• Title/Summary/Keyword: Gas Retention Time

Search Result 178, Processing Time 0.027 seconds

Thermophilic Sewage Sludge Digestion by Anaerobic Sequencing Batch Reactor (고온 협기성 연속회분식 공정에 의한 도시하수슬러지 소화)

  • 허준무;박종안;이종화;손부순;장봉기
    • Journal of environmental and Sanitary engineering
    • /
    • v.14 no.3
    • /
    • pp.130-138
    • /
    • 1999
  • The feasibility of municipal sewage sludge digestion was investigated by using thermophilic anaerobic sequencing batch reactor(ASBR). One-day settle time was enough for the high performance of solid-liquid separation. The conversion of semi-continuous mode to sequencing batch mode is easily achieved without any adverse effects, although the large amount of sludge equal to the volume ratio of 0.3~06 to reactor volume was added in the feed step of the start-up. The ASBRs had higher conversion capability of organics to biogas than the control reactor. Gas yields of the ASBRs were increased by the average of 50% over the control reactor across a range of hydraulic retention time(HRT)s from 10days to 5days. The thermophilic reactors showed higher gas production than mesophilic reactor. Removal efficiencies of organic matter exceeded 80% on the basis of supernatants, except that at the reactor. Solid-liquid separation was essential in the performance of the ASBR, especially, at the lower HFT. The ASBRs were highly efficient in the retention of activated biomass within the reactor. thus compensating for increased equivalent organic loading rate through increased solids retention times followed by the increased solids, while maintaining shorter HRTs.

  • PDF

Simultaneous Analysis of Stimulants and Narcotic Analgesics by Capillary Column Gas Chromatography with Nitrogen Phosphorus Detector (Capillary Column Gas Chromatography/Nitrogen Phosphorus Detector를 이용한 흥분제 및 마약성 진통제의 동시분석에 관한 연구)

  • Lho, Dong-Seok;Shin, Ho-Sang;Kang, Bo-Kyung;Paek, Heang-Kee;Kim, Seung-Ki;Lee, Jeong-Ae;Kim, Young-Lim;Park, Jong-Sei
    • Journal of the Korean Chemical Society
    • /
    • v.35 no.6
    • /
    • pp.659-666
    • /
    • 1991
  • A systematic analysis of 18 stimulants and narcotic analgesics containing nitrogen atom (s) in human urine by gas chromatography with nitrogen phosphorus detector (GC-NPD), is described. The urinary extract with diethyl ether at pH 8.5 showed good recoveries of the drugs and less interference peaks on GC chromatogram. Retention data were standardized by the calculation of relative retention times using diphenylamine as the internal standard. The relative standard deviations of retention times were less than 0.1% for the within-run analyses. The response factor (RRF) of a drug relative to the internal standard was calculated. RRF decreased with increasing number of nitrogen atoms. This technique can be adapted to various analytical toxicology problems.

  • PDF

Effect of Sulfide Removal on Sulfate Reduction at pH 5 in a Hydrogen Fed Gas-Lift Bioreactor

  • Bijmans, Martijn F.M.;Dopson, Mark;Ennin, Frederick;Lens, Piet N.L.;Buisman, Cees J.N.
    • Journal of Microbiology and Biotechnology
    • /
    • v.18 no.11
    • /
    • pp.1809-1818
    • /
    • 2008
  • Biotechnological treatment of sulfate- and metal-ions-containing acidic wastewaters from mining and metallurgical activities utilizes sulfate-reducing bacteria to produce sulfide that can subsequently precipitate metal ions. Reducing sulfate at a low pH has several advantages above neutrophilic sulfate reduction. This study describes the effect of sulfide removal on the reactor performance and microbial community in a high-rate sulfidogenic gas-lift bioreactor fed with hydrogen at a controlled internal pH of 5. Under sulfide removal conditions, 99% of the sulfate was converted at a hydraulic retention time of 24 h, reaching a volumetric activity as high as 51 mmol sulfate/l/d. Under nonsulfide removal conditions, <25% of the sulfate was converted at a hydraulic retention time of 24 h reaching volumetric activities of <13 mmol sulfate/l/d. The absence of sulfide removal at a hydraulic retention time of 24 h resulted in an average $H_2S$ concentration of 18.2 mM (584 mg S/I). The incomplete sulfate removal was probably due to sulfide inhibition. Molecular phylogenetic analysis identified 11 separate 16S rRNA bands under sulfide stripping conditions, whereas under nonsulfide removal conditions only 4 separate 16S rRNA bands were found. This shows that a less diverse population was found in the presence of a high sulfide concentration.

Effect of Hydraulic Retention Time (HRT) on the Hydrogen Production and Its Dynamic Characteristics in the Anaerobic Digestion Process Using Clostridium beijerinckii Donker 1926 (Clostridium beijerinckii Donker 1926을 이용한 혐기성 소화공정에서 체류시간 변화에 의한 수소 생산과 동력학적 특성)

  • Jeong, Tae-Young;Cha, Gi-Cheol;Choi, Suk Soon
    • Applied Chemistry for Engineering
    • /
    • v.18 no.2
    • /
    • pp.162-167
    • /
    • 2007
  • Hydrogen production and its dynamics were investigated in the continuous anaerobic digestion process using Clostridium beijerinckii Donker 1926. In this work, glucose was used as a substrate and hydraulic retention times (HRT) were 0.5, 0.25 or 0.125 day. The removal efficiency of carbohydrate was over 99% under all of HRT conditions. As HRT was shorter, COD removal efficiency became lower while hydrogen content in the total gas and hydrogen production rate became higher. The cell growth yield and hydrogen production yield were 0.27 g-VSS/g-glucose and 0.26 L/g-glucose, respectively, at the steady state. It is expected that the microorganism is able to produce hydrogen when used in the wastewater treatment containing carbohydrate such as glucose. Also, the results in this study could be applied to the actual hydrogen gas production, a promising alternative energy.

Seasonal Variation in Concentration and Composition of Monoterpenes from Artemisia princeps var. orientalis (쑥에 함유된 monoterpenes 의 함량과 조성의 계절적 변이)

  • Kim, Jong-Hee
    • The Korean Journal of Ecology
    • /
    • v.19 no.4
    • /
    • pp.321-328
    • /
    • 1996
  • The profile and concentration of monoterpene metabolites in the leaf and stem of Artemisia princeps var. orientalis were quantified, and seasonal variation in monoterpenes of Artemisia plant was investigated. Samples were taken from five sites at the campus of Kyungnam University during maturing season. Monoterpenes in leaf and stem were analyzed using gas chromatography-mass spectrometry (GC-MS). The major constituents of A. princeps var. orientalis in both the leaf and stem were 21 monoterpenes.$ {\alpha}-pinene,\;{\beta}-pinene,\;{\beta}-myrcene$, dl-limonene, naphthalene and unknown monoterpenes with 5.49 and 16.27 of retenstion time were present in high concentrations of compounds identified on the leaf and stem of A. princeps var. orientalis. The cmounts of total monoterpenes of leaf were from two to five times higher than stem and rapidly decreased with the time, while that of stem was constnat except early spring. Most of the high percentage of monoterpenes in the leaf were those with later retention time. These results indicated that monoterpenes yields are considered to be more variable than monoterpene composition in responding to the time in both the leaf and stem.

  • PDF

Anaerobic digestion and agricultural application of organic wastes

  • Suanu, Leh-Togi Zobeashia S.;Abiodun, Aransiola S.;Josiah, Ijah U.J.;Peter, Abioye O.
    • Advances in environmental research
    • /
    • v.7 no.2
    • /
    • pp.73-85
    • /
    • 2018
  • The anaerobically digestion and agricultural application of organic wastes was conducted using food wastes and cow dung. Twenty kilograms each of the feed stocks was added into two 30 liters-capacity batch digesters. The anaerobic digestion was carried out within a temperature range of $25-31^{\circ}C$ for a retention time of 51 days. The results showed a cumulative gas yield of 5.0 bars for food waste and no gas production for cow dung within the retention time. Bacteria such as Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Proteus vulgaris and Clostridium sp were isolated. Fungi isolated included Aspergillus niger, Aspergillus nidulan, Trichophyton rubrum and Epidermophyton flocossum. The non-dispersive infrared (NDIR) analysis of the biogas produced confirmed that the gas consisted of $CH_4$, $CO_2$ and $H_2$. Statistical analysis revealed there was no significant correlation between temperature and biogas produced from the organic wastes (r= 0.177, p = 0.483).The organic wastes from the biogas production process stimulated maize growth when compared to control (soil without organic waste) and indicated maximum height. The study therefore reveals that food waste as potential substrates for biogas production has a moderate bio-fertilizer potential for improving plant growth and yield when added to soil.

Analysis of n-Hexanal in Headspace Vapor over Cooked Brown Rice by Direct Vapor Injection Gas Chromatography (현미취반시 생성되는 n-hexanal의 가스크로마토그래피에 의한 분리및 정량)

  • Shin, Myung-Gon;Rhee, Joon-Shick;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
    • /
    • v.17 no.5
    • /
    • pp.406-408
    • /
    • 1985
  • n-Hexanal in headspace over the cooked brown rice stored at $5^{\circ}C$ and $35^{\circ}C$ for 0. 4, 8 and 12 months was determined by a modified direct vapor injection gas chromatographic method. The retention time of n-hexanal was 3.5 min and n-hexanal could be rapidly separated from other compounds at the operational conditions of gas chromatography. n-Hexanal contents of cooked brown rice also showed a standard deviation of less than 10% of the average.

  • PDF

Study on Image Retention in an AC Plasma Display Panel

  • Kim, Sang-Ho;Choi, Kyung-Cheol;Shin, Bhum-Jae
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2005.07a
    • /
    • pp.259-262
    • /
    • 2005
  • Image retention is a kind of fatal shortcoming of the AC PDPs for realizing high-quality picture. In this work, the measurement method of image retention was proposed using temporal measurement of luminance, CIEXYZ tristimulus values, IR emission of reset pulse, and temperaturel. On the base of temporal measurement of luminance, CIEXYZ tristimulus value, and IR emission of reset pulse, the retention time of Ne+5%Xe gas-mixture discharge was about 2 hours after white window image. However, it was about 20 minute on the base of temporal measurement of temperature.

  • PDF

Breeding of Fragrant Yellow Phalaenopsis and Scent Pattern Analysis by GC/SAW Electronic Nose System (유향성 황색계 호접란 육성 및 전자코를 이용한 향기패턴 분석)

  • Been, Chul-Gu
    • Horticultural Science & Technology
    • /
    • v.28 no.4
    • /
    • pp.656-663
    • /
    • 2010
  • In order to improve the consumer acceptance of fragrant yellow hybrids of $Phalaenopsis$ ($Phal.$), crosses between yellow hybrid varieties were made and the obtained hybrids were investigated for horticultural characteristics as well as difference in fragrance patterns. Cross combination of $Phal.$ Brother lawrence and $Phal.$ Brother saragold yielded good seedling population of 500 plants. Segregation was noticed in color density, spot and stripe patterns on yellow color base of petal and also in fragrance. Six lines with multi-branch on flower stalk and strong fragrance flower were finally selected. Volatile fragrance components were compared among $Phal.$ Brother lawrence, $Phal.$ Brother saragold and their hybrids by GC/SAW electronic nose. In the derivative pattern of chromatogram and polar derivative pattern of fragrance, similar dominant peaks appeared on retention time 7-9 s and some hybrid lines had two strong peaks on retention time 20-25 s, respectively. Also in polar frequency pattern of fragrance obtained by $VaporPrint^{TM}$ image analysis among parent flowers and hybrids, an identical strong peak near 8 s of retention time was shown. This single fragrance component is considered a key element of fragrance in $Phal.$ Brother lawrence, $Phal.$ Brother saragold and their hybrids. This peak could be used as a marker for the breeding of fragrance in $Phalaenopsis$.

Prediction of Gas Chromatographic Retention Times of PAH Using QSRR (기체크로마토그래피에서 QSRR을 통한 PAH 용리시간 예측)

  • Kim, Young Gu
    • Journal of the Korean Chemical Society
    • /
    • v.45 no.5
    • /
    • pp.422-428
    • /
    • 2001
  • Retention relative times(RRTs) of PAH molecules and their derivatives in gas chromatography are trained and predicted in testing sets using a multiple linear regression(MLR) and an artificial neural network(ANN). The main descriptors of PAHs and their derivatives in QSRR are the square root of molecular weight(sqmw), molecular connectivity($^1{\chi}_v$), molecular dipole moment(D) and length-to-breadth ratios(L/B). The results of MLR shows that a heavy molecule has a propensity for long retention time. L/B closely related with slot model is a good descriptor in MLR. On the other hand, ANN which is not effected by the linear dependencies among the descriptors were exclusively based on molecular weight and molecular dipole moment. The variances which shows the accuracy of prediction for retention times in testing sets are 1.860, 0.206 for MLR and ANN, respectively. It was shown that ANN can exceed the MLR in prediction accuracy.

  • PDF