• Environmental Engineering Research
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• v.11 no.1
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• pp.33-44
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• 2006

The objective of this study was to develop and assess a method for estimating the rain scavenging ratios (RSRs) of particle-bound PAHs and PCBs using measured scavenging ratio of particulate matters (PM) and routinely available data of physico-chemical properties of PM. Paired atmospheric and rainwater sampling was conducted for a total of 4 rain events. Assuming equilibrium partitioning in rainwater-gas-PM system, an equation was derived for estimating the RSR of particle-bound chemicals as a function of RSR of PM and three equilibrium partition constants (i.e. dimensionless Henry's law constant, gas-particle partition coefficient, and water-particle partition coefficient). For all PAHs, the model significantly under-predicted the RSR while the model prediction for PCBs agreed with observation mostly within a factor of 5. The RSR model for the chemicals is of limited use as its accuracy critically depends on how close the observed partitioning of the chemicals in the gas-PM-rainwater system is to that estimated under the equilibrium assumption.

• Particle and aerosol research
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• v.6 no.4
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• pp.151-164
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• 2010

Inorganic ions and water are major components of ambient fine particles. Water content in fine particles is mainly determined by ambient meteorological conditions and the concentrations of hygroscopic species such as inorganic ions. Thus, to reduce fine particle mass concentration, it is important to accurately estimate the relationship between water content and the concentration of ions in fine particles. Water content in fine particles in Seoul are estimated by using a gas/particle equilibrium model to understand the characteristics of fine particle mass concentration. In addition, sensitivity of fine particle mass concentration to the changes of particulate ionic species (sulfate, nitrate, and ammonium) is estimated. It was found that water content in Seoul is mostly determined by the concentrations of the hygroscopic ionic species, especially, sulfate and ammonium, and ambient relative humidity.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.1
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• pp.94-102
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• 2010

Water content of $PM_{2.5}$ (particles in the atmosphere with a diameter of less than or equal to a nominal $2.5{\mu}m$) was estimated by using a gas/aerosol equilibrium model, SCAPE2, for the particles collected at Seoul and Gosan, Korea. From measured and analyzed characteristics of the particles, the largest difference between Seoul and Gosan is the proportions of total ammonia (t-$NH_3$=gas phase $NH_3$+particle phase ${NH_4}^+$), total nitric acid (t-$HNO_3$=gas phase $HNO_3$+particle phase ${NO_3}^-$) and sulfuric acid ($H_2SO_4$). Even though both sites have sufficient t-$NH_3$ to neutralize acidic species such as $H_2SO_4$, t-$HNO_3$, and t-HCl (total chloric acid=gas phase HCl+particle phase $Cl^-$), equivalent fraction of t-$NH_3$ and t-$HNO_3$ are higher at Seoul and $H_2SO_4$ is higher at Gosan. Based on the modeling result, it is identified that the $PM_{2.5}$ at Seoul is more hygroscopic than Gosan if the meteorological conditions are the same. To reduce water content of $PM_{2.5}$, and thus, mass concentration, control measures for ammonia and nitrate reduction are needed for Seoul, and inter-governmental cooperation is required for Gosan.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.6
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• pp.803-810
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• 2004

Water contents in fine particles at Seoul and Gosan are estimated by using a gas/particle equilibrium model, SCAPE (Simulating Composition of Atmospheric Particles at Equilibrium). Also, sensitivity of particulate inorganic ionic concentrations on the total ionic species is estimated. Water content at Gosan is more sensitive to ambient relative humidity (RH) than Seoul. At both sites water content is most sensitive to sulfate concentration among sulfate, nitrate, and ammonium. Solid salts levels and compositions are also studied.

• Advances in environmental research
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• v.1 no.1
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• pp.69-82
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• 2012

Based on the measurement data of the particulate matter with an aerodynamic diameter of less than or equal to a nominal 10 ${\mu}m$ (PM10) by the ${\beta}$-ray absorption method (BAM) equipped with an inlet heater and the gravimetric method (GMM) at two coastal sites in Korea, the optimal inlet heater temperature was estimated. By using a gas/particle equilibrium model, Simulating Composition of Atmospheric Particles at Equilibrium 2 (SCAPE2), water content in aerosols was estimated with varying temperature to find the optimal temperature increase to make the PM10 concentration by BAM comparable to that by GMM. It was estimated that the heated air temperature inside the BAM should be increased up to $35{\sim}45^{\circ}C$ at both sites. At this temperature range, evaporation of volatile aerosol components was minor. Similar ($30{\sim}50^{\circ}C$) temperature range was also obtained from the calculation based on the absolute humidity which changed with ambient absolute humidity and chemical composition of hygroscopic species.

• Journal of the Semiconductor & Display Technology
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• v.17 no.1
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• pp.76-83
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• 2018

The electron energy probability function (EEPF) is of significant importance since the plasma chemistry such as the rate of ionization is determined by the electron energy distribution function. It is usually assumed to be Maxwell distribution for 0-D global model. Meanwhile, it has been observed experimentally that the form of EEPF of Ar plasma changes from being two-temperature to Druyvesteyn like as the gas pressure increases. Thus, to apply the 0-D global model of Maxwellian distribution to the non-Maxwellian plasma, we investigated the relative contribution of two distinct electrons with different temperatures. The contributions of cold/hot electrons to the equilibrium state of the plasma have attracted interest and been researched. The contributions to the power and particle balance of cold/hot electrons were studied by comparing the result of the global model considering all combinations of electron temperatures with that of 1-D Particle-in-Cell and Monte Carlo collision (PIC-MCC) simulation and the results of studies were analyzed physically. Furthermore, comparisons term by term for variations of the contribution of cold/hot electrons at different driving currents are presented.

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.1
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• pp.69-76
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• 1995

Water content and strong acidity are estimated for ambient particles measured between Fall, 1991 and Summer, 1992 in Seoul using a gas/aerosol equilibrium model, called SCAPE. Particle water content and formation of solid species are closely related to ambient relative humidity and ionic concentrations. Generally, water content of particles is high during the night and summer. Estimated particle strong acidity level of Seoul is similar to that of Los Angeles, U.S.A. Acidity of wet and dry depositions in Seoul is discussed.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.2
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• pp.113-120
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• 2000

Effects of sea-salts on the properties of aerosol collected in a coastal region were studied by applying a gas-particle equilibrium model SCAPE to the measurement data from Korea Cheju Island in summer 1994. It was found that the observed higher ammonium concentrations in fine particles (PM2.5) than in TSP were caused by forced evaporation of ammonium in coarse fraction of aerosol by sea-salts and the degree of evaporation was quantified through an application of SCAPE. By subtracting the sea-salt fraction from the measured concentra-tions the changes of aerosol property were also studied. The concentrations of nitrate at both TSP and PM2.5 decreased when alkaline sea-salt fraction was removed from the measured data. Estimates of aerosol acidity increased for most samples with sea salt loadings, However in some cases with high mass fractions of sea-salt components the aerosol acidity of PM2.5 decreased slightly. This is though to be related with the formation of solid salt with the removal of sea-salts.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.3
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• pp.289-296
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• 1996

Effects of crustal species on the characteristics of ambient particles were studied by applying a gas-particle equilibrium model, SCAPE, to the measurements at Kosan, Cheju Island during the spring and summer, 1994. Two cases were simulated; the measured composition was used without any modification (case 1), and the metal ion concentrations originated from crust were subtracted from the measured particle composition (case 2). Total suspended particles (TSPs) were collected by an automatic high volume tape sampler during spring period and by high volume samplers during summer period. The fine particles, PM 2.5, and gaseous volatile species were collected using a filter pack smapler during summer period. The water soluble ion concentrations were analyzed from all the particle samples. According to the simulation results, the effect of crustal elements on the chemical composition of particles is negligible for both TSP particles and PM 2.5 particles. Acidity of particles measured at Kosan, however, is affected by the change of the concentrations of crustal species, stronger effects for TSP particles than for PM 2.5 particles during summer, and stronger effects during summer than spring for TSP particle. The average pH decrease due to the absence of crustal species was about 0.10 for PM 2.5 particle during summer and 1.51 and 0.85 for TSP particles during summer spring, respectively. Water contents of PM 2.5 particles for both cases are comparable to each other. Estimated water content of TSP particles for case 2 is higher than that for case 1 by about 4 $\sim 6 \mum/m^3$ because salts of metal ions are not hygroscopic.

• Asian Journal of Atmospheric Environment
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• v.4 no.1
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• pp.55-61
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• 2010

The sensitivity of aerosol light extinction coefficient to the aerosol chemical composition change is estimated by (1) calculating the aerosol water content and chemical concentrations by a gas/particle equilibrium model and (2) calculating the aerosol light extinction coefficient by a Mie theory based optical model. The major chemical species are total (gas and particle phase) sulfuric acid, total nitric acid, and total ammonia which are based on the measurement data at Seoul and Gosan. At Seoul, since there were enough ammonia to neutralize both total sulfuric acid and total nitric acid, the dry ionic concentration is most sensitive to the variation of the total nitric acid level, while the total mass concentration (ionic concentration plus water content) and thus, the aerosol light extinction coefficient are primarily determined by the total sulfuric acid. At Gosan, since the concentration of ambient sulfuric acid was the highest among the inorganic species, sulfate salts determined aerosol hygroscopicity. Thus, both ionic and total mass concentration, and resultant aerosol light extinction coefficient are primarily determined by the sulfuric acid level.