• Journal of the Korean Chemical Society
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• v.39 no.4
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• pp.244-251
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• 1995

The palladium(II) complexes(where, [Pd(L)2X2], L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Phisox), and 4-amino, 3,5-dimethylisoxazole(4-ADI); X=Cl, Br] with isoxazole and its derivatives are investigated on antitumor activity by EHMO calculation. It is found that the net charge of the two halogen atoms in trans-isomers are greater than those in cis-ones, indicating that ionic character of Pd-X bond in trans-isomers is greater than that of cis-ones, and so dissociation of Cl- ion is easier than that of Br- ion in aqueous solution in body. Furthermore, it is found that the ${\sigma}MO$ energy of Pd(dx2-y2)-X(px) bond $(E{\sigma}(Pd-X))$ is higher than that of Pd(dx2-y2)-N(px) bond $(E{\sigma}(Pd-N))$ without exception, about all the complexes, and also the $E{\sigma}(Pd-X)$ of trans-isomers is higher than that of cis-isomers. From the above facts, the degree of dissociation in Pd-X bond would be related to antitumor activity. In fact, the linear equation of correlation coefficient 0.96 is fairly established between ${\Delta}E{\sigma}(N-X)(E\sigma(Pd-N)－E{\sigma}(Pd-X))$ and inhibitory activity coefficient, logIA.

• Journal of the Society of Naval Architects of Korea
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• v.34 no.1
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• pp.11-23
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• 1997

This paper contains a new approach to blade section design method for marine propellers. The hydrodynamic characteristics of 2-D section are highly influenced by its geometrical parameters i.e., thickness and camber distributions and leading edge radius etc. To consider fully turbulent flow field near 2-D section. the finite volume method with k-${\varepsilon}$ turbulent model which solve Reynolds time averaged Navier-Stokes(RANS) equation is applied. In this study, O-type grid system that can provide many calculation points on blade surface is used. The results were compared with those of the experiment of NACA0012 to confirm the accuracy of the developed codes. The goal of this study is the development of a blade section with high efficiency and low drag. To achieve this, we carried out the tests of lift, drag and cavitation characteristics in cavitation tunnel. The results of experiment were compared with numerical results in order to validate the proposed blades design method. By comparing the numerical results with the experiments, we found that the new blade section, KH28 allows superior performance in efficiency and cavitation avoidance characteristics. We further investigated the blade section design method and an application study of this section, KH28 to apply to the marine propeller. In order to improve the accuracy of numerical results on prediction of lift and drag, we conclude here that the 2-layer boundary model must be used.

• Journal of the Korean Geotechnical Society
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• v.31 no.4
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• pp.45-55
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• 2015

The stability of the adjcent structures or slopes under blasting is typically evaluated using an empirical vibration attenuation curve or dynamic numerical analysis. To perform a dynamic analysis, it is necessary to determine the blast load and the damping ratio of rock mass. Various empirical methods have been proposed for the blast load. However, a study on representative values of damping ratio of a rock mass has not yet been performed. Therefore, the damping ratio was either ignored or selected without a clear basis in performing a blast analysis. Selection of the dampring ratio for the rock mass is very difficult because the vibration propagation is influenced by the layout and properties of the rock joints. Besides, the vibration induced by blasting is propagated spherically, whereas plane waves are generated by an earthquake. Since the geometrical spreading causes additional attenuation, the damping ratio should be adjusted in the case of a 2D plane strain analysis. In this study, we proposed equivalent damping ratios for use in continuum 2D plane strain analyses. To this end, we performed 2D dynamic analyses for a wide range of rock stiffness and investigated the characteristics of blast vibration propagation. Based on numerical simulations, a correlation between the attenuation equation, shear wave velocity, and equivalent damping ratio of rock mass is presented. This novel approach is the first attempt to select the damping ratio from an attenuation relationship. The proposed chart is easy to be used and can be applied in practice.

• Restorative Dentistry and Endodontics
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• v.33 no.4
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• pp.323-331
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• 2008

Flexibility and fracture properties determine the performance of NiTi rotary instruments. The purpose of this study was to evaluate how geometrical differences between three NiTi instruments affect the deformation and stress distributions under bending and torsional conditions using finite element analysis. Three NiTi files (ProFile .06 / #30, F3 of ProTaper and ProTaper Universal) were scanned using a Micro-CT. The obtained structural geometries were meshed with linear, eight-noded hexahedral elements. The mechanical behavior (deformation and von Mises equivalent stress) of the three endodontic instruments were analyzed under four bending and rotational conditions using ABAQUS finite element analysis software. The nonlinear mechanical behavior of the NiTi was taken into account. The U-shaped cross sectional geometry of ProFile showed the highest flexibility of the three file models. The ProTaper, which has a convex triangular cross-section, was the most stiff file model. For the same deflection, the ProTaper required more force to reach the same deflection as the other models, and needed more torque than other models for the same amount of rotation. The highest von Mises stress value was found at the groove area in the cross-section of the ProTaper Universal. Under torsion, all files showed highest stresses at their groove area. The ProFile showed highest von Mises stress value under the same torsional moment while the ProTaper Universal showed the highest value under same rotational angle.

• Journal of the Korean Society of Clothing and Textiles
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• v.32 no.6
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• pp.859-870
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• 2008

The purpose of this study is to investigate the fashion reflecting the aesthetic consciousness of a generation and age spirit and to study Mods-Look aesthetically by analyzing how Mods-Look expressed on the fashion magazines(Collezioni Donna) from 2001 to 2006 developed into a new form. 1960's Mods-Look appeared in the well known collections such as New York, Paris, Milan in the form of crossover or with a changed style. Especially after 2000's, in addition to the British fashion, even a new word Mods Story was created to prominently express the free style of the Mods spirit. The expressive characteristics represent 1) minimal style, 2) sports casual style, 3) vintage style, 4) dandy & androgynous style. In conclusion, Mods-Look in 21st fashion used to be street fashion started from minority subculture after world war II, but now suit of that time, geometrical pattern and sensibility are becoming design sources for the various fashion market from high fashion to sports look. Therefore, as young people are becoming the center of society in new millenium, sensibility of that time will be reinterpreted to design and Mods-Look will not be limited to subculture but reflected in design development fulfilling people's taste and new future fashion sense by compromising the past and new trend.

• Journal of radiological science and technology
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• v.29 no.1
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• pp.13-19
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• 2006

The PET scanner can detect the photon pair arriving from the source in phantom. The number of light photons released by the crystal(scintillator-BGO or LSO). In recent scintillation crystals in block structures were incorporated into full ring systems, and their resulted marked improvement in spatial resolution and increase in a sensitivity to annihilations. The uniformity of the crystal sensitivity is very important to makes correct information of abnormal states in organs. These factors influenced by the dection efficiency of the scintillators. We have study about the uniformity of crystals to the annihilation, And study about the standard deviation to average counts. The relative standard deviation in central detector groups more uniformed than circumferenced detector groups. It is caused detected quanta of gamma ray by the geometrical factors of PET detector. PET cameras are available with different geometric arrangement and several parallel rings oriented in the axial direction. The center groups from 7th to 40th groups are comparatively uniform and sensitive. But at the circumferenced detectors decreased the sensitivity and uniformity.

• Journal of radiological science and technology
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• v.35 no.2
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• pp.173-181
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• 2012

The aim of this study is to compare the geometric characteristics of the lung tumor, such as tumor centroid, HU change relative to breath phase, depending on tumor location and adhesion using 4DCT and deformable image registration program (MIMVista). The Y axis change was most significant and the mean Y axis centroid fluctuation was $7.32{\pm}6.88mm$ in lower lung tumor. The mean HU variation in lower lung mass has changed more than other locations, and its mean HU variation was $7.7{\pm}4.97%$ and non-adhered mass was more changed. Correlation for the mass volume between 3DCT and MIP was very high and its coefficient was 0.998. The effect of tumor location, adhesion and diaphragm excursion to geometric uncertainties was analyzed by linear regression model, it was influenced to mass deformation and geometrical variation so much except diaphragm excursion. but intra-fractional and inter-patient's uncertainties were great, so it couldn't find any exact deformation trend.

• The Journal of Engineering Research
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• v.1 no.1
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• pp.5-14
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• 1997

The purpose of thesis is to analyze the radiation characteristics of an offset gregorian antenna in order to design the satellite-loaded antenna. In order to compute the radiation pattern of the sub-reflector, the reflected wave is obtained by GO(Geometric Optics) at an arbitrary shaped sub-reflector. Then the total radiation EM wave is obtained by summing the diffracted fields obtained by UTD(Uniform Geometrical Theory of Diffraction) and the GO fields. In order to calculate the far field radiation pattern of the main reflector, the radiation integral equation is derived from the induced current density on reflector surface using PO(Physical Optics). The kernel is expanded in terms of Jacobi-Bessel series for increasing the computational efficiency, then the modified radiation integral is represented as the double integral equation independent of observation points. When the incident fields are assumed to be x-or y-polarized field, the characteristics of radiation patterns in the gregorian antenna is analyzed in case of the main reflector having the focal length of 62.4$\lambda$, diameter of 100$\lambda$, and offset height of 75$\lambda$, and the sub-reflector having the eccentricity of 0.501, the inter focal length og 32.8$\lambda$, the horn axis angle of $9^{\circ}$ and the half aperture angle of $15.89^{\circ}$. The cross-polarized level and side lobe level in the offset geogorian reflector are reduced by 30dB and 10dB, respectively, in comparison with those of the offset parabolic antenna.

• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.28-39
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• 1998

This study investigated the natural convection and radiation in a rectangular enclosure with ceiling vent experimentally and numerically. A heat source is located on the center of the bottom surface. The analysis was peformed a pure convection and is combination of natural convection and radiation. The shape of the considered two dimensional model is a square whose center of ceiling($30\%$) is opened. The numerical simulations are carried out for the pure natural convection case and the combined heat transfer case by using the SIMPLE algorithm. For the turbulent flow, Reynolds stresses are closed by the standard $k-{\epsilon}$ model and the wall function is used to determine the wall boundary conditions. The experiment was performed on the same geometrical shape as the computations. The radiative heat transfer is analized by the S-N discrete ordinates method. The results of pure natural convection are compared with those of combined heat transfer by the velocity vectors, stream lines, isothermal lines. The results obtained are as follows 1. Comparing the results of pure convection with those of the combined convection-radiation through the shape of stream lines, isothermal lines are similar to each other. 2. The temperature fields obtained by numerical method are compared to those obtained by experimental one, and it is found that they are showed mean relative error $8.5\%$. 3. Visualization bt smoke is similar to computational results.

• Journal of Radiation Industry
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• v.10 no.4
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• pp.189-192
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• 2016

$^{68}Ga$ has emerged as a promising candidate for non-invasive diagnostic imaging within Positron Emission Tomography (PET) because of its advantageous radiochemical characteristics ($t_{1/2}=68min$, ${\beta}^+$ yield ~89%). $^{68}Ga$ forms a stable chelation with various ligands and it is possible to be quickly and easily study using a $^{68}Ge/^{68}Ga$ generator. Commercial $^{68}Ge/^{68}Ga$ generators are chromatographic system using the inorganic materials such as alumina and tin dioxide which are employed as column matrixes for $^{68}Ge$. In this study, we tried out to make $^{68}Ge/^{68}Ga$ generator system with the $^{68}GeO_2$ microstructures for column matrix. $^{68}Ge$ tends to have stable bond with oxide as $^{68}GeO_2$ microstructures. The $^{68}GeO_2$ has been synthesized by hydrolysis of $GeCl_4$ (sol-gel method) and characterized by X-ray diffraction and scanning electron microscope for geometrical analysis. The stability of $GeO_2$ was tested using eluents with diverse solvents(water, ethanol and 0.1 N HCl). The radioactivity of $^{68}Ga^{3+}$ in eluate through $GeO_2$ was measured to prove a function as column material for a generator.