• Title/Summary/Keyword: Gas phase

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Phase-resolved CARS Temperature Measurements in a Lean Premixed Gas Turbine Combustor;Effect of fuel/air mixing on phase-resolved gas temperature (CARS를 이용한 희박 예혼합 가스터빈 연소기내 온도 측정(1);연료/공기 혼합정도가 위상별 온도에 미치는 영향)

  • Moon, Gun-Feel;Lee, Jong-Ho;Park, Chul-Woong;Hahn, Jae-Won;Jeon, Chung-Hwan;Chang, Young-June
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.97-102
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    • 2003
  • Experimental investigations were carried out in an atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on natural gas. The objective of this study is to obtain the phase-resolved gas temperatures at different phases of the oscillating pressure cycle during unstable combustion. CARS temperature measurements were made at several spatial locations under lean premixed conditions to get the information on temperature field within the combustor. Also the effect of incomplete fuel-air mixing on phase-resolved temperature fluctuation was investigated. Results including phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs) were provided in this paper. Temperature PDFs give an insight on the flame behavior. And strong correlation between phase-resolved temperature profile and pressure cycle was observed. Results of the phase-resolved high temperature give an additional information on the perturbation of equivalence ratio at flame as well as the effect of mixing quality on NOx emission characteristics.

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EXACT RIEMANN SOLVERS FOR COMPRESSIBLE TWO-PHASE SHOCK TUBE PROBLEMS (압축성 이상(二相) 충격파관 문제에 대한 엄밀 리만해법)

  • Yeom, Geum-Su;Chang, Keun-Shik
    • Journal of computational fluids engineering
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    • v.15 no.3
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    • pp.73-80
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    • 2010
  • In this paper, we present the exact Riemann solver for the compressible liquid-gas two-phase shock tube problems. We hereby consider both isentropic and non-isentropic two-phase flows. The shock tube has a diaphragm in the mid-section which separates the liquid medium on the left and the gas medium on the right. By rupturing the diaphragm, various waves are observed on the phasic field variables such as pressure, density, temperature and void fraction in the form of rarefaction wave, shock wave and material interface (contact discontinuity). Both phases are treated as compressible fluids using the linearized equation of state or the stiffened-gas equation of state. We solve several shock tube problems made of a high/low pressure in the liquid and a low/high pressure in the gas. The wave propagations are well resolved by the exact Riemann solutions.

A Study on Thermodynamic Properties of Ethylene Gas Hydrate

  • Lim, Gye-Gyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.E1
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    • pp.10-15
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    • 2007
  • The gas hydrates are probably most sensitive to climate change since they are stable only under specific conditions of high pressure and low temperature. One of the main factors responsible for formation of gas hydrates is the saturation of the gases with water vapor. Quantitative phase equilibrium data and understanding of the roles of water component in the phase behavior of the heterogeneous water-hydrocarbon-hydrate mixture are of importance and of engineering value. In this study, the water content of ethylene gas in equilibrium with hydrate and water phases were analyzed by theoretical and experimental methods at temperatures between 274.15 up to 291.75 K and pressures between 593.99 to 8,443.18 kPa. The experimental and theoretical enhancement factors (EF) for the water content of ethylene gas and the fugacity coefficients of water and ethylene in gas phase were determined and compared with each other over the entire range of pressure carried out in this experiment. In order to get the theoretical enhancement factors, the modified Redlich-Kwong equation of state was used. The Peng-Robinson equations and modified Redlich-Kwong equations of state were used to get the fugacity coefficients for ethylene and water in the gas phase. The results predicted by both equations agree very well with the experimental values for the fugacity coefficients of the compressed ethylene gas containing small amount of water, whereas, those of water vapor do not in the ethylene rich gas at high temperature for hydrate formation locus.

Effect of Crystal Structures on the Sensing Properties of Nanophase $SnO_2$ Gas Sensor (나노상 $SnO_2$ 가스센서에서 센서검지특성에 미치는 결정구조의 영향)

  • 안재평;김선호;박종구;허무영
    • Journal of Powder Materials
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    • v.8 no.2
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    • pp.98-103
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    • 2001
  • Metallic tin powder with diameter less than 50 nm was synthesized by inert gas condensation method and subsequently oxidized to tin oxide ($SnO_2$) along the two heat-treatment routes. The $SnO_2$ powder of single phase with a tetragonal structure was obtained by the heat-treatment route with intermediate annealing step-wise oxidation, whereas the $SnO_2$ powder with mixture of orthorhombic and tetragonal phases was obtained by the heat-treatment route without intermediate annealing (direct oxidation). $SnO_2$ gas sensors fabricated from the nano-phase $SnO_2$ powders were investigated by structural observations as well as measurement of electrical resistance. The $SnO_2$ gas sensors fabricated from the mixed-phase powder exhibited much lower sensitivity against $H_2$ gas than those fabricated from the powder of tetragonal phase. Reduced sensitivity of gas sensors with the new orthorhombic phase was attributed to detrimental effects of phase boundaries between orthorhombic and tetragonal phases and many twin boundaries on the charge mobility.

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GAS-LIQUID TWO-PHASE HOMOGENEOUS MODEL FOR CAVITATING FLOW (캐비테이션 유동해석을 위한 기-액 2상 국소균질 모델)

  • Shin, Byeong-Rog
    • Journal of computational fluids engineering
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    • v.12 no.2
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    • pp.53-62
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    • 2007
  • A high resolution numerical method aimed at solving cavitating flow is proposed and applied to gas-liquid two-phase shock tube problem. The present method employs a finite-difference 4th-order Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL TVD scheme. By applying the homogeneous equilibrium cavitation model, the present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation and large density changes. The speed of sound for gas-liquid two-phase media is derived on the basis of thermodynamic relations and compared with that by eigenvalues. By this method, a Riemann problem for Euler equations of one dimensional shock tube was computed. Numerical results such as detailed observations of shock and expansion wave propagations through the gas-liquid two-phase media at isothermal condition and some data related to computational efficiency are made. Comparisons of predicted results and exact solutions are provided and discussed.

Effect of Process Parameters of UV Enhanced Gas Phase Cleaning on the Removal of PMMA (Polymethylmethacrylate) from a Si Substrate

  • Kwon, Sung Ku;Kim, Do Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.4
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    • pp.204-207
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    • 2016
  • Experimental study of UV-irradiated O2/H2 gas phase cleaning for PMMA (Polymethylmethacrylate) removal is carried out in a load-locked reactor equipped with a UV lamp and PBN heater. UV enhanced O2/H2 gas phase cleaning removes polymethylmethacrylate (PMMA) better at lower process pressure with higher content of H2. O2 gas compete for UV (184.9 nm) absorption with PMMA producing O3, O(1D) and lower dissociation of PMMA. In our experimental conditions, etching reaction of PMMA at the substrate temperature between 75℃ and 125℃ had activation energy of about 5.86 kcal/mol indicating etching was controlled by surface reaction. Above the 180℃, PMMA removal was governed by a supply of reaction gas rather than by substrate temperature.

Analysis of a gas-particle direct-contact heat exchanger with two-phase radiation effect (복사효과를 고려한 기체-입자 직접접촉식 열교환기 해석)

  • Park, Jae-Hyeon;Baek, Seung-Uk;Gwan, Se-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.4
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    • pp.542-550
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    • 1998
  • A direct contact heat exchanger using particle-suspended gas as a heat transfer medium is analyzed with an extended emphasis on the radiation, i. e., considering the radiation by both gas and particles. While the Runge-Kutta method is used for a numerical analysis of the momentum and energy equations, the finite volume method is utilized to solve the radiative transfer equation. Present study shows a notable effect by the gas radiation in addition to the particle radiation, especially when changing the chamber length as well as the gas and particle mass flow rate. When the gas and particle mass flow rate is raised, the gas temperature in the particle heater still increases as the gas absorption coefficient increases, which is different from the results for the small scale heat exchanger.

Greenhouse Gas Management Policy during Construction Execution Phase -Focused on Green Building Rating Systems and Japanese Case- (건축물 시공단계에서의 온실가스 배출 관리 방안 -국내외 친환경 인증제도와 일본 현장의 대응 방안을 중심으로-)

  • Song, Sang Hoon
    • KIEAE Journal
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    • v.10 no.5
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    • pp.139-150
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    • 2010
  • Until now, the eco-friendly construction (green construction) has been focused on reducing environmental impacts in use(operation and maintenance) phase. Considering the environmental influence along the life cycle of construction project, the impact in execution phase is rather lower than that in use phase. However, that impact is thought to be greatly decreased by well-organized activities. Based on its urgency and requirement for timely action, this study aimed to discuss the greenhouse gas (GHG) reduction plan in execution phase from a broad perspective. To achieve this purpose, the green building rating systems in domestic and foreign countries have been reviewed, and the practice in Japan was investigated. In order to improve current on-site greenhouse gas management, the integration among construction phases, participants, and environmental factors, and institutional supports are required as well as the contractor's efforts.

Morphological Effect of Dispersed Phase on Gas Separation Properties through Heterophase Polymer Membrane: Theoretical and Experimental Approaches.

  • Park, Cheolmin;Jo, Won-Ho;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.04a
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    • pp.55-56
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    • 1996
  • Heterophase polymer system has been attractive for a potential applicability to gas separation membrane material. It has been known that there is a trade-off between gas permeability and its selectivity in common polymers. Therefore, the heterophase polymer can be an alternative for a gas separation membrane material because its transport properties can be readily controlled by blending of two different polymers. The transport properties of immiscible polymer blends strongly depend upon the intrinsic transport properties of corresponding polymers. Another important factor to determine the transport properties is their morphology: volume fraction, size and shape of dispersed phase. Although the effect of the volume fraction of the dispersed phase on the transport properties has been widely investigated, the size and shape effects have been paid attention very much. In an immiscible polymer blend of two polymers, its morphology is primarily controlled by its volume fraction of dispersed phase. Therefore, the effect of the size of the dispersed phase can be hardly seen. Therefore, a block copolymer has been commonly employed to control their morphology when each block is miscible with one or the other phase. In this work, gas transport properties will be measured by varying the morphology of the heterophase polymer membrane. The transport properties will be interpreted in terms of their morphology. The effect of the volume fraction of the PI phase and, in particular, its size effect will be investigated experimentally and theoretically.

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Spray Combustion Simulation in Transverse Injecting Configurations

  • Yi, Yoon-Yong;Roh, Tae-Seong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.186-191
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    • 2004
  • The reactive flowfield of the transverse injecting combustor has been studied using Euler-Lagrange method in order to develop an efficient solution procedure for the understanding of liquid spray combustion in the transverse injecting combustor which has been widely used in ramjets and turbojet afterburners. The unsteady two-dimensional gas-phase equations have been represented in Eulerian coordinates and the liquid-phase equations have been formulated in Lagrangian coordinates. The gas-phase equations based on the conservation of mass, momentum, and energy have been supplemented by combustion. The vaporization model takes into account the transient effects associated with the droplet heating and the liquid-phase internal circulation. The droplet trajectories have been determined by the integration of the Lagrangian equation in the flow field obtained from the separate calculation without considering the iterative effect between liquid and gas phases. The reported droplet trajectories had been found to deviate from the initial conical path toward the flow direction in the very end of its lifetime when the droplet size had become small due to evaporation. The integration scheme has been based on the TEACH algorithm for gas-phase equation, the second order Runge-Kutta method for liquid-phase equations and the linear interpolation between the two coordinate systems. The calculation results has shown that the characteristics of the droplet penetration and recirculation have been strongly influenced by the interaction between gas and liquid phases in such a way that most of the vaporization process has been confined to the wake region of the injector, thereby improving the flame stabilization properties of the flowfield.

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