• 제목/요약/키워드: Gas Transport

검색결과 861건 처리시간 0.025초

DC 마그네트론 스퍼터링을 이용한 IZO 박막의 제조와 특성 연구 (Preparation and Characterization of IZO Thin Films grown by DC Magnetron Sputtering)

  • 박창하;이학준;김현범;김동호;이건환
    • 한국표면공학회지
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    • 제38권5호
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    • pp.188-192
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    • 2005
  • Indium zinc oxide (IZO) thin films were deposited on glass substrate by dc magnetron sputtering. The effects of oxygen flow rate and deposition temperature on electrical and optical properties of the films were investigated. With addition of small amount of oxygen gas, the characteristic properties of amorphous IZO films were improved and the specific resistivity was about $4.8{\times}10^{-4}\Omega{\cdot}cm$. Change of structural properties according to the deposition temperature was observed with XRD, SEM, and AFM. Films deposited above $300^{\circ}C$ were found to be polycrystalline. Surface roughness of the films was increased due to the formation of grains on the surface. Electrical conductivity became deteriorated for polycrystalline IZO films. Consequently, high quality IZO films could be prepared by do sputtering with $O_{2}/Ar{\simeq}0.03$ and deposition temperature in range of $150\~200^{\circ}C$; a specific resistivity of $3.4{\times}10^{-4}{\Omega}{\cdot}cm$, an optical transmission over $90\%$ at wavelength of 550 nm, and a rms value of surface roughness about $3{\AA}$.

일본의 해양기본법 제정과 우리의 대응방안 연구 -한중일 해양행정체계 비교를 중심으로- (A Study on the Analysis of Japan's Basic Ocean Law and Policy of Korea -The Case of Korea, Japan and China on the Administrative System for Ocean-)

  • 박성욱;양희철
    • Ocean and Polar Research
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    • 제30권1호
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    • pp.119-128
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    • 2008
  • Japan's new Basic Ocean Law took effect in 20 July 2007. This law contains that 1) calls for the consolidation of eight government offices that previously worked separately on maritime issues; 2) establishes a basic plan for maritime matters, and; 3) creates a comprehensive maritime policy headquarters, run by the Prime Minister. The result is a structure for the integrated promotion of maritime policy. The Minister of Land, Infrastructure and Transport has been appointed to the newly established position of maritime minister. Japan has been in conflict with Korea and China over EEZ and territory, which has caused the country to turn to ocean. If Japan puts more emphasis on sea, it will be on a collision course with neighboring countries such as Korea, China, Russia, and Taiwan. Japan has been at odds with these countries; with Korea over Dokdo islets, with China over the Senkaku Islands and the East China Sea, where gas fields lie, with Taiwan over fishery rights in the East China Sea, with Russia over the Kuril Islands. Korea's position about the establishment of Japan's new Basic Ocean Law is followed: 1) expression of Korea's position in maritime resourcces of east china sea, 2) understand of strategy for maritime resources development and maritime delimitation in China and Japan, 3) a caution for extention of EEZ and maritime activities, 4)effective and comprehensive policy establishment, and strength in R&D, 5) construction of active and responsive system for maritime issues in neighbor country.

우리나라 대기오염배출 원인과 저감 정책 효과 분석 (Causes of Air pollution and Effects of Mitigation Policy in Korea)

  • 배정환;김유선
    • 자원ㆍ환경경제연구
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    • 제25권4호
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    • pp.545-564
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    • 2016
  • 최근 우리나라는 미세먼지 및 초미세먼지 문제가 크게 대두되면서 대기오염문제에 대한 효과적인 해결책이 중요해진 시점에 있다. 본 연구는 대기오염의 원인을 계량경제모형을 통해 찾아보고, 경유가격 인상정책이 경유소비 감소와 대기오염의 저감에 기여하는지를 분석해보았다. 대기오염물질로는 TSP, PM10, $NO_X$, $SO_X$, CO, VOC가 포함되었다. 분석 결과 CO를 제외하고 모든 오염물질에서 경제성장은 역U자형의 영향을 미치는 것으로 나타났고, 소비자 물가지수, 화력발전설비, 경유소비, 황사발생일수, 천연가스버스, 운수업체 사업장수, 평균기온, 제조업체 사업장수 등이 대기오염에 영향을 미치는 변수로 나타났다. 또한 경유가격이 1% 상승하면 대기오염물질은 단기적으로는 0.07~0.12% 감소하고, 장기적으로는 0.31~0.53% 감소하는 것으로 나타났다. 따라서 환경개선부담금의 형태로 경유가격을 올리고, 그 수입원을 바이오디젤 보급 지원에 사용한다면 보다 효과적인 대기오염 개선을 기대할 수 있다.

평행류와 Interdigitated 유로를 가진 교분자 전해질 연료전지(PEMFC)의 성능특성에 대한 수치해석 (Numerical Analysis on Performance Characteristics of PEMFC with Parallel and Interdigitated Flow Channel)

  • 이필형;조선아;최성훈;황상순
    • 전기화학회지
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    • 제9권4호
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    • pp.170-177
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    • 2006
  • 고분자 전해질 연료전지의 분리판의 유동채널 설계는 고전류밀도에서 발생하는 농도분극에 직접적인 영향을 줄 뿐 아니라 생성되는 물의 효과적인 전달을 위하여 매우 중요하다. 평행류 유로와 interdigitated 유로의 성능비교를 위하여 연료극과 공기극이 포함된 완전한 형태의 고분자 전해질 연료전지의 3차원 수치해석모델을 개발하였다. 수치해석모델을 사용하여 평행류 유동장과 interdigitated 유동장의 압력강하, 채널간의 물질전달, $H_2O$$O_2$의 농도 분포 그리고 i-V 성능을 비교하였다. 그 결과 물질전달에서 채널간의 대류에 의한 물질전할이 더욱 우수한 interdigitated 유동채널에서 성능이 더 높게 나타났으며 압력강하는 보다 크게 나타나 설계시 두가지 성능에 대한 상호보완이 필요함을 알 수 있었다.

Assessment of the Nitrate Radical Chemistry and Chemical Composition on Jeju Island during the Asian Pollution Period in the Spring of 2001

  • Shon, Zang-Ho;Kim, Ki-Hyun;Keith N. Bower;Lee, Gangwoong;Kim, Jiyoung
    • Journal of Korean Society for Atmospheric Environment
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    • 제19권E3호
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    • pp.137-148
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    • 2003
  • In this study, we examined the influence of long-range transport of dust particles and air pollutants on the photochemistry of NO$_3$on Jeju Island, Korea (33.17 N, 126.10$^{\circ}$E) during the Asian Dust-Storm (ADS) period of April 2001. Three ADS events were observed during the periods of 10∼12, 13∼14, and 25∼26 April. Average concentration level of nighttime NO$_3$on Jeju Island during the ADS period was estimated to be about 2 x 10$^{8}$ molecules cm$^{-3}$ ( - 9 pptv). Decreases in NO$_3$levels during the ADS period was likely to be determined mainly by the enhancement of the $N_2$O$_{5}$ heterogeneous reaction on dust aerosol surfaces. The reaction of N20s on aerosol surfaces was a more important sink for nighttime N03 during the ADS due to the significant loading of dust particles. The reaction of $N_2$O$_{5}$ with NMHCs and the gas-phase reaction of N20s with water vapor were both significant loss mechanisms during the study period, especially during the NADS. However, dry deposition of these oxidized nitrogen species and a heterogeneous reaction of NO$_3$were of no importance. Short-term observations of $O_3$, NO$_2$, DMS, and SO$_2$in the MBL indicated that concentrations of most of these chemical species were different between the ADS and non - Asian - Dust-Storm (NADS) periods, implying that their levels were affected sensitively by the differences in air mass trajectories.

QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구 (Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD)

  • 송화선;구일섭;김인식
    • 품질경영학회지
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    • 제43권3호
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

자전거도로의 경사기준을 고려한 자전거도로 노선 선정 (The Bicycle Road Route Selection which Considers the Slope Standard of the Bicycle Road)

  • 백승헌;한동엽;진홍성
    • 한국측량학회지
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    • 제29권6호
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    • pp.553-559
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    • 2011
  • 자동차 보유대수 증가에 따른 고유가와 온실가스 배출로 자전거이용의 중요성이 대두되고 있지만, 자전거이용률은 현저하게 낮은 실정이다. 자전거이용 활성화를 위한 대책으로 전국자전거도로 사업이 진행되고 있으며 각 지방자치단체에서도 자전거도로 기본계획을 수립하여 진행되고 있다. 노선 선정에 대한 연구가 활발히 진행되고 있지만, 자료 처리에 대한 연구는 명확한 결과를 도출하기엔 부족한 실정이다. 자전거도로 설계 기준에 명시되어진 종단경사도 지형상황 등으로 인하여 부득이하다고 인정되는 경우에는 예외로 한다고 되어 있다. 본 연구에선 기존 자전거도로가 여수시의 지형상황을 고려하여 개설되어 졌는지, 종단경사 기준을 고려하여 연결 가능한 자전거도로 노선 선정을 제시했다. 추가요소로 차선 수, 도로 폭을 포함시켜 개설 가능한 자전거도로 중 적합한 자전거도로 노선이 산출되었다. 향후 산지가 많은 지역을 대상으로 자전거도로 선정 시 종단경사 기준의 활용 방안으로 이용될 것이다.

Quantum Hall Effect of CVD Graphene

  • Kim, Young-Soo;Park, Su-Beom;Bae, Su-Kang;Choi, Kyoung-Jun;Park, Myung-Jin;Son, Su-Yeon;Lee, Bo-Ra;Kim, Dong-Sung;Hong, Byung-Hee
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.454-454
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    • 2011
  • Graphene shows unusual electronic properties, such as carrier mobility as high as 10,000 $cm^2$/Vs at room temperature and quantum electronic transport, due to its electronic structure. Carrier mobility of graphene is ten times higher than that of Silicon device. On the one hand, quantum mechanical studies have continued on graphene. One of them is quantum Hall effect which is observed in graphene when high magnetic field is applied under low temperature. This is why two dimension electron gases can be formed on Graphene surface. Moreover, quantum Hall effect can be observed in room temperature under high magnetic field and shows fractional quantization values. Quantum Hall effect is important because quantized Hall resistances always have fundamental value of h/$e^2$ ~ 25,812 Ohm and it can confirm the quantum mechanical behaviors. The value of the quantized Hall resistance is extremely stable and reproducible. Therefore, it can be used for SI unit. We study to measure quantum Hall effect in CVD graphene. Graphene devices are made by using conventional E-beam lithography and RIE. We measure quantum Hall effect under high magnetic field at low temperature by using He4 gas closed loop cryostat.

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기능성 무기물과 폴리올레핀계 수지의 정량적 혼합시스템에 의한 환경대응형 포장소재 개발 (Environment Corresponding Package by Quantitative Mixing System with Functional Inorganic Material and Polyolefin Resin)

  • 김희삼;임현주;박영미
    • 한국염색가공학회지
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    • 제21권1호
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    • pp.1-9
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    • 2009
  • A lot of research has been made over the recent decade to develop testing packages with antimicrobial properties to improve food safety. In this study, a new method, experimental device and technology for environmental corresponding packages of polypropylene (PP) film has been developed to provide effective temperature buffering during the transport/long-term storage of grains or foodstuffs from the supplier to the market. This quantitatively optimized mixing system enabled to produce PP films with the 700$\sim$1,400d (width;1.5$\sim$3mm, thickness;0.01$\sim$0.5mm). In the whole mixing systems, the finely-granulated inorganic illite and PP virgin chip for master batch (M/B) chip was calculated by digital measurement methods, and then the M/B chip for PP film was adapted through a air jet and PP grinding method. The prepared PP film was characterized with tensile strength and elongation, far infrared radiation (FIR) emissivity, antimicrobial activity and deodorization properties. The results revealed that the two differently grain-sized illite could be show homogeneously dispersed on PP chip surface, and as the increasing of illite content, the FIR emissivity and the anion emission rate of film was increasingly improved. In both of 325 and 1,500 mesh-sized illite contained PP chip, of course the antimicrobial activity was good. But the ultimate deodorization rate for ammonia gas of PP film were found to be approximately the same.

디젤엔진의 $NO_X$ 저감을 위한 SCR $DeNO_X$ 촉매의 모델링 및 성능해석 (Modeling and Performance Analysis of SCR $DeNO_X$ Catalyst for Reducing $NO_X$ Emissions in Diesel Engine)

  • 김영득;김우승;이천환
    • 한국자동차공학회논문집
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    • 제17권1호
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    • pp.137-145
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    • 2009
  • The steady-state kinetics of the selective catalytic reduction (SCR) of $NO_X$ with $NH_3$ has been investigated over a commercial ${V_2}{O_5}/TiO_2$ catalyst. In order to account for the influence of transport effects the kinetics are coupled with a fully transient two-phase 1D+1D monolith channel model. The Langmuir-Hinshelwood (L-H) mechanism is adopted to describe the steady-state kinetic behavior of the ${V_2}{O_5}/TiO_2$ catalyst. The reaction rate expressions are based on previously reported papers and are modified to fit the experimental data. The steady-state chemical reaction scheme used in the present mathematical model has been validated extensively with experimental data of selective $NO_X$ reduction efficiency for a wide range of inlet conditions such as space velocity, oxygen concentrations, water concentration, and $NO_2/NO$ ratio. The parametric investigations are performed to examine how the $NH_3$ slip from a SCR $DeNO_X$ catalyst and the conversion of $NO_X$ are affected by the reaction temperature, $NH_3/NO_X$ feed ratio, and space velocity for feed gas compositions with $NO_2/NO_X$ ratios of 0 and 0.5.