• Title/Summary/Keyword: Gas production

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Composite Oxidizing Agents Generation Using Electrolysis of Dilute Hydrochloric Acid (묽은 산 전기분해에 의한 복합 산화제 생성)

  • Kang, Shin-Young;Park, Jong-Hun;Kim, Sang-Hyoun
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.329-333
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    • 2016
  • Disinfection by electrolysis would be useful for small wastewater treatment plant, combined sewer overflow, ballast water, swimming pool, and fish farming, where the transport, storage, and the use of chlorine gas is limited. This study investigated the feasibility of the electrolysis of dilute hydrochloric acid (HCl) for disinfection. The effects of HCl concentration, voltage and reaction time on the generation of oxidizing agents, HOCl, $O_3$, and $H_2O_2$, were examined in a series of batch test. The highest current efficiency was 99.3% which was found at 2.2%, 3 V, and 5 min of HCl concentration, voltage, and reaction time, respectively. Continuous electrolysis at 2.2% HCl, 3 V, and 5 min of the hydraulic retention time showed 97.4% of the current efficiency. Addition of sodium chloride up to 20 g/L linearly increased the oxidizing agents production. 92.2% of total coliforms were removed by the contact with the electrolyzed water.

A study on the process optimization of microcellular foaming injection molded air-conditioner drain pen (화학적 초미세 발포 사출성형을 이용한 에어컨 드레인 펜의 공정 최적화에 대한 연구)

  • Kim, Joo-Kwon;Kwak, Jae-Seob;Kim, Jun-Min;Lee, Jun-Han;Kim, Jong-Sun
    • Design & Manufacturing
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    • v.11 no.2
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    • pp.1-8
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    • 2017
  • In this study, we applied microcellular foaming injection molding process to improve the performance of system air-conditioner drain fan which had been produced by injection molding process and studied the optimization of process conditions through 6-sigma process and response surface method (RSM) to reduce weight and deformation of products. Additive type, melt temperature, mold temperature, and injection screw shape were selected as the factor affecting the weight and deformation of the products by carrying out analysis of trivial many through ANOVA and design of experiment (DOE) method. Among the effect factor, we set the addictive type to Long G/F and screw shape to foaming screw which had the highest level of weight reduction and deformation reduction. The amount of foaming agent gas was set at 60 ml, which was the limit beyond which the weight of product did not decrease any more. For melt temperature and mold temperature, we studied the conditions where both weight and deformation were minimized using the RSM. As a result, we set the melt temperature to $250^{\circ}C$, fixed mold temperature to $20^{\circ}C$, and moving mold temperature to $40^{\circ}C$. The improvement effect was analyzed by appling the selected optimal conditions to the production process using the microcellular foaming injection molding. The results showed that the mean weight of product was measured to be 1,420g which was 19% lower than that measured in the current process. The standard deviations of the weights were found to be similar to those in the current process and it showed a low dispersion. The mean deformation was measured to be 0.9237mm, which represented a 57% reduction compared to the mean deformation in the current process, and the standard deviation decreased from 0.3298mm to 0.1398mm. Moreover, we analyzed the process capability for deformation, and the results showed that the short-term process capability increased from 2.73 to 6.60 which was even higher than targeted level of 6.0.

Study on the Growth Environment of 'Gangwha-mugwort' Through the Climatological Characteristic Analysis of Gangwha Region (강화지역의 기후특성 분석을 통한 '강화약쑥'의 생육 환경 연구)

  • Ahn, Joong-Bae;Hur, Ji-Na;Jung, Hae-Gon;Park, Jong-Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.2
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    • pp.71-78
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    • 2012
  • Eupatilin, one of representative medical components of mugwort, can be efficiently extracted from the 'Gangwha Sajabalssuk'. The Eupatilin content may depend on environmental factors such as soil and regional climate in addition to a genetic factor and Gangwha region has a profitable environmental condition for the mugwort growth. In this study, the climatological characteristics of Gangwha was analyzed in order to find the environmental condition of mugwort containing high Eupatilin in term of atmospheric, oceanographic and land variables. The climate of Gangwha is characterized by the relatively low daily temperature and large diurnal variation with plenty of solar radiation, long sunshine duration and less cloudiness. According to our correlation analysis, the long sunshine duration and the large diurnal temperature variation are highly correlated with the Eupatilin contents. The result implies that Gangwha has the favorable conditions for the cultivation and the habitat of the high-Eupatilin concentrated mugwort. Because of the sea surrounding Gangwha Island with low salinity and moderate wind, the salt contained in sea breeze is relatively low compared to other regions. Furthermore, Gangwha has clean atmospheric environment compared to other regions because the concentrations of toxic gases harmful to crop growth such as nitrogen dioxide ($NO_2$), sulfite gas ($SO_2$) and fine dust (PM-10) are lower in the air. The ozone ($O_3$) concentration is moderate and within the level of natural production. It is also found that moderately coarse texture or fine loamy soils known as good for water drainage and for the growth and cultivation of the 'Gangwha-mugwort' are distributed throughout the areas around mountainous districts in Gangwha, coinciding with those of mugwort habitat.

Present Status of Hydrogen Refueling Station in KIER (KIER 수소충전소 구축 현황)

  • Seo, Dong-Joo;Seo, Yu-Taek;Seo, Yong-Seog;Park, Sang-Ho;Roh, Hyun-Seog;Jeong, Jin-Hyeok;Yoon, Wang-Lai
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.21-24
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    • 2006
  • 수소의 소규모 분산 생산 기술은 본격 적 인 수소 인프라가 도입되기 전에 연료전지 자동차의 수소 충전용이나 분산 발전형 연료전지의 수소 공급을 위해 필요하다. 생산 용량은 수소 기준으로 $20{\sim}100 Nm^3/hr$ 정도로 현재로선 천연가스의 수증기 개 질법이 가장 경제적인 공정으로 알려져 있다. 소규모 생산에 따른 열효율 저하를 줄이 기 위해 단위 공정들이 통합된 컴팩트 개질 시스템의 개발이 필요하다. 연료전지 자동차용 수소 인프라 조기 구축을 위하여 수소충전소 구축과 국산화 천연가스 수증기 개질기 개발을 병행하여 진행하였다. 수소 충전소 구축 부분은 충전소 부지 확보, 건물 건축, 각종 유틸리 티 설치의 토목 부분과 천연가스 개질형 수소 제조 유닛 설치, 수소 압축, 저장, 디스펜싱 시스템 설치를 포함하고 있으며 고압 설비에 대한 인허가 대응 및 안전대책 작업도 진행하였다. 구축된 수소충전소는 향후 연료전지 자동차 연계 실증 프로그램에 활용할 수 있다. 국산화 핵심 기술 개발을 위하여 열 및 시스템 통합 설계에 의 해 천연가스 수증기 개질기를 제작하고 내부 열교환 구조에 따른 개질기의 성능을 평가하였다. 개발된 개질기는 개질온도 $720^{\circ}C$, 수증기 대 카본 비 2.7의 운전조건에서 $23Nm^3/h$ 이상의 수소 생산이 가능하였으며 73% 이상의 개질 효율을 나타내었다. 개발된 천연가스 수증기 개질기는 향후 수소 정제용 PSA(Pressure Swing Adsorption) 시스템과 연계하여 수소충전소 국산화 엔지니어링 설계 패키지 개발의 핵심 기 술로 사용할 계획이다.시간 정도 운전한 후 시스템을 정지하였다 메탄 전환율과 일산화 탄소 농도, 열효율을 모니터링 하고 있으며, 현재까지 초기 성능을 그대로 유지하고 있다. 앞으로 일일시동-정지 운전 시험을 지속하면서 초기 시동 특성 및 부하 변동에 따른 응답 특성 개선, 그리고 연료전지와의 연계 운전을 실시할 예정이다 한다. 단위 전지 운전 온도 $130^{\circ}C$, 상대습도 37%의 운전 조건에서도 상당히 우수한 전지 성능을 보임에 따라 고온/저가습 조건에서 상용 Nafion 112 막보다 우수한 막 특성을 나타냄을 확인하였다.소/배후방사능비는 각각 $2.18{\pm}0.03,\;2.56{\pm}0.11,\;3.08{\pm}0.18,\;3.77{\pm}0.17,\;4.70{\pm}0.45$ 그리고 $5.59{\pm}0.40$이었고, $^{67}Ga$-citrate의 경우 2시간, 24시간, 48시간에 $3.06{\pm}0.84,\;4.12{\pm}0.54\;4.55{\pm}0.74 $이었다. 결론 : Transferrin에 $^{99m}Tc$을 이용한 방사성표지가 성공적으로 이루어졌고, $^{99m}Tc$-transferrin의 표지효율은 8시간까지 95% 이상의 안정된 방사성표지효율을 보였다. $^{99m}Tc$-transferrin을 이용한 감염영상을 성공적으로 얻을 수 있었으며, $^{67}Ga$-citrate 영상과 비교하여 더 빠른 시간 안에 우수한 영상을 얻을 수 있었다. 그러므로 $^{

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A study on exposure of organic solvents in manufacturing industry (제조업 산업장의 유기용제 노출에 관한 연구)

  • Moon, Deog-Hwan;Kim, Jeong-Ha;Kim, Pil-Ja;Park, Myung-Hee;Hwang, Yong-sik;Lee, Chae-Kwan;Lee, Chang-Hee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.3
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    • pp.219-228
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    • 2001
  • Objective : For the purpose of preparing the fundamental data and health promotion and control program on organic solvents in air of manufacturing industry. Methods : The author surveyed number of organic solvent components which was used in working site and also determined the organic solvents concentration in air of 927 manufacturing industries and 1,267 working process with gas chromatography(NIOSH manual) for five years from 1995 to 1999. Results : Mean number of solvents components by type of industry, working process was number of 12. There were exceeded to TLV of 1,2-dichloroethane in textile manufacturing industry N,N-dimethyl furan in tanning and dressing of leather ; luggage, handbags, saddlery, harness and footwear manufacturing industry and chemical and chemical product manufacturing industry by type of industry. There were exceeded to TLV of 1,2-dichloroethane in handwriting and drawing process, cellosolve in adhesive spreading process, N,N-dimethly furan in production of solvent process and adhesion process by working process Total exceeded rate to threshold limit values of organic solvents mixture were 12.9% for EI(Exposure index) and 10.0% for Em(Estimation of mixture) by type of industry, 11.3% for EI and 8.2% for Em by type of working process. The highest exceed rate was 36.7% for EI in tanning and dressing of leather ; luggage handbags, saddlery, harness and footwear manufacturing industry and 29.0% for Em in textile manufacturing industry. The highest exceeded rate was 23.1% for EI and 12.5% for Em in adhesive spreading process by working process. Mean values of total subjects by type of industry and type of working process were $0.7{\pm}1.8$ for EI and $0.7{\pm}1.7$ for Em respectively. Conclusions : As above results, the author suggest that it makes the environmental control program on 1.2-dichloroethane, N,N-dimethyl furan, cellosolve by kind of organic solvent and on textile manufacturing industry, tanning and dressing of leather ; luggage, handbags, saddlery harness and footwear manufacturing industry by type of industry, and on handwriting, drawing process and adhesive spreading process and adhesion process by type of working process.

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Effects of Metal Oxide Addition on Co-pyrolysis of PVC and ABS Mixtures (PVC와 ABS 혼합물의 공열분해에 대한 금속산화물의 첨가 효과)

  • Kim, Hee Taik;Choung, Youn Wook;Lee, Hae Pyeong
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.296-303
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    • 2005
  • The co-pyrolysis characteristics of polyvinylchloride (PVC) and acrylonitrile butadiene styrene (ABS) mixtures with various mixing ratios and effect of addition of CaO and $Cu_2O$ have been studied using thermogravimetry (TG) and gas chromatograph-mass spectrometry (GC-MS). In an isothermal decomposition conducted at $500^{\circ}C$, the yields of styrene monomers and aromatic compounds increased as the mixing ratio of ABS increased, and the yield of BTX compounds reached its maximum (16.14%) when the mixing ratios of PVC and ABS was 4:1. In an isothermal decomposition added with metal oxides, the maximum yield of liquid product was 73% when CaO [CaO/(PVC+ABS)=0.4] was added and it was 70% when $Cu_2O$ [$Cu_2O$/(PVC+ABS)=0.4] was added, respectively, where HCl contained in the gaseous product was completely removed when added with CaO [CaO/(PVC+ABS)=0.5] and $Cu_2O$ [$Cu_2O$/(PVC+ABS)=1.0]. Therefore, to obtain the highest yield of liquid product it appears to be the reaction condition: the reaction temperature of $500^{\circ}C$ and mixing ratios of CaO and $Cu_2O$ are 0.5 and 1.0, respectively.

Antimicrobial Characteristics of Metabolites of Lactic Acid Bacteria Isolated from Feces of Newborn Baby and from Dongchimi (신생아 분변 및 동치미에서 분리한 젖산균 대사산물의 항균특성)

  • Lee, Ji-Young;Park, Yeong-Soo;Kim, Yong-Suk;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.34 no.3
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    • pp.472-479
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    • 2002
  • The antimicrobial effects of metabolites from isolated strains from feces of Korean newborn baby and from Dongchimi against six food-borne microorganisms, and characteristics of the metabolites were investigated.. The metabolites from isolated strains adjusted pH to 3.5, 4.0, and 4.5 showed strong growth inhibition against S. Typhimurium, and S. Enteritidis. The metabolites has kept its inhibition activities to the pathogens after catalase, trypsin or pepsin treatment. In addition, antimicrobial activity of metabolites was not decreased by heat treatment at $121^{\circ}C$ for 15 min. D2 and F35-2 strains were confirmed homofermentative and F20-3 was heterofermentative bacteria identified by final organic acid and gas production. The amount of lactic acid produced by D2 and F35-2 strains after 24 h of incubation was 1.84 and 1.85% respectively, but F20-3 strain produced acetic acid (0.22%) and lactic acid (0.91%).

Configuration of Fuel Cell Power Generation System through Power Conversion Device Design (전력변환장치 설계를 통한 연료전지 발전시스템 구성)

  • Yoon, Yongho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.21 no.6
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    • pp.129-134
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    • 2021
  • Recently, the demand for electricity is gradually increasing due to the rapid industrial development and the improvement of living standards. In the case of Korea, which is highly dependent on fossil fuels due to such a surge in electricity demand, reduction and freezing of greenhouse gas emissions due to international environmental regulations will immediately lead to a contraction in industrial activities. Accordingly, there are many difficulties in competition with advanced countries that want to link the environment with the country's industrial production activities, and the development of alternative energy as a countermeasure is of great interest around the world. Among these new power generation methods, small-scale power generation facilities with relatively small capacity include photovoltaic generation, wind power generation, and fuel cell generation. Among them, the fuel cell attracts the most attention in consideration of continuous operation, high power generation efficiency, and long-term durability, which are important factors for practical use. Therefore, in this paper, the fuel cell power generation system was researched and constructed by designing the power conversion circuit necessary to finally obtain the AC power used in our daily life by using the DC power generated from the fuel cell as an input.

Determination of fuel marker in petroleum products using GC-MS (GC-MS를 이용한 석유제품 중의 식별제 분석)

  • Youn, Ju Min;Doe, Jin Woo;Yim, Eui Soon;Lee, Jung Min
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1073-1080
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    • 2018
  • There are several types of petroleum products used for the fuel oil, according to their respective quality standards, grades and usage. Depending on the degree of oil tax rate by country, even the same petroleum products will have price gap. The illegal mixing of cheap petroleum products, which are subject to the lower tax rate, with relatively expensive transportation fuel causes problems such as tax evasion, environmental pollution and vehicle breakdown. In order to prevent illicit production and mixing of these different petroleum products, a small amount of markers are legally added to specific petroleum products. In Korea, markers are introduced and used to prevent illegal activity that kerosene used as fuel for house and commercial boiler are mixed with automotive diesel fuels, and marker contents are analyzed to use UV-Vis spectrophotometer and high performance liquid chromatography (HPLC). In this study, we have developed a method to qualitatively and quantitatively determine the marker added to petroleum products by gas chromatography-mass spectrometry (GC-MS) without adding developing reagent or sample pre-treatments.

Solar ESS Peak-cut Simulation Model for Customer (수용가 대응용 태양광 ESS 피크컷(Peak-cut) 시뮬레이션 모델)

  • Park, Seong-Hyeon;Lee, Gi-Hyun;Chung, Myoung-Sug;Chae, U-ri;Lee, Joo-Yeuon
    • Journal of Digital Convergence
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    • v.17 no.7
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    • pp.131-138
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    • 2019
  • The world's electricity production ratio is 40% for coal, 20% for natural gas, 16% for hydroelectric power, 15% for nuclear power and 6% for petroleum. Fossil fuels also cause serious problems in terms of price and supply because of the high concentration of resources on the earth. Solar energy is attracting attention as a next-generation eco-friendly energy that will replace fossil fuels with these problems. In this study, we test the charge-operation plan and the discharge operation plan for peak-cut operation by applying the maximum power demand reduction simulation. To do this, we selected the electricity usage from November to February, which has the largest amount of power usage, and applied charge / discharge logic. Simulation results show that the contract power decreases as the peak demand power after the ESS Peak-cut service is reduced to 50% of the peak-target power. As a result, the contract power reduction can reduce the basic power value of the customer and not only the economic superiority can be expected, but also contribute to the improvement of the electric quality and stabilization of the power supply system.