• Title/Summary/Keyword: Gas-in-Oil

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Thermal Destruction of Waste Insulating Oil Containing PCBs under High Temperature and Pressurized Conditions

  • Seok, Min-Gwang;Lee, Gang-Woo;Lee, Jae-Jeong;Kim, Min-Choul;Kim, Yang-Do;Jung, Jong-Hyeon;Shon, Byung-Hyun
    • Environmental Engineering Research
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    • v.17 no.3
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    • pp.157-165
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    • 2012
  • This experimental study was performed to obtain thermal energy from the combustion of synthetic gas, produced by the pyrolysis of insulating oil containing polychlorinated biphenyls (PCBs) in a high temperature and high pressure reactor. The average synthetic gas generated was $59.67Am^3/hr$ via the steady state gasification of insulating oil waste (20 kg/hr) with average concentrations (standard deviation) of $CO_2$, CO, and $H_2$ in the synthetic gas of $38.63{\pm}3.11%$, $35.18{\pm}1.93%$, and $28.42{\pm}1.68%$, respectively. The concentrations of the PCBs in the transformer insulating oil and synthetic gas after its gasification, and the concentrations of the dioxins that could be produced from the incomplete degradation of PCBs were measured. It was revealed that the PCBs in the insulating oil were composed of the series from tetrachlorobiphenyl to octachlorobiphenyl. However, only the #49, #44, #52, and #47/75/48 congeners were detected from the synthetic gas after gasification of the insulating oil and in the flue gas from the combustor. In conclusion, the experimental conditions suggested in this study were very useful for the appropriate treatment of insulating oil containing PCBs. Also, fuel gas containing CO and $H_2$ can be obtained from the pyrolysis of insulating oil containing PCBs.

Study on $H_2$ Sensing Characteristics of Gas Extractor for Dissolved Gas in Oil (유중 가스 검출장치의 수소 가스 감지 특성에 관한 연구)

  • Hwang, Kyu-Hyun;Seo, Ho-Joon;Rhie, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1162-1165
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    • 2004
  • In oil-filled enuipment such as transformers, partial discharge or local overheating will precede a final shutdown. Accompanied with such problems is a decomposition of insulating material into gases, which are dissolved into the transformer oil. The gases dissolved in oil can be separated with some membranes based on the differences in permeability of membranes to different gases. This paper discuss the permeability characteristics of several membranes for separation hydrogen gas in oil. With result of this paper, it may become possible to detect fault-related gases from transformer oil and predict incipient failures in the future.

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Structural Safety Evaluation of a 3-way Damper Valve for Scrubber-linked Exhaust Gas Control (스크러버 연계 배기가스 배출제어용 3방향 댐퍼밸브의 구조 안전성 평가)

  • Kim, Young-Hun
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.6_2
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    • pp.1007-1014
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    • 2020
  • IMO(International Maritime Organization) continues to strengthen environmental regulations on exhaust gases such as CO2, NOx, SOx. As for sulfur oxides, from 1 January 2020, all ships on international voyages must use fuel with a sulfur content of 0.5% or less. Or, it is obligatory to use an exhaust gas treatment device that has the same effect. Shipping companies are using low-sulfur oil, replacing them with LNG fuel, or installing scrubbers that suppress sulfur oxide emissions. In the case of ships using bunker C oil, the load on the engine is lower when entering and departing, so the exhaust gas pressure is lowered and the scrubber cannot be properly utilized. Therefore, diesel oil with low sulfur content is used when entering and leaving the coast. When diesel oil is used, exhaust gas is directly discharged through the control system and piping system, and when bunker C oil is used, sulfur oxides are reduced by scrubbers through other control systems and piping systems to discharge exhaust gas. Accordingly, a company has developed a system called a three-way damper valve that can control exhaust gas emissions while integrating these two control systems and piping systems into one. In this study, the control characteristics of the integrated exhaust gas control system and structural safety against external loads in a high-temperature exhaust gas environment were reviewed.

Ultrasonication-Induced Changes in Physicomechanical and Tribotechnical Properties of PTFE Composites

  • Argunova, Anastasiia G.;Petrova, Pavlina N.;Okhlopkova, Aitalina A.;Shadrinov, Nikolay V.;Gogoleva, Olga V.;Cho, Jin-Ho
    • Journal of the Korean Chemical Society
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    • v.59 no.3
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    • pp.233-237
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    • 2015
  • The effect of ultrasonication on PTFE and its composites with zeolite and fluoroplast F-4NTD-2 was studied. Ultrasonication was found to cause changes in the supramolecular structure, and consequently, the tensile strength, relative elongation, and mass wear rate. Changes in the topology of the materials following ultrasonication were investigated by scanning electron microscopy. The optimum enhancement of the desired properties was found in the PTFE composite containing 2% activated zeolite.

A Study on the Effectiveness of Sanctions against Russian Energy Sector-Focusing on the Oil and Gas Sector (대러 에너지 제재의 효과성에 대한 연구 -석유가스 부문을 중심으로)

  • Won-Soon Kwon;Ju-young Ko
    • Korea Trade Review
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    • v.48 no.1
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    • pp.165-191
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    • 2023
  • The US and EU have imposed energy sanctions on the Russian oil and gas sector in response to the Ukraine crisis. One of the key measures is to cut oil and gas imports from Russia. The US and EU are both the senders of sanctions against Russia. However, there is a fundamental difference between them. While the US is the net oil and gas exporter, most EU member states are heavily dependent on Russian oil and gas. If the US and other major oil and gas exporting countries can replace Russia in the EU energy market, the effectiveness of energy sanctions against Russia can be guaranteed. Our result shows that it is difficult for the major oil and gas exporters to fully replace Russia in the short run because of the lack of additional production capacity and infrastructure. We conclude that the US and EU's energy sanctions against Russia can not guarantee its effectiveness. We argue that other measures, such as diplomacy, should be taken to settle the conflicts in Ukraine.

Numerical Analysis of Flow Characteristics of the Filter for Separating Oil Mist from Blow-by Gas (블로바이 가스 내 오일입자들을 제거하기 위한 필터의 유동특성 수치해석)

  • Yun, Jeong-Eui;Chae, Kangseog;Kang, Hyukjin;Chung, Doyoung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.5
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    • pp.549-555
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    • 2016
  • This research was performed to determine the oil separation characteristics of the specially designed oil filter installed in a PCV cylinder head passage. The oil filter was specially designed with fleece for separating oil mist from blow-by gas. The fleece, made of fiber fabric material, is placed in the oil filter case to absorb oil mist with a small pressure drop during blow-by gas through the filter. To do this, 3-D CFD analysis was simulated for the simplified PCV system with the oil filter using the commercial code, Ansys CFX. Results showed that the oil filter's efficiency with fleece sharply increased as oil droplet size increased.

Headspace gas chromatographic analysis as an objective method for measuring rancidity in soybean oil (Headspace 가스크로마토그라피를 이용한 대두유 산화진행도의 객관적 평가방법)

  • Chun, Ho-Nam;Kim, Ze-Uook
    • Applied Biological Chemistry
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    • v.34 no.2
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    • pp.154-161
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    • 1991
  • An objective method for measuring rancidity in soybean oil was developed based on the volatile contents obtained by headspace gas chromatographic analysis. Apparatus for headspace volatile cold trapping-thermal desorption was described, designed to collect and analyze volatiles of soybean oil. Samples of commercially processed soybean oil were stored under controlled condition and then evaluated for flavor by a eight member trained panel and for volatile contents by headspace gas chromatographic analysis. Twenty-three GC peaks were identified on the basis of relative retention time of reference compounds and gas chromatography-mass spectrometry. The volatile compounds identified were autoxidation products of principal unsaturated fatty acids of soybean oil. The simple linear regressions of flavor score with the pentanal or hexanal contents in aged soybean oil gave correlation coefficient of 0.990 and 0.994. respectively. Pentanal and hexanal contents could be used as a potentially useful index for predicting flavor scores of soybean oil.

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An Analytical Evaluation on the flue Gas and Combustion Efficiency of Emulsion Fuel (에멀죤 연료의 연소 배출가스특성 및 연소 효율에 관한 분석평가)

  • Park, Hyun-Mee;Eo, Yun-Woo;Baig, Seung-Woo;Park, Il Yong;Paeng, Ki Jung;Kim, Young-Man;Lee, Kang-Bong
    • Analytical Science and Technology
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    • v.15 no.5
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    • pp.427-432
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    • 2002
  • The combustion behavior of heavy oil and its emulsion with water was evaluated. The concentration of $SO_x$ in the combustion gas of emulsion oil was reduced to 57% with respect to that of the combustion gas from neat heavy oil. Also, the concentration of $NO_x$ in the combustion gas of emulsion oil was reduced to 67% with respect to that of the combustion gas of neat heavy oil. These reductions of $SO_x$ in the combustion gas of emulsion oil seems to be due to the reaction with salts included in surfactant of emulsion oil. Also, the combustion efficiency of emulsion oil is evaluated to be about 6% higher than that of neat heavy oil.

Review on the Relationship of Dissolved Gas Analysis and Internal Inspection of Transformer (변압기 절연재료 분석과 내부점검 결과와의 상관성 연구)

  • Park, Hyun-Joo;Nam, Chang-Hyun;Jung, Nyun-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.10
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    • pp.1869-1873
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    • 2010
  • For reliable operation of oil-filled electrical equipment, monitoring and maintenance of insulating oil is essential. Dissolved gas analysis(DGA) is widely used for monitoring faults in high voltage electrical equipment in service. Therefore, oil analysis should be monitored regularly during its service life. KEPCO has investigated thousands of dissolved gas analysis data since 1985, and conducted studies on the relationship of gas in oil analysis and internal inspection results of transformer. As the results, KEPCO revised criteria for transformer diagnosis and has applied it since 2008. Almost of 100 cases of internal inspection results since 2001 have been investigated. This paper presents the correlation of the fault-identifying gases with faults found in actual transformers and how should we approach to internal inspection of transformer by dissolved gas analysis.

Estimation of Economic Effects on Overseas Oil and Gas E&P by Macroeconomic Model of Korea (거시경제모형을 이용한 해외석유가스개발사업의 경제적 효과 추정 연구)

  • Kim, Ji-Whan;Chung, Woo Jin;Kim, Yoon Kyung
    • Environmental and Resource Economics Review
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    • v.23 no.1
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    • pp.133-156
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    • 2014
  • In general, quantity results of empirical analysis using model shows how much big performance policy has. Therefore this is useful to evaluate a policy. This paper composed macro economic model based on Bank of Korea's quarterly model and annual model, that estimates performance of overseas oil and gas development project to Korean economy in aspect of quantity. In this model, we estimated each effect in real GDP, current account, unemployment rate, CPI and exchange rate carried by recovered amount from overseas oil and gas development project. The recovered amount was evaluated in currency coming from oil and gas acquired from overseas oil and gas development project. Macro economic model of this paper benchmarked macro model composed by Bank of Korea(1997, 2004, 2012). We reviewed model robustness using statistical suitability of each equation and historical simulation for from 1994 to 2011. The recovered amount of overseas oil and gas development project has positive effect in every macro economic index except CPI and exchange rate. Economic effect to macro economic index become bigger with time because the recovered amount of overseas oil and gas development project are increasing until now. Although empirical results of economic effects in every year from the recovered amount of overseas oil and gas development project are different, as of 2011, empirical results showed that the recovered amount of overseas oil and gas development project increase 2.226% and 0.401% in current account and real GDP respectively. And it also decrease 0.489%p in unemployment rate. Exchange rate to US dollars also decrease in amount of 0.379%.