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Intergranular Corrosion Mechanism of Slightly-sensitized and UNSM-treated 316L Stainless Steel

  • Lee, J.H.;Kim, K.T.;Pyoun, Y.S.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.226-236
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    • 2016
  • 316L stainless steels have been widely used in many engineering fields, because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion and stress corrosion cracking etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled by methods such as the lowering of carbon content, solution heat treatment. This work focused on the intergranular corrosion mechanism of slightly-sensitized and Ultrasonic Nano-crystal Surface Modification (UNSM)-treated 316L stainless steel. Samples were sensitized for 1, 5, and 48 hours at $650^{\circ}C$ in $N_2$ gas atmosphere. Subsequently UNSM treatments were carried out on the surface of the samples. The results were discussed on the basis of the sensitization by chromium carbide and carbon segregation, the residual stress and grain refinement. Even though chromium carbide was not precipitated, the intergranular corrosion rate of 316L stainless steel was drastically increased with aging time, and it was confirmed that the increased intergranular corrosion rate of slightly-sensitized (not carbide formed) 316L stainless steel was due to the carbon segregation along the grain boundaries. However, UNSM treatment improved the intergranular corrosion resistance of aged stainless steels, and its improvement was due to the reduction of carbon segregation and the grain refinement of the outer surface, including the introduction of compressive residual stress.

Surface Modification of Polypropylene Membrane by ${\gamma}$ Irradiation Methods and their Solutes Permeation Behaviors

  • Shim, J. K.;Lee, S. H.;Kwon, O. H.;Lee, Y. M.;Nho, Y. C.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.99-101
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    • 1998
  • 1. Introduction : The conventional grafting polymerization technique requires chemically reactive groups on the surface as well as on the polymer chains. For this reason, a series of prefunctionalization steps are necessary for covalent grafting. The surface prefunctionalizational technique for grafting can be used to ionization radiation, UV, plasma, ion beam or chemical initiators. Of these techniques, radiation method is one of the useful methods because of uniform and rapid creation of active radical sites without catalytic contamination in grafted samples. If the diffusion of monomer into polymer is large enough to come to the inside of polymer substrate, a homogeneous and uniform grafting reaction can be carried out throughout the whole polymer substrate. Radiation-induced grafting method may attach specific functional moieties to a polymeric substrate, such as preirradiation and simultaneous irradiation. The former is irradiated at backbone polymer in vacuum or nitrogen gas and air, and then subsequent monomer grafting by trapped or peroxy radicals, while the latter is irradiated at backbone polymer in the presence of the monomer. Therefore, radiation-induced polymerization can be used to modification of the chemical and physical properties of the polymeric materials and has attracted considerable interest because it imparts desirable properties such as blood compatibility. membrane quality, ion excahnge, dyeability, protein adsorption, and immobilization of bioactive materials. Synthesizing biocompatible materials by radiation method such as preirradiation or simultaneous irradiation has often used $\gamma$-rays to graft hydrophilic monomers onto hydrophobic polymer substrates. In this work, in attempt to produce surfaces that show low levels of anti-fouling of bovine serum albumin(BSA) solutions, hydroxyethyl methacrylate(HEMA) was grafted polypropylene membrane surfaces by preirradiation technique. The anti-fouling effect of the polypropylene membrane after grafting was examined by permeation BSA solution.

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A Study on the Development Direction of the Renewable Energy Carbon Certification System: Focused on Analysis of International Trade Policy and the Dispute Cases Related to Environmental Labeling (재생에너지 탄소인증제도의 개발 방향성에 관한 연구 : 국제무역규범 및 환경라벨링 관련 무역 분쟁사례분석을 중심으로)

  • Sang, Min-Kyung;Han, Sung-Ae;Park, Sun-Hyo
    • Journal of the Korean Solar Energy Society
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    • v.39 no.6
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    • pp.1-13
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    • 2019
  • With the adoption of the Paris Agreement, a new climate regime is intensifying the global interest in reducing greenhouse gas emissions. In the meantime, Korea is preparing to introduce a new renewable energy carbon certification system in order to activate the use of renewable energy and to reduce carbon emissions in the entire life cycle of manufacturing and disposal of renewable energy facilities. Therefore, this study aims to identify the implications for the introduction of the carbon certification system and to establish a theoretical basis for the system design by examining the status of overseas carbon certification, international trade norms and trade disputes. As a result, carbon emissions certification is being implemented in developed countries such as EU, UK, France, USA and Japan, but only France, Germany and EU have adopted carbon certification for renewable energy sector. The analysis of the WTO TBT Agreement and GATT also confirmed the possibility of a violation of the international trade rules of the carbon certification system and derived nine international technical standards related to carbon certification. Finally, by examining the case of trade disputes related to environmental labeling, the minimum requirements to be considered at the institutional design stage were drawn to eliminate the possibility of trade disputes.

Technical Treatment on Foreign Invasive Marine Species of Living-things in ship′s Ballast-water (선박안정수의 해양외래침입생물체 처리 기술)

  • 소대화;장지도
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.7
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    • pp.1563-1568
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    • 2003
  • The introduction of invasive marine species of living things into new environments by ship's ballast water, attached to ships' hulls and via other vectors has been identified as one of the four greatest threats to the world's oceans by Global Environment Facility(GEF). Making use of the new technology of alpha-AL$_2$O$_3$ dielectric barrier layer, the strong electric-field gas discharge was introduced and obtained between micro-gap electrodes at high pressure (∼105㎩) of $O_2$ in air and $H_2O$ in seawater. The mixed air with $H_2O$ could be ionized and dissociated into large numbers of activated particles of OH, $O_2$+, O(1D), HO$_2$ and so on, and then dissolved into the ballast water to form dissolved hydroxyl radical with the concentration of ∼20mg/L. Therefore, the invasive marine species was treated effectively through the hydroxyl radical dissolved pipeline of ballast water by strong electric -field discharge.

Influence of α-SiC Seed Addition on Spark Plasma Sintering of β-SiC with Al-B-C: Microstructural Development (Al-B-C 조제 β-SiC의 스파크 플라즈마 소결에 미치는 α-SiC seed 첨가 영향: 미세 구조 변화)

  • Cho, Kyeong-Sik;Lee, Hyun-Kwuon;Lee, Sang-Woo
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.13-22
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    • 2010
  • The unique features of spark plasma sintering process are the possibilities of a very fast heating rate and a short holding time to obtain fully dense materials. $\beta$-SiC powder with 0, 2, 6, 10 wt% of $\alpha$-SiC particles (seeds) and 4 wt% of Al-B-C (sintering aids) were spark plasma sintered at $1700-1850^{\circ}C$ for 10 min. The heating rate, applied pressure and sintering atmosphere were kept at $100^{\circ}C/min$, 40 MPa and a flowing Ar gas (500 CC/min). Microstructural development of SiC as function of seed content and temperature during spark plasma sintering was investigated quantitatively and statistically using image analysis. Quantitative image analyses on the sintered SiC ceramics were conducted on the grain size, aspect ratio and grain size distribution of SiC. The microstructure of SiC sintered up to $1700^{\circ}C$ consisted of equiaxed grains. In contrast, the growth of large elongated SiC grains in small matrix grains was shown in sintered bodies at $1750^{\circ}C$ and the plate-like grains interlocking microstructure had been developed by increasing sintering temperature. The introduction of $\alpha$-SiC seeds into $\beta$-SiC accelerated the grain growth of elongated grains during sintering, resulting in the plate-like grains interlocking microstructure. In the $\alpha$-SiC seeds added in $\beta$-SiC, the rate of grain growth decreased with $\alpha$-SiC seed content, however, bulk density and aspect ratio of grains in sintered body increased.

The development of industrial secure L2 switch and introduction example for management and security improvement of supervisory control network in purification plant (정수장 감시제어망의 관리와 보안개선을 위한 산업용 보안 L2스위치 개발 및 적용사례)

  • Kim, Yunha;Yu, Chool;Oh, Eun;Kim, Chanmoon;Park, Ikdong;Kim, Yongseong;Choi, Hyunju
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.5
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    • pp.329-339
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    • 2019
  • Recently, the advancement of information and communication technology(ICT) is expanding the connectivity through Internet of Things(IoT), and the media of connection is also expanding from wire/cable transmission to broadband wireless communication, which has significantly improved mobility. This hyperconnectivity has become a key element of the fourth industrial revolution, whereas the supervisory control network of purification plants in korea is operated as a communication network separated from the outside, thereby lagging in terms of connectivity. This is considered the best way to ensure security, and thus there is hardly any consideration of establishing alternatives to operate an efficient and stable communication network. Moreover, security for management of a commercialized communication network and network management solution may be accompanied by immense costs, making it more difficult to make new attempts. Therefore, to improve the conditions for the current supervisory control network of purification plants, this study developed a industrial security L2 switch that supports modbus TCP(Transmission Control Protocol) communication and encryption function of the transmission section. As a result, the communication security performance improved significantly, and the cost for implementing the network management system using Historical Trend and information of HMI(Human Machine Interface) could be reduced by approximately KRW 200 million. The results of this study may be applied to systems for gas, electricity and social safety nets that are infrastructure communication networks that are similar to purification plants.

Feasibility Identification on Establishment of Solar Energy (Photovoltaic and Solar Heating) at the Environmental Basic Facilities in Busan (부산시 환경기초시설 내 태양에너지(태양광/태양열) 이용 시설 설치 타당성 확인)

  • Kim, Jiwon;Choi, Hyunho;Kim, Samuel;Park, Jeahong;Kim, Donghyun;Lee, Daeseon;Park, Sangtae;Kim, Gyusik;Yu, Jaecheul
    • Journal of Climate Change Research
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    • v.6 no.2
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    • pp.73-85
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    • 2015
  • With 12 environmental basic facilities (EBF) in Busan, each business place's present situation of the operation of new and renewable energy as well as the feasibility to establish additional systems of utilizing solar energy (photovoltaic power generation system [PPGS] and solar heating system [SHS]) were investigated. Currently, with the environmental basic facilities, the new and renewable energies (such as, waste heat, biogas, PPGS, SHS, and small hydro power) can produce 195 GWh per year as electric power unit. Among the energy sources, except waste heat, biogas (154 GWh/yr) appears as the highest. Next, PPGS is the second most widely used system and produces 5,560 MWh/yr at 11 business places. Through a field survey, it appears that 19 business places of total 27 places at 12 EBFs have good locational conditions and they need an introduction of PPGS. Through it, it is investigated that it would be possible to produce 5,311 MWh/yr and to reduce $2,348tCO_2/yr$. And, it is identified that SHS can be additionally introduced in only 4 EBFs. This can reduce energy cost as much as one ten million won/yr and green-house gas as much as $28tCO_2/yr$. A cost-benefic analysis shows that the use of governmental support or private investment can be the most efficient way, when PPGS and SHS are introduced in EBFs.

Variation of the CO2 Capture Reaction by Ammonia Solution with Temperature (온도에 따른 암모니아 용액에 의한 CO2 포집 반응의 변화 양상)

  • Kim, Soo-Yeon;Choi, Ye-Seul;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.6
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    • pp.896-904
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    • 2011
  • The features of the capture reaction of $CO_2$ by ammonia solution have been investigated along with the effect of temperature on the reaction based upon computer program-utilizing calculation and thermodynamic estimation. The stable region of $CO{_3}^{2-}$ was observed to increase with temperature and the change of the stable region of $CO{_3}^{2-}$ with temperature was greater than the temperature variation of the stable region of other carbonate species. The distribution diagram for $NH_4{^+}-NH_3$ system was constructed and the rise of temperature resulted in the decrease of the stability of $NH_4{^+}$ ion, which was thought to be due to the endothermic nature of its acidic dissociation. Considering the introduction of $Ca^{2+}$ ion in the carbon capture reaction by $NH_4{^+}$, the temperature was observed to be important in the determination of the order of reaction between carbonate ion and these cations. The removal process of $CO_2$ gas by ammonia solution was presumed to occur in open system and the temperature variations of the concentration of carbonate system species along with their total concentration were calculated for the proper control and design of the real process.

Introduction to Image Processing Technology for Precise Positioning of Underground Buried Lifelines (영상정보 기반 지하매설관 정밀 위치조사 기술 소개)

  • Ryu, Byunghyun;Cheon, Jangwoo;Lee, Chulhee;Lee, Impyeong;Lee, Jangguen;Kang, Jaemo
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.12
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    • pp.51-57
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    • 2021
  • Underground lifelines such as water supply/sewer pipe, power cable and gas pipe are indispensable facilities to the life of urban society. These lifelines have been constructed long time ago and buried positioning information is not precisely recorded. Moreover, they have been concentrated on the narrow area and are complicatedly entangled in 3-dimension. In the fourth industrial revolution, a 3-dimensional visualization for underground lifelines is strongly required, and a database (D/B) with precise positioning information should be preceded. In this study, image processing technology for precise positioning of underground buried lifelines is introduced, which is able to build the database more accurately, efficiently and practically.

Monitoring of air Pollution on the Premises of the Factory Sharrcem - L.L.C

  • Luzha, Ibush;Shabani, Milazim;Baftiu, Naim
    • International Journal of Computer Science & Network Security
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    • v.22 no.10
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    • pp.214-222
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    • 2022
  • In these proceedings, we will address the problem of air pollution on the premises of the Cement factory SHARRCEM L.L.C. in Hani Elezit in the Republic of Kosovo respectively around the clinker cooler, rotary kiln, and raw material mill. By air pollution, we mean the introduction of chemicals, particles, or other harmful materials into the atmosphere which in one way or another causing damage to the development of plants and organisms. Air pollution occurs when certain substances are released into the air, which depending on the quantitative level, can be harmful to human health, animals, and the environment in general. The analysis of air shows the influence of the extractive and processing industry on the chemical composition of air. Parameters analyzed though under control such as the case of carbon dioxide, due to the increasing production capacity of cement, the production of hundreds of thousands of cubic meters of CO2 gas made CO2 production a concern. With the purchase of the latest technology by the SHARCEM Factory in Hani Elezit, the amount of air pollution has been reduced and the allowed parameters of environmental pollution have been kept under control. Air pollutants are introduced into the atmosphere from various sources which change the composition of the atmosphere and affect the biotic environment.The concentration of air pollutants depends not only on the quantities that are emitted from the sources of air pollution but also on the ability of the atmosphere to absorb or disperse these emissions. Sources of air pollutants include vehicles, industry, indoor sources, and natural resources. There are some natural pollutants, such as natural fog, particles from volcanic eruptions, pollen grains, bacteria, and so on.