• Polymer(Korea)
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• v.32 no.6
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• pp.593-597
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• 2008

To separate carbon dioxide from a flue gas, membranes for gas separation was fabricated from polystyrene-b-polybutadiene (SB) diblock copolymer blends with poly(phenylene oxide), PPO. SB diblock copolymer formed miscible blends with PPO in the experimental range (lower than or equal to 70 wt% PPO). When the blend contained PPO whose composition is in the range of 40-50 wt%, the discontinuous phase of polybutadiene block in SB diblock copolymer, was changed to discrete phase, while polystyrene blocks containing PPO was changed to the continuous phase. A sudden decrease of the gas permeability and a sudden increase of the gas selectivity was observed at these blend compositions. A gas separation membranes having excellent mechanical properties and exhibiting advantages in gas permeability and selectivity could be fabricated from blends containing more than 50 wt% PPO.

• International Journal of Air-Conditioning and Refrigeration
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• v.11 no.2
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• pp.61-66
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• 2003

In order to prevent roll-over and a rapid boil-off of LNG in tanks, the phase equilibria of carbon dioxide in liquefied natural gas components as binary mixtures at cryogenic temperatures have been experimentally measured using Fourier transform infrared spectroscopy in conjunction with a specially designed variable pressure/temperature cryostat cell (pathlength 2 mm; pressures up to 30 bar). Solid carbon dioxide has been found to be comparatively soluble in liquid nitrogen (3.25$\times$${10}^{-6}$ mole fraction), liquid methane (1.04$\times$${10}^{-4}$ mole fraction), liquid ethane (3.1$\times$${10}^{-2}$ mole fraction) and liquid propane (6.11$\times$${10}^{-2}$ mole fraction) at their normal boiling temperatures. The solubilities of carbon dioxide in various cryogens, which increased with increasing temperature, are much lower than those obtained by others using gas chromatography. The differences are attributed to infrared spectroscopy selectively measuring dissolved solute in situ whereas gas chromatography measures microscopic particulate solid in addition to dissolved solute.

• Journal of the Korean Society for Heat Treatment
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• v.12 no.1
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• pp.9-20
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• 1999

The effect of post oxidation, water-quenched after holding in air for 5~420 seconds or cooling or furnace cooling, on corrosion resistance and phase formation characteristics of the surface layer of SM20C and SM45C carbon steels after gas nirtrocarbursing in the $NH_3-5%CO_2-N_2$ gas atmosphere at $580^{\circ}C$ for 3hours is studied. The compound layers of two steels consist of ${\varepsilon}-Fe_{2-3}N$, ${\gamma}^{\prime}-Fe_4N$ and $Fe_3O_4$, phases, however, the quantity of ${\gamma}^{\prime}-Fe_4N$ phase increases for the furnace cooled specimen compared to that of air cooling specimen. With increasing $NH_3$ content in the gas mixture and also increasing the keeping time in the air after gas nitrocarburising, the ${\varepsilon}-Fe_{2-3}N$ phase of compound layer increases, while the decreased current density recognizing the improvement of corrosion resistance are shown. the passive current density of SM45C steel is lower than that of SM20C steel at the same nitrocarburising conditions.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.55 no.6
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• pp.308-312
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• 2006

Partial Discharge (PD) phenomena occurred by different nature of insulating defects has been regarded as a random process by which Phase Resolved Partial Discharge Analysis(PRPDA) has been proposed and then commercially accepted for the diagnosis of the power apparatus since more than three decades. Moreover, for the same purpose, a novel approach based on the Chaotic Analysis(CAPD) has been proposed since 2000, in which Partial Discharge(PD) phenomena is suggested to be considered as a deterministic dynamical process. In this work, for the diagnosis of Gas Insulated Transformer(GITr), four different types of specimen were fabricated as a model of the possible defects that might possibly cause its sudden failures such as turn to turn insulation, inter coil insulation, free moving particle and protrusion. For this purpose, these defects are introduced into the Gas Insulated Transformer(GITr) mock-up and experimental investigations have been carried out in order to analyze the related Partial Discharge(PD) patterns by means of both Phase Resolved Partial Discharge Analysis(PRPDA) and Chaotic Analysis(CAPD) respectively and then their comparisons are made systematically.

• Journal of ILASS-Korea
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• v.13 no.3
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• pp.117-125
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• 2008

The correlations for the prediction of maximum liquid-phase penetration in diesel spray are reviewed in this study. The existing models developed for the prediction of maximum liquid-phase penetration can be categorized as the zero-dimensional (empirical) model, the multi-dimensional model and the other model. The existing zero-dimensional model can be classified into four groups and the existing multidimensional models can be classified into three groups. The other model includes holistic hydraulic and spray model. The maximum liquid-phase penetration is mainly affected by nozzle diameter, fuel volatility, injection pressure, ambient gas pressure, ambient gas density and fuel temperature. In the case of empirical correlations incorporated with spray angle, the predicted results will be different according to the selection of correlation for spray angle. The research for the effect of boiling point temperatures on maximum liquid-phase penetration is required. In the case of multidimensional model, there exist problems of the grid and spray sub-models dependency effects.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.1
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• pp.48-53
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• 2001

The crystal structure of ZnS fabricated by gas-liquid phase reaction was refined by the Rietveld program using X-ray diffraction data. The R-weighted pattern (R$\sub$wp/) of ZnS powder was 10.85%. The fraction of HCP phase was closely related with extra amount of H$_2$S gas. The lattice parameters and crystalline size were changed by the relative ratio of multi-phase. The luminescence property of ZnS:Cu, Al green phosphors prepared by conventional methods was good in the range of 91∼94% and 150∼190${\AA}$, respectively. According to the maximum entropy electron density(MEED) methods, any defects in (001) plane of cubic phase were not found. We suggest that both the Rietveld and maximum entropy density methods may be useful tools for studying luminescence mechanism of other phosphors materials.

• 한국전산유체공학회:학술대회논문집
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• 2004.10a
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• pp.215-220
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• 2004

A mathematical formulation based on two-phase, two-fluid hyperbolic conservation laws is developed to investigate propagation of shock waves in one- and two-dimensions. We used a high resolution upwind scheme called the split-coefficient matrix method. Two extreme cases are computed for validation of the computer code: the states of a pure gas and a pure liquid. Computed results agreed well with the previous experimental and numerical results. It is studied how the shock wave propagation pattern is affected by the void fraction in the two-phase flow. The shock structure in a two-phase flow turned out, in fact, much deviated from the shape well known in the gas only phase.

• Journal of Environmental Science International
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• v.9 no.1
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• pp.75-80
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• 2000

Kinetic data for the acid phase anaerobic digestion were presented in this study and the constants were determined with acid production rate and gas production rate. Process models based on continuous culture theory were used to describe the characteristics of the acid forming microorganisms and to enable further development toward utilization of the process in a more rational manner. Acid phase digestion can be separated with appropriate manipulation of hydraulic retention time in anaerobic digestion. Kinetic analysis of data from the various hydraulic retention times using a phase specific model obtained form the acid phase indicated maximum specific growth rate of 0.40/h, saturation constant of 2,000mgCOD.$\ell$, yield coefficient of 0.35 mgVSS/msCOD utilized and decay constant of 0.04/h for the acid production rate. Similar analysis of data for the gas production rate indicated maximum specific growth rate of 0.003/h, saturation constant of 2,200mgCOD/$\ell$, yield coefficient of 0.035 mgVSS/mgCOD utilized and decay constant of 0.06/h.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.469-470
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• 2006

[ $TiO_2$ ] nanoparticle was synthesized by the flame method, which was controlled by varying the ratio and flow rate of gas mixtures consisting of oxygen (oxidizer), methane (fuel) and nitrogen (carrier gas). The crystalline phases of $TiO_2$ nanoparticle depended strongly on the temperature distribution in the flame, whereas the morphology was not sensitive. We proved that the anatase phase formed without the phase transformation in the flame and the rutile phase generated through several phase transformations.

• Journal of the Korean Institute of Gas
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• v.4 no.2 s.10
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• pp.7-14
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• 2000

LNG (Liquified Natural Gas) carried by LNG ship is unloaded into the LNG storage tanks at the very low temperature (a little lower than the boiling point of LNG). Because LNG is unloaded through the pipeline, two phase flow appears in the pipeline. In this study, we have studied the pressure-drop mechanisms of the two-phase flow in the pipeline, and the calculation method of BOG (Boil-off Gas) amount based on the heat transfer mechanism through the insulation and the surface of the pipeline. We have developed a computer program for thermal-hydraulic analysis on the LNG pipeline system. We have also developed the optimal design program to find the optimal thickness of insulation and the pipeline size. The program searches the optimal design with the minimum capital cost of pipelines and insulation on the operating conditions of maximum allowance pressure-drop and BOG amount, etc.