• Title/Summary/Keyword: Gas-combined

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Study on the channel of bipolar plate for PEM fuel cell (고분자 전해질 연료전지용 바이폴라 플레이트의 유로 연구)

  • Ahn Bum Jong;Ko Jae-Churl;Jo Young-Do
    • Journal of the Korean Institute of Gas
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    • v.8 no.2 s.23
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    • pp.15-27
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    • 2004
  • The purpose of this paper is to improve the performance of Polymer electrolyte fuel cell(PEMFC) by studying the channel dimension of bipolar plates using commercial CFD program 'Fluent'. Simulations are done ranging from 0.5 to 3.0mm for different size in order to find the channel size which shoves the highst hydrogen consumption. The results showed that the smaller channel width, land width, channel depth, the higher hydrogen consumption in anode. When channel width is increased, the pressure drop in channel is decreased because total channel length Is decreased, and when land width is increased, the net hydrogen consumption is decreased because hydrogen is diffused under the land width. It is also found that the influence of hydrogen consumption is larger at different channel width than it at different land width. The change of hydrogen consumption with different channel depth isn't as large as it with different channel width, but channel depth has to be small as can as it does because it has influence on the volume of bipolar plates. however the hydrogen utilization among the channel sizes more than 1.0mm which can be machined in reality is the most at channel width 1.0, land width 1.0, channel depth 0.5mm and considered as optimum channel size. The fuel cell combined with 2cm${\times}$2cm diagonal or serpentine type flow field and MEA(Membrane Electrode Assembly) is tested using 100W PEMFC test station to confirm that the channel size studied in simulation. The results showed that diagonal and serpentine flow field have similarly high OCV and current density of diagonal (low field is higher($2-40mA/m^2$) than that of serpentine flow field under 0.6 voltage, but the current density of serpentine type has higher performance($5-10mA/m^2$) than that of diagonal flow field under 0.7-0.8 voltage.

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Air Cleaning Unit using Combination of $TiO_2$ Photocatalyst and Pulsed Discharge Plasma (산화티타늄 광촉매와 펄스 방전 플라즈마 조합에 의한 공기정화장치)

  • Hong, Yeong-Gi;Sin, Su-Yeon;Gang, Jeong-Hun;Lee, Seong-Hwa;Jo, Jeong-Su;Park, Jeong-Hu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.10
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    • pp.710-715
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    • 1999
  • The purpose of this work is to develop a high-efficiency air cleaning system for air pollutants such as particulate and gaseous state in indoor environments. In order to enhance a removal efficiency of gaseous state pollutants, we suggested that pulsed discharge plasma be combined with $TiO_2$ photocatalyst (photocatalytic plasma air cleaning unit). We investigated experimentally the basic characteristics of photocatalytic plasma air cleaning unit and measured air pollutants removal efficiency. The wavelength of light radiated from pulsed discharge plasma under the atmospheric condition was 310~380nm. Its energy is enough to excite the $TiO_2$ photocatalyst and it makes a photochemical reaction in the surface of $TiO_2$ photocatalyst. The removal quantity of trimethylamine$((CH_3)_3N)\; was\; 130mg/m^34 which is twice quantity of pulsed discharge plasma without $TiO_2$ phtocatalyst unit. From the result of gas analysis using FT-IR, nitric oxide was not detected and trimethylamine was decomposed to $H_2O\; and \;CO_2$. And trimethylamine removal efficiency was 95%. These experimental results indicate that photocatalytic plasma air cleaning unit is a potential method in removing the pollutants.

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Solid $CO_2$ sorbents and WGS catalyst for pre-combustion $CO_2$ capture (연소전 $CO_2$ 회수를 위한 고체 흡수제 및 WGS 촉매 특성 평가)

  • Eom, Tae Hyoung;Lee, Joong Beom;Park, Keun Woo;Choi, Dong Hyuk;Baek, Jeom-In;Ryu, Chong Kul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.111.1-111.1
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    • 2010
  • 석탄가스화복합발전(IGCC: Integrated Gasification Combined Cycle)의 고온 고압 합성가스로부터 $CO_2$를 저비용으로 포집하기 위한 연소전 포집 기술 중 유동층 촉진수성가스전환(SEWGS) 공정이 제안되어 연구개발 중에 있다. 연소전 $CO_2$ 포집을 위한 SEWGS 공정은 동일한 2탑 순환 유동층 반응기에서 고온 고압의 합성가스($H_2$, CO)를 유동층 WGS 촉매를 사용하여 CO를 $CO_2$로 전환하는 동시에 전환반응으로 생성된 $CO_2$를 흡수제를 이용하여 포집하는 기술이다. 본 연구는 $CO_2$ 회수와 WGS 반응이 동시에 이루어지는 공정에 적용 가능한 건식 재생 흡수제 및 유동층 WGS 촉매 개발을 목표로 $CO_2$ 흡수제(P Series) 및 WGS 촉매(PC Series) 조성을 제안하고 분무건조기를 이용하여 6~8kg/batch로 성형 제조하였다. 제조된 $CO_2$ 흡수제 및 촉매의 특성 평가 결과 내마모도(Attrition resistance)를 포함한 물리적 특성이 유동층 공정의 요구조건을 만족하는 결과를 얻을 수 있었다. 또한, 모사 석탄 합성가스를 이용하여 20bar, $200^{\circ}C$ 흡수/$400^{\circ}C$ 재생 조건에서 열중량 분석기(TGA) 및 가압 유동층(Fluidized-bed) 반응기를 통한 흡수제의 $CO_2$ 흡수능 평가를 수행하였다. 그 결과 내마모도(AI) 3% 이하로 기계적 강도가 우수하며, $CO_2$ 흡수능 17.6 wt%(TGA) 및 11wt%(가압 유동층)를 나타냈다. 유동층 WGS 특성 평가 결과 내마모도가 7~35%로 우수하였고, CO 전환율은 $200^{\circ}C$에서 80% 이상으로, 유동층 SEWGS 공정에 적용 가능한 특성을 확인하였다.

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Method Development for the Odor-Active Compound Determination by Gas Chromatography/Flame Ionization Detection/Olfactometry (냄새성분 측정을 위한 기체 크로마토그래피/불꽃이온화 검출/후각 검출법의 개발)

  • Kim, Man-Goo;Jung, Young-Rim;Seo, Young-Min;Yang, Hee-Hwa
    • Analytical Science and Technology
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    • v.14 no.2
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    • pp.180-190
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    • 2001
  • Oder-active compounds are complex in a sample. These compounds are usually analyzed by GC or GC/MSD while such analytical measurement can quantify specific volatile organic compounds, it has limitations in identifying odor-active compounds. To resolve this problem, GC-Sniffing or GC-Olfactometry method has been attempted. In this study, GC/FID/Olfactometry system was developed. This system can simultaneously sniff and detect GC effluents by traditional GC combined with human olfactory system. The time gap between FID and ODP response was dependent on the kinds and concentrations of chemicals and panels, with more volatile, stronger and shorten breath cycle panel showing narrow time gap. Thus, clear relationship between FID and ODP should be considered to identify the odor-active compounds.

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Properties and Mock-up Test of Lightweight Foamed Concrete Based on Blast Furnace Slag by Crack Reducing Admixture (팽창성 균열저감제를 이용한 고로슬래그 미분말 기반 경량기포 콘크리트의 특성 및 목업실험)

  • Han, Sang-Yoon;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.6
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    • pp.507-515
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    • 2017
  • This study is to develop a high quality lightweight foamed concrete that can be applied in the field using EXFG by cracking reducing agent combined with FGD and ALS. First, to increase the volume of foam, the flow and density of the mixture was increased and decreased, respectively. At this time, the effect of substitution ratio of EXFG on fluidity was negligible. The fraction of foam was the highest at EXFG 1%, and the settlement was found to be prevented by the expansion reaction at EXFG 1%. At this time, the ratio of foam was 65%. In the compressive strength, the strengths were similar or decreased when the substitution ratio of EXFG was more than 1%. The apparent density satisfied the KS 0.5 type at the bubble contents was 65%. In case of EXFG substitution, dry shrinkage was decreased by about 10%. As the substitution ratio of EXFG increased, the thermal conductivity increased proportionally.

A Study of the Possibility of Building Energy Saving through the Building Data : A Case Study of Macro to Micro Building Energy Analysis (건물데이터를 통한 건물에너지 절감 가능성에 대한 연구 : 도시단위의 거시적 분석부터 미시적 건물에너지 분석사례)

  • Cho, Soo Youn;Leigh, Seung-Bok
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.11
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    • pp.580-591
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    • 2017
  • In accordance with 2015 Paris agreement, each individual country around the world should voluntarily propose not only its (individual) reduction target, but also actively develop and present expansion targets of its scope and concrete reduction goals exceeding the previous ones. Accordingly, it is necessary to prepare a macroscopic, long-range strategy for reducing energy consumption and greenhouse gas emissions, which can cover a single building, town, city and eventually even a province. The purpose of this research is to gather and compile government-acquired data from various sources and (in accordance with contents and specificity), combine building data by stages by using multi-variable matrix and then analyze the significance of combined data for each stage. The first order data presents the probability and the cost effectiveness of energy saving on the scale of a city or a province, based only upon general information, size and power consumption of buildings. The second order data can identify a pattern of energy consumption for a building of a specific purpose and which tends to consume a larger amount of energy during one particular season (than others). Finally, the third order data can derive influential factors (base load, humidity) from the energy consumption pattern of a building, and thus propose an informed and practical energy-saving method to be applied in real time.

Glass strengthening and coloring using PIIID technology

  • Han, Seung-Hee;An, Se-Hoon;Lee, Geun-Hyuk;Jang, Seong-Woo;Whang, Se-Hoon;Yoon, Jung-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.178-178
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    • 2016
  • Every display is equipped with a cover glass to protect the underneath displaying devices from mechanical and environmental impact during its use. The strengthened glass such as Gorilla glass.$^{TM}$ has been exclusively adopted as a cover glass in many displays. Conventionally, the strengthened glass has been manufactured via ion-exchange process in wet salt bath at high temperature of around $500^{\circ}C$ for hours of treatment time. During ion-exchange process, Na ions with smaller diameter are substituted with larger-diameter K ions, resulting in high compressive stress in near-surface region and making the treated glass very resistant to scratch or impact during its use. In this study, PIIID (plasma immersion ion implantation and deposition) technique was used to implant metal ions into the glass surface for strengthening. In addition, due to the plasmonic effect of the implanted metal ions, the metal-ion implanted glass samples got colored. To implant metal ions, plasma immersion ion implantation technique combined with HiPIMS method was adopted. The HiPIMS pulse voltage of up to 1.4 kV was applied to the 3" magnetron sputtering targets (Cu, Ag, Au, Al). At the same time, the sample stage with glass samples was synchronously pulse-biased via -50 kV high voltage pulse modulator. The frequency and pulse width of 100 Hz and 15 usec, respectively, were used during metal ion implantation. In addition, nitrogen ions were implanted to study the strengthening effect of gas ion implantation. The mechanical and optical properties of implanted glass samples were investigated using micro-hardness tester and UV-Vis spectrometer. The implanted ion distribution and the chemical states along depth was studied with XPS (X-ray photo-electron spectroscopy). A cross-sectional TEM study was also conducted to investigate the nature of implanted metal ions. The ion-implanted glass samples showed increased hardness of ~1.5 times at short implantation times. However, with increasing the implantation time, the surface hardness was decreased due to the accumulation of implantation damage.

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A Study on Design of the Linear Generator in the Double Acting Stirling Engine (양방향 스털링엔진의 선형발전기 설계에 관한 연구)

  • PARK, SEONGJE;KO, JUNSEOK;HONG, YONGJU;KIM, HYOBONG;YEOM, HANKIL;IN, SEHWAN
    • Journal of Hydrogen and New Energy
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    • v.26 no.6
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    • pp.638-644
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    • 2015
  • This paper describes the continuing effort to analysis and design on dynamic and electrical behavior of gamma-type free piston Stirling engine/generator with dual-opposed linear generator for domestic micro-CHP (Combined Heat and Power) system. The double acting Stirling engine/generator has one displacer and two power piston which are supported by flexure springs. Two power pistons oscillate with symmetric sinusoidal displacement and are connected with moving magnet type linear generators for power generation. To operate Stirling engine/generator, combustion heat of natural gas is supplied to hot-end and heat is rejected from cold-end by cooling water. The temperature difference across the displacer induces the oscillating motion, and it can be explained with mass-spring vibration system. The purpose of this paper is to describe the design process of linear generator for the double acting free-piston Stirling engine.

Effect of Nanocellulose on the Mechanical and Self-shrinkage Properties of Cement Composites (나노셀룰로오스가 시멘트복합체의 역학적 특성 및 자기수축 특성에 미치는 영향)

  • Kim, Sun-Woo;Yoon, Byung-Tae
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.380-385
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    • 2016
  • Nanocelluloses, mainly cellulose nanofibrils (CNF) and cellulose nanocrystals (CNC, i.e., defect-free, rod-like crystalline residues after acid hydrolysis of fibers), have been the subject of recent interest. Due to the presence of hydroxyl groups on the surface of nanocelluloses, their surfaces are reactive, making them suitable candidates for reinforcing materials for manufacturing polymer composites. In this study, CNF was used as a reinforcing material for manufacturing cement composites. CNF was prepared by TEMPO (2,2,6,6,-tetramethyl piperidine-1-oxyl radical) oxidation procedure combined with extensive homogenization and ultrasonication. Transmission electron microscopy (TEM) analysis of the suspension showed the width of CNF between 10 and 15 nm. The compressive strength of cement composites containing 0.5% CNF was comparable to that of conventional cement composites. On the other hand, the tensile and flexural strength were improved by 49.7% and 38.8%, respectively, compared to those of conventional cement composites. Also, at an ambient condition, the degree of self-shrinkage reduction reached to 18.9% in one day, followed by 5.9% in 28 days after molding.

Characteristics of Substrate Degradation and Bacterial Population in the Membrane Separation Anaerobic Digestion Process (막분리혐기성소화공정에 있어서 기질분해와 세균군의 분포특성)

  • Cha, Gi-Cheol;Chung, Hyung-Keun;Kim, Dong-Jin;Kim, Young-Chur
    • Journal of Korean Society on Water Environment
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    • v.16 no.4
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    • pp.541-554
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    • 2000
  • Experimental study of anaerobic digestion process combined with and without the submerged separation membrane was investigated by using laboratory-scale reactor at the hydraulic retention time of 0.5 day and 1.0 day. The removal efficiencies of carbohydrate at the digester without and with membrane were 84.4 to 86.8 % and 99.6 to 99.7 %, respectively, and the methane gas recovery efficiencies were 0.4 to 1.2 % and 12.3 to 28.7 %. According to the measurement by the most probable numbers method. the numbers of various groups of bacteria in the digesters with membrane were enumerated in the following ranges ; acidogens : $1.7{\times}10^9$ to $5.0{\times}10^9MPN/m{\ell}$, homoacetogens : $5.0{\times}10^7$ to $2.4{\times}10^8MPN/m{\ell}$, $H_2$-utilizing methanogens : $1.3{\times}10^7$ to $9.2{\times}10^8MPN/m{\ell}$, and acetate-utilizing methanogens : $2.3{\times}10^6$ to $2.0{\times}10^8MPN/m{\ell}$. The number of methanogens at the digester with membrane increased by approximately $10^2$ to $10^4$ times in comparison with that of the digester without membrane.

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