• Title/Summary/Keyword: Gas-Phase

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Surface Acoustic Wave Gas Sensor (탄성표면파 가스센서)

  • Yoo, Beom-Keun;Park, Yong-Wook;Kang, Chong-Yun;Kim, Jin-Sang;Choi, Doo-Jin;Yoon, Seok-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.251-252
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    • 2006
  • A development of surface acoustic wave gas sensor to detecting volatile gas has been observed by monitoring output signal as function of time onto the network analyzer. The SAW sensor with a center frequency of 200MHz was fabricated on $42^{\circ}$ S-T Quartz substrates. Using the gas chromatography column has been selectivity. Experimental results, which show the phase change of output signal under the absorption of volatile gas onto sensors, were presented. The proposed sensor has the properties of high sensitivity compare to the conventional SAW gas sensor and chemical selectivity. Thus, it is thought these results are applicable for use in sensor array of an high performance electronic nose system.

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Simulation of Two Phase Flow in Porous Media After Disso of Methane Hydrates (다공성 매질 내에서 메탄 하이드레이트의 분해에 의한 2 상 유동 해석)

  • Chang, Dong-Gun;Kim, Nam-Jin;Lee, Jae-Yong;Kim, Chong-Bo
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.241-246
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    • 2000
  • Gas hydrates are solid solutions when water molecules are linked through hydrogen bondin create host lattice cavities that can enclose a large variety of guest gas molecules. The natural hydrate crystal may exist at low temperature above the normal freezing point of water and pressure greater than about 30 bars. A lot of quantities of natural gas hydrates exists in the ear many production schemes are being studied. In the present investigation, depressurization method considered to predict the production of gas and the simulation of the two phase flow - gas and - in porous media is being carried out. The simulation show about the fluid flow in porous have a variety of applications in industry. Results provide the appearance of gas and water prod the pressure profile, the saturation of gas/ water/ hydrates profiles and the location of the pl front.

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A Study on the Phase Equilibrium Conditions of Mixture Gas Hydrates using CSMHYD (CSMHYD를 이용한 혼합가스 하이드레이트의 상평형에 대한 연구)

  • Seo, Hyang-Min;Park, Yun-Beom;Chun, Won-Gee;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.585-589
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    • 2007
  • Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production, Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% Nacl. The results show that Nacl acts as a inhibitor, but help gases such as ethan, propane, i-butane, and n-butane reduce the hydrate formation pressure at the same temperature.

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Numerical Simulation on Flow and Heat Transfer in a Gas Atomizer (가스분무장치에서 열유동 특성에 관한 전산해석)

  • 이성연
    • Journal of Powder Materials
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    • v.4 no.1
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    • pp.55-62
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    • 1997
  • Flow and heat transfer characteristics of gas, and trajectories and cooling characteristics of droplets/particles in a gas atomizer were investigated by a numerical simulation using FLUENT code. Among several kinds of solution method, the k-$\varepsilon$ turbulent model, power-law scheme, SIMPLE algorithm is adopted in this study. Momentum and heat exchange between a continuous phase(gas) and a dispersed phase(particle) were taken into account. Particle trajectories are simulated using the Lagrangian method, and Rosin-Rammler formula is used for the particle size distribution. Streamlines, velocities and pressures of gas, and trajectories, velocities and cooling rates of particles have been investigated for the various gas inlet conditions. Small but very intensive recirculation is found just below the melt orifice, and this recirculation seems to cause the liquid metal to spread radially. Particle trajectory depends on the particle size, the location of particle formation and the turbulent motion of gas. Small particle cools down rapidly, while large diameter particles solidify slowly, and this is mainly due to the differences in thermal inertia.

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Effects of Convection Gas on Formation of Sn Oxide Nanoparticles (Sn 산화물 나노입자 형성에 미치는 대류 가스의 영향)

  • ;;;K. Niihara
    • Journal of Powder Materials
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    • v.9 no.1
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    • pp.32-37
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    • 2002
  • In the present study of IGC (Inert Gas Condensation) evaporation-condensation processing study, the effects of IGC convection gas on the crystallographic structure, size and shape of tin oxide nanoparticles were investigated. In addition, the phase transformation of tin oxide nanoparticles was studied after heat treatment. IGC processing was conducted at 1000℃ for 1 hr. The mixture gas of oxygen and helium was used as a convection gas. Metastable tetragonal SnO nanoparticles were obtained at a lower convection gas pressure, whereas amorphous tin oxide nanoparticles were obtained at a higher one. The formation of amorphous phase could be explained by the rapid quenching of the vaporized atoms. The resultant nanoparticles size was about 10 nm with a rounded shape. The tin oxide nanoparticles prepared by IGC were almost transformed to the stable tetragonal SnO₂ after heat treatment.

Impact of mixer design to reactants mixing characteristics and gas-phase reactions in the mixing region of a hydrocarbon reformer (개질기 혼합영역 형상에 따른 반응물의 혼합도 및 가스상 반응특성에 대한 수치해석적 연구)

  • Kim, Sunyoung;Bae, Joongmyeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.99.1-99.1
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    • 2011
  • Reactant mixing has a critical role in ensuring reformate quality and an important design objective is to achieve sufficiently complete mixture of reactants. For that purpose it is required to understand the coupled transport-kinetics phenomena in the mixing region. Three-dimensional computational fluid dynamics model was developed and validated in previous works. The mixing characteristics in various alternatives of a prototype mixing chamber were compared, and then a reduced reaction kinetics was applied to two extreme designs for investigating the impact of gas-phase reactions. Both designs did not reach threshold ethylene mole fraction of 0.001, but surprisingly more ethylene was generated in the design having better mixing characteristics. The presentation will deliver the development process of coupled transport and kinetics model briefly and the detailed information about the mixing characteristics and gas-phase reactions in two mixer designs.

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Effect of pH on the Preparation of Spherical Fine Zirconia Powders Using Gas-Liquid Phase Reaction (기액반응법을 이용한 구형 지르코니아 미분체 제조시 pH의 영향)

  • 김창현;이대희;이창섭;이병교
    • Journal of the Korean Ceramic Society
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    • v.34 no.10
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    • pp.1009-1014
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    • 1997
  • Ammonia gas was blown into the solution of zirconium ion to induce precipitation of supersaturated zirconium ion at gas-liquid interface with increase in pH. The influence of pH on the phase and particle size of precipitate and calcined powders has been investigated. At pH 4.5 of zirconium solution, maximum yield of 98.7% was obtained. Above pH 4.5, there was no more increase of yield. Above pH 5.5, large aggregates consisting of primary particles were observed in precipitate and calcined powders. At pH 4.5, almost aggregate-free fine spherical zirconia powders were obtained.

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Rapid Gas Chromatographic Screening of Saliva Samples for Organic Acids (기체크로마토그래피법에 의한 타액내 유기산의 신속한 스크리닝)

  • 김경례;김정한;박영준;김정옥
    • YAKHAK HOEJI
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    • v.39 no.3
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    • pp.283-288
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    • 1995
  • Rapid gas chromatographic profiling method was applied to saliva from healthy subjects for the analysis of free organic acids. Saliva samples were first saturated with NaHCO$_{3}$ and extracted with diethyl ether. The aqueous phase was solid-phase extracted using Chromosorb P as the adsorbent and diethyl ether as the eluent after the acidification and NaCl saturation, followed by triethylamine treatment. The resulting tiiethylammonium salts of acids were directly converted into stable tert.-butyl-dimethylsflyl derivatives, with subsequent analysis by dual-capiuary column gas chromatography and gas chromatograpy -mass spectrometry. From the ten saliva samples studied, twenty eight free organic acids including various fatty acids, hydroxy acids, dicarboxylic acids, md aromatic acids were tentatively identified. Among the acids identified , the concentration of lactic acid was highest for five saliva samples while $\alpha$-hydroxyisocaproic acid was most abundant for me sample, and succinic acid and glycolic acid for two samples. respectively. When the GC profiles were simplified to the corresponding acid retention index spectra of bar graphical form, they presented characteristic patterns for each individual.

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Flow Characteristics of Vertical Upward Gas-Liquid Two-Phase Flow (수직상향 기액이상류의 유동특성)

  • Choi Bu-Hong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.4
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    • pp.377-383
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    • 2005
  • This paper deals with the flow characteristics of air-water two-phase flow in a vertical tube of 10mm I.D. and 600mm in length at an adiabatic condition. The obtained experimental data were covered with the liquid superficial velocity ranging from 0.095m/s to 2.56m/s. and the gas superficial velocity ranging from 0.032m/s to 21.08m/s. The effects of the gas and liquid superficial velocity on the flow pattern transitions, frictional pressure drop, and film thickness and gas-liquid interface roughness were also examined. It was found that the film thickness increased and the liquid film wave length was more longer with the liquid superficial velocity $j_L$ increasing at $j_G$ constant. It was also showed that the frictional pressure drops were experienced in three regions. namely increasing region(bubbly flow), decreasing region (Taylor bubble and slug flows) and re-increasing region (annular flow).

Characterization of Gas Phase Etching Process of SiO2 with HF/NH3

  • Kim, Donghee;Park, Heejun;Park, Sohyeon;Lee, Siwon;Kim, Yejin;Hong, Sang Jeen
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.45-50
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    • 2022
  • The etching with high selectivity of silicon dioxide over silicon nitride is essential in semiconductor fabrication, and gas phase etch (GPE) can increase the competitiveness of the selective dielectric etch. In this work, GPE of plasma enhanced chemical vapor deposited SiO2 was performed, and the effects of process parameters, such as temperature, partial pressure ratio, and gas supply cycle, are investigated in terms of etch rate and within wafer uniformity. Employing multiple regression analysis, the importance of each parameter elements is analyzed.