• 제목/요약/키워드: Gas in Oil

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Corrosion and Materials Selection for Bitumen with Heavy Naphthenic Acid in Canadian Oil Sands

  • Eun, Thomas Jung-Chul
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.350-361
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    • 2008
  • Canada's oil sands contain one of the largest reserves of oil in the world. According to recent estimates, there are nearly 180 billion barrels of oil in the Canadian oil sands trapped in a complex mixture of sand, water and clay. More than 40 companies have been currently operating or developing oil sands facilities since the first production in 1967. The process of oil sands upgrading is similar with down stream refinery, but the corrosion environment in upgrading refinery is often more severe than in the refinery because of high chlorides, mineral contents, carbonic acid, heavy viscosity and fouling, higher naphthenic acid [$NA-R(CH_{2})nCOOH$], and greater sulfur contents. Naphthenic acid corrosion (NAC) which is one of the most critical corrosion issues in up & downstream refinery plants was observed for the first time in 1920's in refinery distillation processes of Rumania, Azerbaizan (Baku), Venezuela, and California. As a first API report, the 11th annual meeting stated sources and mechanism of NAC in early 1930's. API has been developing the risk base standards, such as API RP580, 571, and Publication 581 which are based on the worst NAC damage in the world since 2000. Nevertheless not only the NAC phenomena and control in Canadian sands oil process are not much widely known but also there are still no engineering guidances for the Canadian sands oil in API standards. This paper will give NAC phenomina and materials selection guidance against NA environment in Canadian oil sands upgrading processes.

Perspective on Maritime Boundary Delimitation through Oil and Gas Development Dispute between China and Japan in the East China Sea (동중국해 중.일 유전 개발 분쟁을 통해 본 양국의 해양경계획정에 대한 입장 연구)

  • Yang, Hee-Cheol;Park, Seong-Wook;Park, Se-Hun
    • Ocean and Polar Research
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    • v.28 no.2
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    • pp.175-186
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    • 2006
  • There are disputes for oil and gas development between China and Japan in the East China Sea. These involve the area where China is already carrying out activities of oil and gas development and where Japan is proclaiming its EEZ. China insists that the Chinese activities on oil and gas development area are being carried out within the Chinese jurisdictional waters even if the median line principle of Japanese proclamation is applied in delimitation. Indeed, the permit for Japanese development is causing disputes between China and Japan because its permit allows development in the waters adjacent to Chinese development area. h the event, the core of this dispute around the oil and gas field in the East China Sea relates to issues of maritime boundary delimitation and issues of resources acquisition with both states. Chinese policy on oil and gas development is to first consider development issues in accordance with a median line principle where waters toward to China from the median line should be developed by China and the area toward Japan from the median line within the Chinese continental shelf should be jointly developed. However, the Japanese position is that the East China Sea should be jointly developed, and Japan hopes to eventually convince China to accept its median line delimitation. With on-going development of such issues, Korea should establish a strategy of negotiation based on analyses of resource distributional conditions and other strategic factors in the Korean delimitation area. In particular, Korea should prepare and make the best use of joint development zone established in an agreement between the ROK and Japan concerning the development of the southern part of continental shelf adjacent to both states.

Detection of Hydrogen Gas Dissolved in Insulation Oil Based on Palladium-coated Fiber Bragg Grating (팔라듐이 코팅된 광섬유 격자를 이용한 절연유속의 용존 수소가스 검출)

  • Kim, Kwang Taek;Choi, Nu ri;Baik, Se-Jong
    • Journal of Sensor Science and Technology
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    • v.27 no.6
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    • pp.403-406
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    • 2018
  • We have investigated a fiber-optic sensor for detecting the hydrogen gas dissolved in insulation oil based on a palladium (Pd)-coated fiber Bragg grating (FBG). As the palladium absorbs the hydrogen gas dissolved in the insulation oil, its volume expands and the Bragg wavelength shifts to a longer wavelength. The experimental results showed that the Bragg wavelength of FBG increased to 70 nm when the concentration of hydrogen dissolved in the insulation oil was 409 ppm.

A Study on Syngas Co-combustion Characteristics in a Heavy Oil Combustion System with Multi Burners (멀티 버너 중유 연소로에서의 합성 가스 혼합 연소 특성 연구)

  • Yang, Dong-Jin;Choi, Shin-Young;Yang, Won
    • Journal of the Korean Society of Combustion
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    • v.15 no.1
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    • pp.43-49
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    • 2010
  • Co-combustion of syngas in an existing boiler can be one of the options for replacing conventional fossil fuel with alternative fuels such as waste and biomass. This study is aimed to investigate effects of syngas cocombustion on combustion characteristics and boiler efficiency. An experimental study was performed for a pilot-scale furnace with 4 oil burners. Tests were conducted with mixture-gas as a co-combustion fuel and heavy oil as a main fuel. The mixture-gas was composed of 15% CO, 7% $H_2$, 3% $CH_4$ and 75% $N_2$ for simulating syngas from air-blown gasification. And LHV of the mixture-gas was 890 kcal/$Nm^3$. Temperature distribution in the furnace and flue gas composition were measured for various heat replacement ratio by the mixture gas. Heat loss through the wall was also carried out through heat & mass balance calculation, in order to obtain informations related to boiler efficiency. Experimental results show that similar temperature distribution and flue gas composition can be obtained for the range of 0~20% heat replacement by syngas. NOx concentration is slightly decreased for higher heat replacement by the syngas because fuel NOx is decreased in the case. Meanwhile, heat loss is a bit decreased for higher heat replacement by the syngas, which implies that boiler efficiency can be a bit decreased when syngas co-combustion is applied to a boiler.

An Experimental Study on Oil Effect of CO2 in Heat Pump Outdoor Heat Exchanger (CO2용 실외열교환기의 오일 영향에 따른 성능변화에 대한 실험적 연구)

  • Lee, Jin-Gwan;Chang, Young-Soo;Kim, Seo-Young;Kim, Yong-Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.4
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    • pp.243-250
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    • 2011
  • In order to investigate the effects of PAG oil concentration on heat transfer performance and pressure drop during gas cooling process of $CO_2$, the experiments on fin-tube heat exchanger of $CO_2$ heat pump were performed. The experimental apparatus consists of a gas cooler, a heater, a chiller, a mass flow meter, a pump and measurement system. Experiments were conducted in various experimental conditions, which were inlet temperature($110^{\circ}C$), mass flow rates (50, 55, 60, 65, 70 g/s) and PAG oil concentration(0 to 2.6 wt%). Heat transfer rate decreased with the increase of the oil concentration and the decrease of inlet pressure. And pressure drop increased with the increase of the oil concentration and mass flow rate of refrigerant. The COP reduction by deterioration of gas cooler performance with oil concentration was analyzed. When inlet pressure of gas cooler is 100 bar, the COP reduction was estimated by 6% under 1 wt% of oil concentration.

Characteristic Classification of Aroma Oil with Gas Sensors Array and Pattern Recognition (가스센서 어레이와 패턴인식을 활용한 아로마 오일의 특성 분류)

  • Choi, Il-Hwan;Hong, Sung-Joo;Kim, Sun-Tae
    • Journal of Sensor Science and Technology
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    • v.27 no.2
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    • pp.118-125
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    • 2018
  • An evaluation system for an electronic-nose concept using three types of metal oxide gas sensors that react similarly to the human olfactory cells was constructed for the quantitative and qualitative evaluation of aroma fragrances. Four types of aroma fragrances (lavender, orange, jasmine, and Roman chamomile), which are commonly used in aromatherapy, were evaluated. All the gas sensors reacted remarkably to the aroma fragrances and the good correlation of r=0.58-0.88 with the aromatic odor intensities by olfaction was confirmed. From the results of the analysis of an electronic-nose concept for classifying the characteristics of aroma oil fragrances, aroma oils could be classified using the fragrance characteristics and oil extraction methods with the cumulative variability contribution rate of 95.65% (F1: 69.65%, F2: 26.03%) by principal component analysis. In the pattern recognition based on the artificial neural network, the four aroma fragrances were 100% recognized through the training data of 56 cases (70%) out of 80 cases, and the pattern recognition rate was 57.1%-71.4% through the validation and testing data of 24 cases (30%). The pattern recognition success rate through all confusion matrices was 82.1%, indicating that the classification of aroma oil fragrances using the three types of gas sensors was successful.

Strategies of Technology Development for Improvement of National Energy Resources Supply (국내 에너지자원 자급률 향상을 위한 기술개발 전략)

  • Lim, Jong-Se
    • Journal of Energy Engineering
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    • v.19 no.2
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    • pp.57-61
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    • 2010
  • In order to make higher domestic self-sufficiency ratio of energy resources, these are required to purchase the producing oil & gas fields through the investment of oversea petroleum development, to make M&A, and to enhance recovery in the existing oil & gas fields. For this purpose, it is essential to acquire the core technology regarding the evaluation, design, and management of oil & gas fields. The accumulation of technology of the evaluation, optimal design, proper management of production fields by the help of the continuous R&D program will make great contribution for higher domestic self-sufficiency ratio by the increased number of purchase of foreign producing fields, the increase amount of produced petroleum out of existing fields, and the effective management of the oil and gas fields.

Study of Toxic Gas Removal Characteristics by Chemical Analysis of Essential Oil using SPME Method (SPME법을 이용한 식물정유 성분분석을 통한 유해가스 제거 특성연구)

  • 박영규
    • KSBB Journal
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    • v.19 no.3
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    • pp.231-235
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    • 2004
  • This paper was investigated to clarify the possibility of ammonia gas removal by essential oil. First of all, the chemical analysis was peformed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil react with ammonia by neutralization and their reaction mechanism was elucidated. Based on their chemical neutralized reaction, the removal efficiencies of ammonia gas were studied to derive the optimal conditions in the scrubber tower such as optimal temperature and pH. The experimental result shows that the removal efficiency of ammonia gas was achieved over 98 % by the misty aerosol dispersion of scrubber tower.

A Study on the integrity assessment of the high voltage transformer with Dissolved Gas Analysis (특고압 변압기 건전성 평가에 관한 연구)

  • Lee, Il-Moo;You, Sang-Bong;Joung, Hea-Sung
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1463-1464
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    • 2015
  • This paper describes for the diagnosis insulating oil for transformers integrity assessment. The high-capacity oil transformer has several insulators are entered for the purpose of insulation, such as insulating oil, insulating paper and press board. Irradiated with a gas component dissolved in the insulating oil can analyze the status of the transformer, and can prevent a sudden accident in advance.

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Comparison of combustion characteristics between esterified and non-esterified bio-diesel oil on CRDI diesel engine with turbocharger (전자 제어 분사식 과급디젤기관에서 에스테르화와 비에스테르화 바이오 디젤유의 연소 특성 비교)

  • Lee, Sang Deuk;Jung, Suk Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.1
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    • pp.53-58
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    • 2013
  • In order to judge that non-esterified soybean oil could be used on diesel engine with electronic control of fuel injection system, The test of combustion performance using only gas oil, gas oil blended with esterified bio-diesel oil 5% and non-esterified soybean oil 5% were carried out. It is noticed that most performances of gas oil blended with esterified bio-diesel oil 5% and non-esterified 5% have similar characteristics but non-esterified bio-diesel oil 5% emitted smaller NOx, resulting from fuel NO.