• 제목/요약/키워드: Gas-phase Analysis

검색결과 882건 처리시간 0.026초

Leidenfrost Points Tuned via Surface Coating and Structures

  • Jeon, Deok-Jin;Lee, Jun-Young;Yeo, Jong-Souk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.126.1-126.1
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    • 2015
  • A quantitative relationship between Leidenfrost point and surface characteristics such as surface material and roughness is investigated. Based on the relationship, we have fabricated the surfaces with their Leidenfrost points (LFP) tuned by controlling surface coating and structures. As discovered by Leidenfrost, liquids placed on a hot plate levitate on the gas phase-air gap formed by the vaporization of liquids. This phenomenon is called 'Leidenfrost effect'. A change of LFP has attracted many researchers for several years but the ability to tune LFP is still a remaining issue. Many of previous work has progressed for various conditions so the systematic approach and analysis are needed to clearly correlate the LFP and the surface conditions. In this report, we investigate a relation of surface energy and LFP using various coating materials such as Octadecyltrichlorosilane (OTS) and 1H, 1H, 2H, 2H-Perfluorooctyltrichlorosilane (FOTS). Also, we analyze how surface roughness affects LFP via surface micro structuring with ICP-RIE fabrication process. The improved understanding can have potential applications such as the control of liquid droplet behavior at elevated temperatures for efficient cooling system.

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고온기류중에 재분사된 연소기 후류의 수치해석 (Numerical simulation of combustor afterward sprayed in hot product stream)

  • 김태한;권형정
    • 대한기계학회논문집B
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    • 제21권7호
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    • pp.841-848
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    • 1997
  • Combustion of gaseous fuel combustor in a high temperature vitiated air stream was studied with computer simulation. It is for application to afterburner of gas turbine engine which the exact mechanism is not yet clarified. As the jet velocity from fuel nozzle is very high and the geometry of combustor is three dimensional complex structure, many time and money are required to have good results. To consider this demerit, it is simplified to 2-dimensional and modified with the nozzle hole area to same area of annual status. As the thickness of annual is too thin, it is to divide with the many grids for reasonable results. Accordingly, new method which injected fuel mass, momentum and energy are added to source terms of each governing conservation equation as a source terms is introduced like as two phase analysis. Reaction rate is determined by taking into account the Arrhenius reaction based on a single step reaction mechanism. It is focused to temperature and product concentration distribution at each equivalence ratio of inlet hot product.

Fe-Based Nano-Structured Powder Reinforced Zr-Based Bulk Metallic Glass Composites by Powder Consolidation

  • Cho, Seung-Mok;Han, Jun-Hyun;Lee, Jin-Kyu;Kim, Yu-Chan
    • 한국재료학회지
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    • 제19권9호
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    • pp.504-509
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    • 2009
  • The Zr-based bulk metallic glass matrix composites of a mixture of gas-atomized metallic glass powders and Fe-based nanostructured powders were fabricated by spark plasma sintering. The Fe-based nanostructured powders adopted for the enhancement of plasticity were well distributed in the matrix after consolidation, and the matrix remains as a fully amorphous phase. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering. Unlike other amorphous matrix composites, in which improved ductility could be obtained at the expense of their strength, the developed composite exhibited improvement both in strength and ductility. The ductility improvement in the composite was considered to be due to the formation of multiple shear bands under the presence of the Fe-based nanostructured particles.

스월변화에 따른 모형 가스터빈 연소기의 열유동장의 실험적 연구 (Experimental Study of Thermo-Flow Field in a Model Gas Turbine Combustor with Various Swirl Conditions)

  • 류송열;구자예
    • 한국항공우주학회지
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    • 제30권4호
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    • pp.70-76
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    • 2002
  • 가스터빈 연소기의 스월러와 노즐을 제작하여 스월러 형상 변화에 따른 비연소시 케로신 분무 특성과 연소시에 열유동장의 특성을 조사하였다. 액적의 크기(SMD)와 속도를 파악하기 위해서 위상도플러입자분석기(PDPA)를 이용하였고, 연소 온도를 조사하기 위해서 R-type 열전대(Platinum vs. Platinum-13%rhodium)를 이용하였다. 분무와 화염의 가시화는 스틸 카메라를 이용하였다. 스월러각이 커서 스월수가 큰 경우에 분무 및 화염이 반경방향으로 빠르게 발전하였다. 화염은 스월수가 작을 때는 원추형의 화염이 형성되지만 스월수가 커지면서 스월 모멘텀이 중심축으로 이송되고 혼합이 촉진되어 원통형으로 바뀌었다.

SIMULATION OF UNIT CELL PERFORMANCE IN THE POLYMER ELECTROLYTE MEMBRANE FUEL CELL

  • Kim, H.G.;Kim, Y.S.;Shu, Z.
    • International Journal of Automotive Technology
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    • 제7권7호
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    • pp.867-872
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    • 2006
  • Fuel cells are devices that convert chemical energy directly into electrical energy. Owing to the high efficiency of the fuel cells, a large number of research work have been done during these years. Among many kinds of the fuel cells, a polymer electrolyte membrane fuel cell is such kind of thing which works under low temperature. Because of the specialty, it stimulated intense global R&D competition. Most of the major world automakers are racing to develop polymer electrolyte membrane fuel cell passenger vehicles. Unfortunately, there are still many problems to be solved in order to make them into the commercial use, such as the thermal and water management in working process of PEMFCs. To solve the difficulites facing the researcher, the analysis of the inner mechanism of PEMFC should be implemented as much as possible and mathematical modeling is an important tool for the research of the fuel cell especially with the combination of experiment. By regarding some of the assumptions and simplifications, using the finite element technique, a two-dimensional electrochemical mode is presented in this paper for the further comparison with experimental data. Based on the principals of the problem, the equations of electronic charge conservation equation, gas-phase continuity equation, and mass balance equation are used in calculating. Finally, modeling results indicate some of the phenomenon in a unit cell, and the relationships between potential and current density.

교외지역에서 대기 중 Hexachlorocyclohexane의 농도분포 및 온도 의존성 (The Concentration Distribution and Temperature Dependence of Hexachlorocyclohexane in Rural Atmosphere)

  • 최민규;여현구;김태욱;천만영;선우영
    • 한국대기환경학회지
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    • 제18권3호
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    • pp.183-192
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    • 2002
  • Concentrations of $\alpha$- and ${\gamma}$-hexachlorocyclohexane (HCH) were measured in ambient air samples at a two week intervals between July 1999 and February 2000 at Ansung, Kyonggi province. Their concentration levels averaged at 78 ($\alpha$-HCH) and 18 pg/m$^3$(${\gamma}$-HCH). Although the use of HCHs was ceased in South Korea since 1979, their residues are still present in air even after nearly 20 years. Given the composition of the two main HCH pesticide formulation (technical HCH antral lindane), the $\alpha$/${\gamma}$-HCH ratio in air is a useful indicator on the regional scale. The moderately low $\alpha$/${\gamma}$-HCH ration in this study indicates previous usage of both technical HCH and lindane. The relationship of temperature with gas-phase partial pressures was also examined using the Clausius-Clapeyron equation. Slopes generated by linear regression analysis between partial pressure (In P) and 1/T were considerably steep thor HCHs. It is thus suggested that their concentrations are controlled by re-volatilization processes from surfaces in the local surroundings of the sampling site.

Sulfate Reduction at pH 5 in a High-Rate Membrane Bioreactor: Reactor Performance and Microbial Community Analyses

  • Bijmans, Martijn F. M.;Dopson, Mark;Peeters, Tom W. T.;Lens, Piet N. L.;Buisman, Cees J. N.
    • Journal of Microbiology and Biotechnology
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    • 제19권7호
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    • pp.698-708
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    • 2009
  • High rate sulfate reduction under acidic conditions opens possibilities for new process flow sheets that allow the selective recovery of metals from mining and metallurgical waste and process water. However, knowledge about high-rate sulfate reduction under acidic conditions is limited. This paper investigates sulfate reduction in a membrane bioreactor at a controlled pH of 5. Sulfate and formate were dosed using a pH-auxostat system while formate was converted into hydrogen, which was used for sulfate reduction. Sulfide was removed from the gas phase to prevent sulfide inhibition. This study shows a high-rate sulfate-reducing bioreactor system for the frrst time at pH 5, with a volumetric activity of 188 mmol $SO_4^{2-}$/I/d and a specific activity of 81 mmol $SO_4^{2-}$volatile suspended solids/d. The microbial community at the end of the reactor run consisted of a diverse mixed population including sulfate-reducing bacteria.

SiC의 선택적 증착에 관한 연구 (A study on the SiC selective deposition)

  • 양원재;김성진;정용선;오근호
    • 한국결정성장학회지
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    • 제8권2호
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    • pp.233-239
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    • 1998
  • 화학기상증착법을 이용하여 tetramethylsilane(TMS)과 hexamethyldisilane(HMDS)으로부터 SiC층을 증착시켰다. 반응관 내의 압력은 1torr를 유지시켰으며, $H_2$ 가스를 사용하여 precursor를 반응로내로 수송하였고 $1200^{\circ}C$의 반응온도로 SiC 증착이 이루어졌다. 기판은 tantalum으로 masking한 Si-wafer와 platinum, molybdenum으로 masking한 MgO 단결정을 사용하였다. 금속층(Ta, Pt, Mo)에서의 SiC 증착 양상과 Si, MgO 위에서의 SiC 증착 양상을 비교함으로써 SiC 증착의 선택성을 관찰하였다. 증착층의 주된 상은 X-선 회절분석에 의해 $\beta-SiC$로 확인되었다. 또한 전자현미경 분석을 통해 각 층에서의 증착 양상의 차이를 조사하였다.

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드럼형 회전연료노즐의 미립화 기구 및 분무특성 연구 (The Atomization Mechanism and Spray Characteristics of Drum Type Rotary Atomizer)

  • 이동훈;최현경;최성만;유경원;허환일
    • 한국추진공학회지
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    • 제12권2호
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    • pp.57-65
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    • 2008
  • 가스터빈엔진에 적용할 수 있는 드럼형 회전연료노즐의 모델링을 통해 원심력이 충분한 연료분사압력을 발생시킴을 보였고, 회전연료분사의 미립화 현상에 대해 실험적으로 연구하였다. 회전연료분사의 미립화기구 및 분무특성을 이해하기 위하여 고속 회전연료노존 시험리그를 이용하여 $5,000\;{\sim}\;40,000rpm$의 영역에서 분무가시화와 PDA를 이용한 분무액적 측정을 실시하여 회전연료분무의 미립화 특징을 규명하고, 미립화성능 향상을 위해서는 회전속도증가를 통해 액적분열시점을 앞당기는 것이 중요함을 알았다.

유동층 연소로의 스케일-업을 위한 유동층 내 연료농도분포 해석 (Analysis on the fuel concentration distribution in a fluidized bed for the scale-up of a FBC)

  • 이동우;박승호
    • 대한기계학회논문집B
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    • 제21권6호
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    • pp.747-757
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    • 1997
  • A numerical investigation of the fuel concentration field in a fluidized bed has been carried out for the scale-up of a fluidized bed combustor (FBC). A two-dimensional transient model is developed using the two-phase fluidization, a simple chemical reaction, and lateral solid mixing theories. The uniformity of fuel concentration distributions is controlled by the location and the number of fuel feeders, fluidizing velocities and the bed-heights. While larger bubbles owing to greater fluidizing velocities enhance the fuel-dispersion in the bed, they have adverse effects on fuel combustion and thus result in the increase of fuel concentration, since a greater bubble means a larger bypass which reduces gas-exchange rates between bubble and emulsion phases. Average or maximum values of the bed fuel concentration are utilized as criteria for the scale-up from a pilot/lab-scale to a commercial-size bed.