• Bulletin of the Korean Chemical Society
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• 제29권3호
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• pp.627-640
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• 2008

The geometrical structures, atomic charges, and relative energies of tetracoordinated Pd complexes [PdCl3Z (Z = Cl-, Br-, OH?-, H2O, NH3, PH3), PdCl2Z2 (Z = Br-, OH?-, H2O, NH3, PH3), PdZ?2X (Z = Cl-, OH?-, H2O, NH3, PH3; X = oxalate, O2-?CCO2-), and PdZ2Y (Z = Cl?-, OH?-, H2O, NH3, PH3; Y = succinate, CO2-?CHCHCO2-?)] and the ligand exchange reactions of the Pd complexes were investigated using the ab initio second order Mller-Plesset perturbation (MP2) and Density Functional Theory (DFT) methods. The geometrical characteristics of the tetracoordinated Pd(II) complexes with mono- and bidentate ligands, the effects of the atomic charges for the charged and uncharged ligands, the (dz2-p ) interactions between the dz2-orbital of Pd(II) and the p -orbital of bidentates, and the relative stabilities between the isomers of PdCl2Z2 and PdZ2Y were investigated in detail. The potential energy surfaces for the ligand exchange reactions used for the conversions of {[PdCl2(NH3)2] + H2O} to {[PdCl(NH3)2(H2O)]+ + Cl?-?} and {[PdCl2(PH3)2] + H2O} to {[PdCl(PH3)2(H2O)]+ + Cl?-?]} were investigated. The geometrical structure variations, molecular orbital variations (HOMO and LUMO), and relative stabilities for the ligand exchange processes were also examined quantitatively.

• 복식문화연구
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• 제10권6호
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• pp.763-780
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• 2002

The aim of this research is to analyze Vionnet´s geometric features, which can be regarded as the key formative beauty among the external characteristics of her works. and to thereby establish the theory that her works emitted a time-transcending life force because they were patterns designed based on a geometrical frame of mind. To prove such argument, studies to understand the basic geometrical aspects appearing in her works will be made by taking a look at the general features of geometry, viewing Vionnet´s philosophy for designing, and examining the geometric cutting methods. The period covered in this paper will center mainly on dresses Vionnet made from her very active days in the fashion sector, 1919. till when she retired from the fashion industry, around 1939. What's outstanding about Vionnet´s geometric principle expressed in her works is the unique cutting method that acknowledges the silhouette of the human body as a cubic or three-dimensions concept, through insight of the human body, the mechanics of the materials, and geometry. Vionnet introduced a simple and elegant design by combining geometric figure cuts, such as rectan히es. quadrants, and triangles. Moreover, she created a new sewing structure that plans everything about the materials to the tiniest detail, resulting in producing a softer style With this, Vionnet showed the geometrical correlation can bring about harmony and the beauty of ideal proportion, forming the source of eternal beauty. As discussed so fu, the geometrical characteristics appearing in Vionnet´s works are marked such as spirals, zig-zag lines, asymmetries. panels, gradation, golden proportion, and the mobius-band.

• 한국산학기술학회논문지
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• 제20권4호
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• pp.464-469
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• 2019

테이퍼 롤러 베어링은 큰 부하 하중이 가해져도 안정적으로 차량을 지지할 수 있어서 승합차, 화물차, 열차 등에 핵심적인 구동 부품으로 광범위하게 사용된다. 테이퍼 롤러 베어링 부품 중에서 케이지는 롤러들 사이의 간격을 유지해 주며, 이를 통해서 마찰 방지 및 마모, 발열을 억제하고 윤활을 위한 공간을 제공해주는 등의 역할을 한다. 차량이 주행 중에 공진으로 인해 케이지가 심하게 변형되면 롤러가 원활한 구름 운동을 하지 못하거나, 케이지를 이탈하는 경우가 발생하게 된다. 따라서 베어링의 안정적인 내구성능을 확보하기 위해서는 케이지의 공진주파수를 파악하는 것이 매우 중요하다. 베어링 케이지는 구조적으로 동일한 형상이 반복되는 주기적 구조물로 볼 수 있는데, 이러한 구조물은 제작과정에서 설계 시 의도한 완벽한 기하학적 형상과는 어느 정도의 오차를 가진 형상으로 제작되게 된다. 본 연구에서는 이러한 케이지의 기하학적 불완전성이 동특성에 미치는 영향을 파악하고자 한다. 그 결과 기하학적인 불완전성에 의하여 이상적인 케이지의 고유진동수 부근에서 고유진동수 분리가 발생하며, 그 간격은 기하학적 오차의 크기에 비례하고 모드의 차수가 증가할수록 그 간격도 넓어진다고 판단된다.

• Structural Engineering and Mechanics
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• 제45권3호
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• pp.411-422
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• 2013

A well-designed mesh shape of the cable net is of essential significance to achieve high performance of cable-network antenna reflectors. This paper is concerned with the mesh design problem for such antenna reflector structure. Two new methods for creating the topological forms of the cable net are first presented. Among those, the cyclosymmetry method is useful to generate different polygon-faceted meshes, while the topological mapping method is suitable for acquiring triangle-faceted meshes with different mesh grid densities. Then, the desired spatial paraboloidal mesh geometrical configuration in the state of static equilibrium is formed by applying a simple mesh generation approach based on the force density method. The main contribution of this study is that a general technical guide for how to create the connectivities between the nodes and members in the cable net is provided from the topological point of view. With the new idea presented in this paper, multitudes of mesh configurations with different net patterns can be sought by a certain rule rather than by empiricism, which consequently gives a valuable technical reference for the mesh design of this type of cable-network structures in the engineering.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.1108-1111
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• 2003

We consider geometrical conditions of liquid crystals of bent-shape molecules that result in optically isotropic antiferroelectric structure that can be reversibly switched to birefringent states. An example of an ester based banana-shape substance is discussed that almost fulfills the ideal conditions and provides fast electro-optical switching with or without crossed polarizers.

• 복식
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• 제56권7호
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• pp.115-125
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• 2006

The study on plane composition in clothing was focused mainly on woven wear earlier but its application has been reaching the knit wear. This study is confined to the utilization with geometrical linear pattern in the modern apparel. The work here intends to grasp the plane structure found in both woven wear and knit wear and, in particular, to understand the aesthetics of fashion. The modern flat patterned clothing has been affected by the oriental style or postmodernism in view of social and cultural aspect while its fabric material and expression method shows the diversity in terms of industrial and technical aspect. It can be characterized as several outstanding patterns: the geometrical pattern in structure, the linear pattern with seam line and 2-dimensional plane pattern without seam line, and the flexible silhouette integrated into one single shape with human body unlike the traditional apparel The aesthetics of fashion in modern flat patterned clothing can be divided into such category as the organically spatial change, the re-creation of tradition and the non-format framework. The organically spatial change shows the geometrical formation in clothes due to change in dimension, where the organically changing uniformity and generosity appears as the dimension progresses. The timeless without any difference of up and down, left and right, and inside and outside and the discontinuity due to limitless spatial change are also imbedded. The re-creation of tradition tells the reshaped spirits of old tradition by integrating and modifying the hereditary features in the old customed clothing into modern clothing. The modern flat patterned clothing implies the contemporaneousness or the frame through which the old and modern cultures may be shared and indicates the re-creation of the past and uniformity. The non-format framework contains the uncertainty in meaning and it doesn't have any certain standards. As both the apparel and the human body with this style aim at the open space, the numerous contingencies are realized.

• 복식문화연구
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• 제12권4호
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• pp.663-675
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• 2004

The plastic arts is used when designers draw inspirations to create fashion design. The author referred to fashion magazines for designing ideas of Mondrian＇s geometrical abstract painting in practical applications used by designers in Paris, Italy, London and New York during the 10-year period(1991-2000). The collections of data were analyzed as following: ◇ Fashion Designing Idea 1. Matching Idea The art is reproduced in the design as how it is with no transformation. First, the painting＇s complete figure is reproduced on the entire or parts of clothing. Second, the painting＇s partial figure is reproduced on the entire or parts of clothing. 2. Contrasting Ideas The composition elements in Mondrian＇s geometrical abstract painting, for example, structures of shapes, vertical and horizontal lines and different colors are applied in the design. First, one particular shape in painting is transformed into different shape of square, circle or triangle and reproduced in designing. Second, one particular shape in painting is disassembled and then reshaped into different form in reproduction. Third, additional lines are put in to create different look from the original painting. Forth, existing lines are extended over the boundary to create different look from the original painting. Fifth, achromatic colors: black and white, and three basic colors: red, blue and yellow in the original painting are modified into different shades or color scheme is increased in broad range.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2016년도 학술발표회
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• pp.326-326
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• 2016

단층은 지질학적 관점에서 국부적인 지구구조응력(tectonic stress)이 암반 내에 존재하는 어떤 면을 따라 파괴 분기값을 초과하는 경우에 발생하는 매우 큰 공간적 변이에 의한 파괴 면으로 정의된다. 이러한 단층의 수문지질학적 특성은 단층의 공간적인 분포와 간극의 연결성에 따라 변화된다. 단층의 형성이 단층 내의 간극의 생성과 파괴를 이끄는 과정이 포함될 때 단층을 따라 발생되는 변이와 간극의 변화 사이에 복잡한 관계가 존재한다. 본 연구에서는 단층의 기하학적 특성에 따라 변화되는 흐름 변화를 3차원 이산 균열망 모형을 통해 모의 및 분석을 수행하였다. 단층의 기하학적 특성에 대해 3가지 경우를 고려하였다. 첫 번째는 영역 중심에 위치한 폭이 매우 좁고 상대적으로 주위 암반보다 매우 높은 투수성을 가진 단층, 두 번째는 단층 주변에 손상지역(damaged zone)이 존재하는 경우 그리고 세 번째는 relay 구조를 가진 단층이다.

• 한국농공학회지
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• 제36권1호
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• pp.116-127
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• 1994

A reliability analysis model for the frame structure which grafts the discretized ideal plastic method to the stochastic finite element method is introduced. The proposed method simmulates realistically the sequencial occurrence of plastic hinges and yields the probability of failure directly from the geometrical and material properties of a frame structure. The presented method can also take into account the uncertainties inherent in loads and resisten- ces through the stochastic finite element technique. The analysis results are compared with those of the Monte Carlo Simmulation, the Bound Theory, and the fs-unzipping method, and show good agreement.

• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.37-45
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• 1994

$(NH_4)_{4.5}[H_{3.5}{\alpha}-PtMo_6O_{24}]{\cdot}1.5\;H_2O(A),\;(NH_4)_4[H_4{\beta}-PtMo_6O_{24}]{\cdot}1.5\;H_2O(B),\;and\;K_{3.5}[H_{4.5}{\alpha}-PtMo_6O_{24}]{\cdot}3\;H_2O(C)$ have been synthesized and their molecular structures have been also determined by single-crystal X-ray diffraction technique. The space groups, unit cell parameters, and R factors are as follows: Compound A, monoclinic, $A_{2/a}$, a= 19.074 (3), b=21.490 (3), c=15.183 (2) ${\AA};\;{\beta}$=109.67 (1) ${\AA}$; z=8; R=0.075($IF_0I>4{\sigma}(IF_0I);$ Compound B, triclinic, P$bar{1}$, a=10.776 (2), b=15.174 (4), c=10.697 (3) ${\AA};\;{\alpha}$ =126.29 (2), ${\beta}$=111.55 (2), ${\gamma}$=93.18 (2) ${\AA}$; Z=2; R=0.046($IF_0I>3{\sigma}(IF_0I);$): Compound C, triclinic, Pl, a=12.426 (2), b=13.884 (2), c=10.089 (1) ${\AA}$; ${\alpha}$=102.59 (2), ${\beta}$=110.73 (1), ${\gamma}$=53.93 (1) ${\AA}$; Z=2; R=0.074 ($IF_0I>3{\sigma}(IF_0I)$. Compounds A and C contain the well-known Anderson structure (planar structure) heteropoly oxometalate having approximate $bar{3}_m(D_{3d})$ symmetry, while compound B contains the bent structure heteropoly oxometalate having appproximate $2_{mm}(C2_v)$ symmetry. The bent structure and the planar one are geometrical isomers. These compounds are rot only novel heteroply molybdates containing platinate(IV) but also the first example of geometrical isomerism in the hexamolybdoheteropoly oxometalates. That isomerization surprisingly occurred because of the change of only 0.5 non-acidic hydrogen atom attached to the polyanion such as $[H_{3.5}{\alpha} -PtMo_6O_{24}]^{4.5-}{\to}[H_4{\beta}-PtMo_6O_{24}]^{4-}{\to}[H_{4.5}{\alpha} -PtMo_6O_{24}]^{3.5-}$. It seems that the gradual protonation of the polyanion plays an important role in that isomerism. These heteropolyanions form dimers by strong hydrogen bonds between two heteropolyanions in the respective crystal system.