• Journal of environmental and Sanitary engineering
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• v.18 no.2
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• pp.87-93
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• 2003

This study carried out to recommend adaptable technologies and countermeasures for performance improvement of Wet Scrubber(WS) in industrial waste incinerator. When not using the Activated Carbon(AC), the removal efficiency of dust and HCl is 73%, 92%. And particulate phase and gaseous phase dioxins removal efficiency was evaluated up to 31% and 12%. In this case, dioxins enrichment was not revealed in WS. When using the AC mixing with scrubbing water, the case of 1,000ppm, removal efficiency of particulate phase dioxins was about 51%, and gaseous phase dioxins was about 96%. The case of 2,000ppm, removal efficiency of particulate phase dioxins was about 55%, and gaseous phase dioxins was about 97%. And the case of 3,500ppm, the removal efficiency of particulate phase dioxins was about 35%, and gaseous phase dioxins was about 96% respectively. By this study, using the AC was more useful to remove the gaseous phase dioxins, and needed to use proper concentration of the AC, that in case of 3,500ppm, the particulate phase dioxins removal efficiency was more lower than other cases.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.1
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• pp.52-58
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• 2012

In this study, the effect of standard phase difference in calibration of carbonyl compounds (CC) was evaluated by using their standards prepared in both gaseous and liquid phase. For this analysis, standards in both phases were prepared for 6 different CCs (formaldehyde (FA), acetaldehyde (AA), propionaldehyde (PA), butyraldehyde (BA), isovaleraldehyde (IA) and valeraldehyde (VA)) at similar concentration levels. Their gaseous standard was calibrated after derivatization with three types of DNPH cartridge, and their calibration results were compared against liquid-phase standards. Although there was a strong compatibility between 2 phases for CCs with lower molecular weights (e.g., formaldehyde and acetaldehyde), it was not the case for the heavier CCs. The results of our analysis indicate that the analytical bias of the heavier CCs can be significantly large (by more than a few tens of %). As a result, underestimation of hevier CCs can be significant, if their gaseous samples are quantified by liquid phase standard.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.11a
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• pp.191-194
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• 1996

Maxwell displacement current clearly shows the onset of a first order phase transition from gaseous to gaseous-fluid phase, and polar ordering of liquid molecules in the solid phase coexisting with fluid. For further monolayer compression in the fluid/solid phase transition, the condensation of domains was suggested.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.4
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• pp.269-284
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• 1997

The ambient concentrations of gaseous and particulate phase ionic species and gaseous organic species in the Yochon industrial estate were measured during the spring ans summer of 1996. A three-stage filter pack sampler was used to collect particles and gaseous species, and stainless steel air sampling containers were used to collect air samples for organic species analyses. The concentrations of ions in aerosol wree comparable to those measured in Seoul. Aerosols measured were acidic, thus, most volatile acidic species were in the gas phase. The concentrations of organic species were highly variable, implying those were strongly dependent on the emissions of organic species from petrochemical plants. The concentrations of a few hazardous organic components were higher than those in Seoul or some populated areas in USA.

• Proceedings of the Korean Biophysical Society Conference
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• 2003.06a
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• pp.27-27
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• 2003

Conformations of the +5 to +13 charge state of ubiquitin ions have been studied in the gas phase by an Electron Capture Dissociation (ECD) mass spectrometry (MS) technique. This approach has showed that the conformations of the gaseous ions change from the compact to extended structures as the number of protons on the protein ions increases, consistent with previous collisional cross-section measurements by an ion-mobility MS. However, this observation is in contrast to that of the solution-phase where the unique native structure is usually found. The (un)folding stability and kinetics of these gaseous ions were further investigated experimentally using gradual blackbody-radiation or sudden laser-induced thermal heating, respectively. These studies have provided the evidence that the thermodynamics and kinetics of protein (un)folding in the gas phase are quite different from those of the native aqueous proteins.

• Journal of the Korean Society for Heat Treatment
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• v.1 no.1
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• pp.8-12
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• 1988

This study has been carried out to evaluate gaseous nitrocarburizing treatment undertaken for pure iron at $570^{\circ}C$ in an atmosphere containing 50% endothermic gas, generated from natural gas, and 50% ammonia. The results obtained from the experiment are as follows ; 1) The microstructure of gaseous nitrocarburized pure iron consists of the compound layer on the surface and the diffusion zone beneath it. The compound layer progresses uniformly into ferrite with a thickness of $20{\mu}$ obtained after treating for 3 hours. 2) Chemical analysis has shown that the compound layer has a C/N ratio of 0.19 and that the average combined interstitial content of the compound layer is about 30 atomic percent, which is close to the lower limit of the ${\varepsilon}$-carbonitride phase field in Fe-C-N phase diagram. 3) X-ray diffraction analysis has revealed that the compound layer consists mainly of the c.p.h. phase, ${\varepsilon}-Fe_3$(C.N) and a small amount of $Fe_4N$ and traces of ferrite are also present in the compound layer. 4) The microhardness of the compound layer is about 600 V.H.N and shows a relatively sharp fall-off at the compound layer/diffusion zome interface. 5) The average actual degree of ammonia dissociation is calculated to be 27% for a gaseous nitrocarburizing treatment carried out at $570^{\circ}C$.

• Korean Journal of Materials Research
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• v.16 no.1
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• pp.50-57
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• 2006

Phase mixtures of Titanium boride, nitride, and carbide powder were produced by the reduction of a mixture of titanium and boron oxides with carbon via a gas-solid phase reaction. Boron oxides produce a vapour phase or decompose to a metal sub-oxide gaseous species when reduced at elevated temperature. The mechanism of BO sub-oxide gas formation from $B_2O_3$ and its subsequent reduction to titanium diboride for the production of uniform size hexagonal platelets is explained. These gaseous phases are critical for the formation of boride, nitride and carbide ceramics. For the production of ceramic phase composite microstructures, the nitrogen partial pressure was the most critical factor. Some calculated equilibrium phase fields has been verified experimentally. The theoretical approach therefore identifies conditions for the formation of phase mixtures. The thermodynamic and kinetic factors that govern the phase constituents are also discussed.

• Proceedings of the Optical Society of Korea Conference
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• 2002.07a
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• pp.248-249
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• 2002

The gaseous molecular condensation retardation by laser excitation has been known, but with limited success. Condensation inhibition between the gas phase molecules by laser excitation was clearly shown in many experiments.(1)-(2) However, surface condensation inhibition of the excited molecules has been controversial for the last several decades.(3)-(4) In 1994, S. J, Sibener and Y. T. Lee published an experimental evidence of the internal energy dependence of the surface condensation of gaseous $SF_{6}$ and $CCl_4$ molecules. (omitted)

• Journal of the Korean Society for Heat Treatment
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• v.16 no.2
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• pp.71-77
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• 2003

We investigate the phase formation in the compound layer of cast irons during the gaseous nitrocarburising of four different cast irons, that contain different types of graphites in the shape and size. We examine the change in the surface roughness with the nitrocarburising time. The observation of cross-sectional microstructure and X-ray diffraction analysis indicate that the compound layer consists of single ${\varepsilon}-Fe_{2-3}(N,C)$ phase and that its thickness increases in a parabolic manner with the treatment time. The surface roughness parameters, Rz and Ra increase with increasing treatment time. In other words, the roughness parameters increase as the thickness of compound layer increases. The parameters also depend on the shape and size of graphite in the individual cast irons.

• 한국생물공학회:학술대회논문집
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• 2000.11a
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• pp.73-76
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• 2000

A novel, continuous bioreactor system combining a bubble column (absorption section) and a two-phase bioreactor (degradation section) has been designed to treat a gas stream containing benzene. The bubble column contained hexadecane as an absorbent for benzene, and was systemically chosen considering physical, biological, environmental, operational and economic factors. This solvent has infinite solubility for benzene and very low volatility. After absorbing benzene in the bubble column, the hexadecane served as the organic phase of the two-phase partitioning bioreactor, transferring benzene into the aqueous phase where it was degraded by Alcaligenes xylosoxidans Y234. The hexadecane was then continuously recirculated back to the absorber section for the removal of additional benzene. All mass transfer and biodegradation characteristics in this system were investigated prior to operation of the integrated unit, and these included: the mass transfer rate of benzene in the absorption column, the mass transfer rate of benzene from the organic phase into the aqueous phase in the two-phase bioreactor, the stripping rate of benzene out of the two-phase bioreactor, etc. All of these parameters were incorporated into model equations, which were used to investigate the effects of operating conditions on the performance of the system. Several experiments were conducted to show the feasibility of this system. This process is believed to be very practical for the treatment of high concentrations of gaseous pollutants.