• Title/Summary/Keyword: Gas diffusion test

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An Experimental Study on the Estimation of Chloride Diffusion Coefficient of LNG Storage Tanks (LNG 저장탱크 염해 확산 계수 산출을 위한 실험적 고찰)

  • Lee, Seung-Rim;Hwang, Seung-Hyun
    • Journal of Energy Engineering
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    • v.21 no.2
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    • pp.119-123
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    • 2012
  • Although LNG storage tanks are very delicate with chloride attack owing to its operating inshore location, specific integrity management system for chloride attack has not been studied so far. As the design warranty life time, about 25 years, has come, to prevent paying huge amount of construction cost and required resources for new alternative storage tanks and manage the life time of operating storage tanks, the basic data of chloride attack is necessary. This study intended to build up basic data for following detailed study to develop technologies for life time management of LNG storage tanks, NT Build 492 method in North Europe was used to test chloride diffusion coefficient for the newly-constructing concrete outer tank. Results of these tests lead us to the conclusion that 90 days diffusion coefficients show 46% of 28 days' due to a large quantity of fly ash mixing and much similar to estimation from concrete process table. It seems resonable to conclude that 90 days specimens are recommended estimating the chloride diffusion coefficient for LNG storage tanks to enhance the reliabilities.

The Stress Distribution Analysis of PEMFC GDL using FEM (유한요소법을 이용한 고분자전해질연료전지 기체확산층의 응력분포 연구)

  • Kim, Chulhyun;Sohn, Youngjun;Park, Gugon;Kim, Minjin;Lee, Jonguk;Kim, Changsoo;Choi, Yusong;Cho, Sungbaek
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.468-475
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    • 2012
  • A proper stacking force and assembly are important to the performance of fuel cell. Improper assembly pressure may lead to leakage of fuels and high interfacial contact resistance, excessive assembly pressure may result in damage to the gas diffusion layer and other components. The pressure distribution of gas diffusion layer is important to make interfacial contact resistance less for stack performance. To analyze the influence of design parameter factors for pressure distribution, and to optimize stack design, DOE (Design of Experiment) was used for polymer electrolyte membrane fuel cell stack pressure test. As commonly known, the higher clamping force improves the fuel cell stack performance. However, non-uniformity of stress distribution is also increased. It shows that optimization between clamping force and stress distribution is needed for well designed structure of fuel cell stack. In this study, stack design optimization method is suggested by using FEM (Finite Element Methode) and DOE for light-weighted fuel cell stack.

In situ isolation and characterization of the biosurfactants of B. Subtilis

  • Akthar, Wasim S.;Aadham, Mohamed Sheik;Nisha, Arif S.
    • Advances in environmental research
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    • v.9 no.3
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    • pp.215-232
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    • 2020
  • Crude oils are essential source of energy. It is majorly found in geographical locations beneath the earth's surface and crude oil is the main factor for the economic developments in the world. Natural crude oil contains unrefined petroleum composed of hydrocarbons of various molecular weights and it contains other organic materials like aromatic compounds, sulphur compounds, and many other organic compounds. These hydrocarbons are rapidly getting degraded by biosurfactant producing microorganisms. The present study deals with the isolation, purification, and characterization of biosurfactant producing microorganism from oil-contaminated soil. The ability of the microorganism producing biosurfactant was investigated by well diffusion method, drop collapse test, emulsification test, oil displacement activity, and blue agar plate method. The isolate obtained from the oil contaminated soil was identified as Bacillus subtilis. The identification was done by microscopic examinations and further characterization was done by Biochemical tests and 16SrRNA gene sequencing. Purification of the biosurfactant was performed by simple liquid-liquid extraction, and characterization of extracted biosurfactants was done using Fourier transform infrared spectroscopy (FTIR). The degradation of crude oil upon treatment with the partially purified biosurfactant was analyzed by FTIR spectroscopy and Gas-chromatography mass spectroscopy (GC-MS).

Electron Energy Distribution Function in SF6-He Gas by Simulation (시뮬레이션에 의한 SF6-He 혼합기체에서 전자에너지 분포함수)

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.1
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    • pp.19-23
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    • 2014
  • This paper describes the electron transport characteristics in $SF_6$-He gas calculated E/N values 0.1~700[Td] by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters obtained by TOF method. This study gained the values of the electron swarm parameters such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients for $SF_6$-He gas at a range of E/N. A set of electron collision cross section has been assembled and used in Monte Carlo simulation to predict values of swarm parameters. The result of Boltzmann equation and Monte Carlo Simulation has been compared with experimental data by Ohmori, Lucas and Carter. The swarm parameter from the swarm study are expected to sever as a critical test of current theories of low energy scattering by atoms and molecules.

Investigation on the Liquid Water Droplet Instability in a Simulated Flow Channel of PEMFC (고분자전해질형 연료전지의 유로 채널 모사를 통한 단일 액적의 불안정성 관찰)

  • Kim, Bo-Kyung;Kim, Han-Sang;Min, Kyung-Doug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.2
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    • pp.93-98
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    • 2008
  • To investigate the characteristics of water droplet on the gas diffusion layer from both top-view and side-view of the flow channel, a rig test apparatus was designed and fabricated with prism attached plate. This experimental device is used to simulate the growth of single liquid water droplet and its transport process with various air flow velocity and channel height. The contact angle hysteresis and height of water droplet are measured and analyzed. It is found that droplet tends towards to be instable by decreasing channel height, increasing flow velocity or making GDL more hydrophobic. Also, the simplified force balance model matches with experimental data only in a restricted range of operating conditions and shows discrepancy as the air flow velocity and channel height increases.

Physical and Mechanical Properties of Cementitious Specimens Exposed to an Electrochemically Derived Accelerated Leaching of Calcium

  • Babaahmadi, Arezou;Tang, Luping;Abbas, Zareen;Martensson, Per
    • International Journal of Concrete Structures and Materials
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    • v.9 no.3
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    • pp.295-306
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    • 2015
  • Simulating natural leaching process for cementitious materials is essential to perform long-term safety assessments of repositories for nuclear waste. However, the current test methods in literature are time consuming, limited to crushed material and often produce small size samples which are not suitable for further testing. This paper presents the results from the study of the physical (gas permeability as well as chloride diffusion coefficient) and mechanical properties (tensile and compressive strength and elastic modulus) of solid cementitious specimens which have been depleted in calcium by the use of a newly developed method for accelerated calcium leaching of solid specimens of flexible size. The results show that up to 4 times increase in capillary water absorption, 10 times higher gas permeability and at least 3 times higher chloride diffusion rate, is expected due to complete leaching of the Portlandite. This coincides with a 70 % decrease in mechanical strength and more than 40 % decrease in elastic modulus.

Study on Performance and Durability of the Proton Exchange Membrane Fuel Cell with Different Micro Porous Layer Penetration Thickness (미세다공층의 침투깊이가 다른 기체확산층이 고분자전해질 연료전지의 성능과 내구성에 미치는 영향에 관한 연구)

  • Cho, Junhyun;Park, Jaeman;Oh, Hwanyeong;Min, Kyoungdoug;Jyoung, Jy-Young;Lee, Eunsook
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.81.2-81.2
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    • 2011
  • The gas diffusion layer (GDL) consists of two main parts, the GDL backing layer, called as a substrate and the micro porous layer (MPL) coated on the GDBL. In this process, carbon particles of MPL penetrates to the GDBL consequently forms MPL penetration part. In this study, the micro porous layer (MPL) penetration thickness is determined as a design parameter of the GDL which affect pore size distribution profile through the GDL inducing different mass transfer characteristics. The pore size distribution and water permeability characteristics of the GDL are investigated and the cell performance is evaluated under fully/low humidification conditions. Transient response and voltage instability are also studied. In addition, to determine the effects of MPL penetration on the degradation, the carbon corrosion stress test is conducted. The GDL that have deep MPL penetration thickness shows better performance in high current density region because of enhanced water management, however, loss of penetrated MPL parts is shown after aging and it induces worse water management characteristics.

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Vacuum Carburizing System for Powdered Metal Parts & Components

  • Kowakewski, Janusz;Kucharski, Karol
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1018-1021
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    • 2006
  • Powdered metal parts and components may be carburized successfully in a vacuum furnace by combining carburizing technology $VacCarb^{TM}$ with a hi-tech control system. This approach is different from traditional carburizing methods, because vacuum carburizing is a non-equilibrium process. It is not possible to set the carbon potential as in a traditional carburizing atmosphere and control its composition in order to obtain a desired carburized case. This paper presents test results that demonstrate that vacuum carburizing system $VacCarb^{TM}$ carburized P.M. materials faster than traditional steel with acceptable results. In the experiments conducted, PM samples with the lowest density and open porosity showed a dramatic increase in the surface carbon content up to 2.5%C and a 3 times deeper case. Currently the boost-diffusion technique is applied to control the surface carbon content and distribution in the case. In the first boost step, the flow of the carburizing gas has to be sufficient to saturate the austenite, while avoiding soot deposition and formation of massive carbides. To accomplish this goal, the proper gas flow rate has to be calculated. In the case of P.M. parts, more carbon can be absorbed by the part's surface because of the additional internal surface area created by pores present in the carburized case. This amount will depend on the density of the part, the densification grade of the surface layer and the stage of the surface. "as machined" or "as sintered". It is believed that enhanced gas diffusion after initial evacuation of the P.M. parts leads to faster carburization from within the pores, especially when pores are open . surface "as sintered" and interconnected . low density. A serious problem with vacuum carburizing is delivery of the carbon in a uniform manner to the work pieces. This led to the development of the different methods of carburizing gas circulation such as the pulse/pump method or the pulse/pause technique applied in SECO/WARWICK's $VacCarb^{TM}$ Technology. In both cases, each pressure change may deliver fresh carburizing atmosphere into the pores and leads to faster carburization from within the pores. Since today's control of vacuum carburizing is based largely on empirical results, presented experiments may lead to better understanding and improved control of the process.

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Review of pulmonary function test in terms of insurance medicine (폐기능검사의 보험의학적 이해)

  • Lee, Sinhyung
    • The Journal of the Korean life insurance medical association
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    • v.33 no.2
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    • pp.8-11
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    • 2014
  • Pulmonary function test is a group of tests which are composed of measurement for lung function. Thy are spirometry, blood-gas analysis, lung volumes, exercise test, diffusion capacity, and bronchial challenge test. In this article, I will review the pulmonary function test and it's application in terms of clinical aspect and insurance medicine. The standard spirometric indicies are forced vital capacity(FVC), forced expiratory volume at 1 second(FEV1), and the ratio of FEV1 over FVC(FEV1/FVC). If the value of FEV1/FVC less than 70%, the examinee has obstructive ventilatory dysfunction.

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A study on the Structure of Turbulent Diffusion Flame Behind the Hollowed Flame Holder (중앙분공형 보염기 후류에 안정된 난류확산화염의 구조에 관한 연구(I))

  • Kang, I.G.;Lee, W.S.;Kim, T.H.;Lee, D.H.
    • Journal of Power System Engineering
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    • v.2 no.2
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    • pp.13-19
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    • 1998
  • The purpose of study is to investigate the flame stability and Structure of turbulent diffusion flame behind the hollowed flame holder, which is located on the waste gas coming out from the test furnace. Fluctuating temperature and ion current measurement and their statistical treatment were used for the purpose. Three types of flame were stabilized and each of which were changed by adequate equivalence ration. And we found that have no periodicity near reacting zone.

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