    • v.25 no.6
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    • pp.1-8
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    • 2011
  • This paper describes a new method for a digital gas metal arc welding (GMAW) system. The GMAW system is an arc welding process that incorporates the GMAW power source (PS-GMAW) with a wire feed unit (WFU). The PS-GMAW requires an electric power of constant voltage. A constant magnitude is maintained for the arc current by controlling the wire-feed speed of the WFU. A mathematical model is derived, and a self-tuning fuzzy proportional-integral-derivative (PID) controller is designed and applied to control the welding current. The electrode wire feeding mechanism with this controller is driven by a DC motor, which can compensate for both the molten part of the electrode and undesirable fluctuations in the arc length during the welding process. By accurately maintaining the output welding current and welding voltage at constant values during the welding process, excellent welding results can be obtained. Simulation and experimental results are shown to prove the effectiveness of the proposed controller.

A Floristic Study on the Indigenous Habitat of Donghae-si and Samcheok-si in Gangwon-do, Korea (강원도 동해시·삼척시 일대 고유생육지의 식물상)

  • Kim, Jung-Hyun;Kim, Sun-Yu;Kim, Jin-Seok;Lee, Byoung-Yoon;Yun, Jong-Hak;Nam, Gi-Heum
    • Journal of Environmental Science International
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    • v.23 no.5
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    • pp.911-942
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    • 2014
  • This study was carried out to investigate the flora of indigenous habitat of Donghae-si and Samcheok-si in Gangwon-do, Korea. The vascular plants were collected 18 times (from March to October 2011), and were identified as 804 taxa; 127 families, 445 genera, 720 species, 8 subspecies, 69 varieties, 5 forms and 2 hybrids. In the flora of this area, the calcicolous plants were 55 taxa; Cheilanthes argentea, Clematis serratifoliam, Quercus variabilis. Epipactis papillosa, etc. The endangered plants designated and protected by the wildlife protection law, the Ministry of Environment, Korean were counted to one taxon; Cymbidium macrorhizum. The red list of vascular plants according to IUCN valuation basis were examined, endangered species (EN); Prunus yedoensis and Cymbidium macrorhizum, Vulnerable species (VU); Juniperus chinensis, Pulsatilla tongkangensis, Diarthron linifolium and Swertia wilfordii, Near Threatened species (NT); Paeonia japonica, Allium senescens, Epipactis papillosa and Pogonia minor, Least Concern species (LC); Asplenium ruta-muraria, Platycladus orientalis, Monotropa hypopithys and Eleutherococcus divaricatus var. chiisanensis, etc., Data Deficient species (DD); Paeonia lactiflora var. trichocarpa, and Not Evaluate species (NE); Prunus choreiana, Panax ginseng and Polygonatum infundiflorum etc. Korean endemic plants of this area were 26 taxa; Aconitum pseudolaeve, Corydalis hirtipes, Vicia chosenensis, Salvia chanroenica and Hemerocallis hakuunensis, etc. The floristic regional indicator plants found in this area were 130 taxa comprising 11 taxa of grade V, 15 taxa of grade IV, 33 taxa of grade III, 15 taxa of grade II, 56 taxa of grade I. The naturalized plants were identified as 67 taxa and the percent of naturalized index (NI) was 8.3% of total 804 taxa vascular plants.

Antiplatelet Effects of Cordycepin-Enriched WIB-801CE from Cordyceps militaris: Involvement of Thromboxane A2, Serotonin, Cyclooxygenase-1, Thromboxane A2 Synthase, Cytosolic Phospholipase A2

  • Ok, Woo Jeong;Nam, Gi Suk;Kim, Min Ji;Kwon, Hyuk-Woo;Kim, Hyun-Hong;Shin, Jung-Hae;Lim, Deok Hwi;Kwon, Ho-Kyun;Lee, Chang-Hwan;Chung, Soo-Hak;Kim, Jong-Lae;Park, Hwa-Jin
    • Biomedical Science Letters
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    • v.22 no.4
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    • pp.127-139
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    • 2016
  • A species of the fungal genus Cordyceps has been used as an ingredient of traditional Chinese medicine. In this study, we prepared cordycepin-enriched WIB-801CE, an ethanol extract from culture solution of Cordyceps militaris-hypha, and evaluated its antiplatelet effects on human platelet aggregation. WIB-801CE dose-dependently inhibited ADP-, collagen-, and thrombin-induced platelet aggregation. These antiplatelet effects by WIB-801CE were associated with the attenuation of thromboxane $A_2$ ($TXA_2$) production and serotonin release by ADP, collagen, and thrombin. The inhibition of $TXA_2$ production by WIB-801CE was due to the inhibition of cyclooxygenase-1, $TXA_2$ synthase, and cytosolic phospholipase $A_2$ activity. Therefore, these data suggest that WIB-801CE may be a beneficial component against protection from platelet aggregation-mediated thrombotic disease.

Modeling of Various Tool Influence Functions in Computer Controlled Optical Surfacing (컴퓨터 제어를 통한 광학 가공에서의 다양한 툴 영향 함수의 모델링)

  • Kim, Gi-Chul;Ghim, Young-Sik;Rhee, Hyug-Gyo;Kim, Hak-Sung;Yang, Ho-Soon;Lee, Yun-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.3
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    • pp.167-172
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    • 2016
  • The computer controlled optical surfacing (CCOS) technique provides superior fabrication performance for optical mirrors when compared to the conventional method, which relies heavily on the skill of the optician. The CCOS technique provides improvements in terms of mass production, low cost, and short polishing time, and are achieved by estimating and controlling the moving speed of the tool and toolpath through a numerical analysis of the tool influence function (TIF). Hence, the exact estimation of various TIFs is critical for high convergence rates and high form accuracy in the CCOS process. In this paper, we suggest a new model for TIFs, which can be applied for various tool shapes, different velocity distributions, and non-uniform tool pressure distributions. Our proposed TIFs were also verified by comparisons with experimental results. We anticipate that these new TIFs will have a major role in improving the form accuracy and shortening the polishing time by increasing the accuracy of the material removal rate.

Development of Emission Factors for Greenhouse Gas CO2) from Anthracite Fired Power Plants in Korea (무연탄 화력발전소의 이산화탄소 배출계수 개발)

  • Jeon, Eui-Chan;Myeong, Soo-Jeong;Jeong, Jae-Hak;Lee, Sung-Ho;Sa, Jae-Whan;Roh, Gi-Hwan;Kim, Ki-Hyun;Bae, Wi-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.440-448
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    • 2007
  • Although the anthracite power plant is an important source of greenhouse gas, research on this type of power plant has not been conducted much. The present study investigated the entire anthracite power plants in Korea and analyzed the emitted gas in connection with GC/FD and a methanizer in order to develop $CO_2$ emission factors. The study also sampled the anthracite to analyze the amount of carbon and hydrogen using an element analyzer, and to measure the calorie using an automatic calorie analyzer. The emission factors computed through the fuel analysis was 30.45 kg/GJ and that computed through the $CO_2$ gas analysis was 26.48 kg/GJ. The former is approximately about 15% higher than the latter. When compared the carbon content factors of anthracite with that of bituminous coal, the value of anthracite was 24% higher Compared with IPCC values, the emission factors by the fuel was 14% higher, and that by the emitted $CO_2$ gas was about 1.2% lower. More research is needed on our own emission factors of various energy-consuming facilities in order to stand on a higher position in international negotiations regarding the treaties on climate changes.

An Analysis of Cultural Relics Location (문화유적의 공간적 입지 유형 분석)

  • Kim, Chang-Hwan;Bae, Sun-Hak
    • Journal of the Korean association of regional geographers
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    • v.12 no.5
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    • pp.583-594
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    • 2006
  • Relics are life traces of ancestors, and they are good data for giving an idea about space locations of that period. This study classifies relics according to their type, and for each classified group metrical analysis is carried out using GIS and triangle diagram. The criteria used for analysis of relics' locations are elevation, road accessibility and water accessibility. The analysis results show that every relic has its own distribution characteristics according to the time and the type. This means high possibility of approaching a geographical focus on relics distribution and location. While historical period was taking over prehistorical, relics locations moved from the points of great usage water supply possibility to the points of great traffic accessibility. Also, relics of the ruling class for each time period generally have good locations.

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Application of geophysical methods to determine the extent of the Dongrae Fault in the Oedong-eup area, Gyeongju City (경주시 외동읍 구어리 일대 동래단층 연장성 확인을 위한 물리탐사 적용)

  • Hwang, Hak-Soo;Hamm, Se-Yeong;Lee, Cheol-Woo;Lee, Chung-Mo;Kim, Sung Wook
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.207-215
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    • 2017
  • The northern extension of the Dongrae Fault is inferred to transect the Ulsan Fault in the Gueo-ri area, Oedong-eup, ~15 km SE of Gyeongju City, Gyeongbuk province, S Korea. We conducted geological and geophysical (magnetic, electrical resistivity, and frequency domain electromagnetic) surveys to identify the extent and orientation of the Dongrae Fault in this region. Through joint interpretation of the geological and geophysical data sets, we confirm the presence of the Dongrae Fault and determine its strike ($N14^{\circ}E$). The Dongrae Fault is thought to cross the Ulsan Fault near Ipsil Bridge in the Gwangeo-ri area. Geophysical surveying revealed a fault damage zone that widens to the south, with a typical width of >200 m. Geological field surveys did not delineate the geometry of the Dongrae Fault because alluvial deposits overlie the fault in this area.