• 제목/요약/키워드: Gas Resistance

검색결과 1,351건 처리시간 0.029초

전기화학적 노이즈 저항 측정에서의 불확도 평가 (Uncertainty evaluation in electrochemical noise resistance measurement)

  • 김종집;강수연
    • Corrosion Science and Technology
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    • 제12권5호
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    • pp.220-226
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    • 2013
  • The uncertainty in statistical noise resistance measurement was evaluated for a type 316 stainless steel in NaCl solutions at room temperature. Sensitivity coefficients were determined for measurands or variables such as NaCl concentration, pH, solution temperature, surface roughness, inert gas flow rate and bias potential amplitude. The coefficients were larger for the variables such as NaCl concentration, pH, inert gas flow rate and solution temperature, and they were the major factors increasing the combined standard uncertainty of noise resistance. However, the contribution to the uncertainty in noise resistance measurement from the above variables was remarkably low compared to that from repeated measurements of noise resistance, and thus, it is difficult to lower the uncertainty in noise resistance measurement significantly by lowering the uncertainties related with NaCl concentration, pH, inert gas flow rate and solution temperature. In addition, the uncertainty in noise resistance measurement was high amounting to 17.3 % of the mean, indicating that the reliability in measurement of noise resistance is low.

Butyl고무와 EPDM고무 블렌드의 경화특성, 물리적 성질 및 내오존성 (Cure Characteristics, Physical Properties and Ozone Resistance of Butyl Rubber and EPDM Rubber Blends)

  • 박찬영;황영배
    • Elastomers and Composites
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    • 제46권4호
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    • pp.329-334
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    • 2011
  • 일반적으로 butyl 고무(IIR : isobutylene isoprene rubber)는 우수한 내기체투과성 및 저반발 탄성체로서 우수한 충격흡수성을 갖는다. 본 실험에서는 butyl고무에 EPDM(ethylene propylene diene monomer)을 기계적 혼련법으로 blend 혼련물을 제조하여 이들의 가교 거동, 물리적 성질 및 내오존성 등을 측정하였다. EPDM 고무량이 증가할수록 최적 가황시간이 단축되는 경향을 보였다. 기체투과속도 테스트에 의한 내기체투과성 측정 결과 butyl고무량이 50 wt% 이상일 경우에는 기체투과도가 현저히 감소하였다. 한편 butyl rubber/EPDM 블렌드의 경우에 EPDM의 함량이 25 wt.% 이상 함유될 경우 내오존성이 향상되어 50 pphm, $50^{\circ}C$, 120시간 조건에서도 아무런 표면변화가 없었다.

아미노산을 이용한 망간 산화물 기공성 나노 구조의 합성 및 C3H8 가스에 대한 선택적 감응 특성 (Preparation of Manganese Oxide Porous Nanostructures using Amino-acid and its Selective C3H8 Sensing Properties)

  • 최권일;이종흔
    • 센서학회지
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    • 제20권1호
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    • pp.64-69
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    • 2011
  • Porous manganese oxide porous nanostructures were prepared by amino-acid-mediated solvothermal self assembly reaction and subsequent heat treatment at $600^{\circ}C$. When Mn-precursors were heat-treated at $400-550^{\circ}C$, the sensors did not show significant gas responses. In contrast, the manganese oxide heat-treated at $600^{\circ}C$ showed the significant gas responses, that is, the resistance decrease to 100 ppm $C_3H_8$ ($R_a/R_g$ = 2.17, $R_a$ : resistance in air, $R_g$ : resistance in gas) and the resistance increase to 100 ppm $C_2H_5OH$ ($R_g/R_a$ = 1.92). The opposite change of resistance upon exposure to $C_3H_8$ and $C_2H_5OH$ was discussed in relation to the mixed phases of manganese oxides with different valences.

관엽식물의 오존($O_3$)흡수능에 관여하는 요인 분석 (Analysis of Factors Rerated to Absorption Ability of Foliage Plants Exposed to $O_3$)

  • 박소홍;배공영
    • 한국대기환경학회지
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    • 제14권6호
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    • pp.537-544
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    • 1998
  • We selected Spathiyhyllum patinii and Pachira aqkatica, since the former has high O3 absorption while the latter low absorption, and analyzed physiological factors such as diffusive coefficient, transpiration rate, photosynthetic rate, and CO2 absorption rate, which affected O3 absorption capacity There was significant relationship between gas absorption capacity and the other factors; photosynthetic rate, diffusive resistance, stomatal resistance and CO2 absorption rate. Therefore model formula for estimation of O3 absorption rate in plant was formulated by making use of these factors. There was difference for the estimation of O3 absorption rate according to plant species. In case of Spathiphyllum patinii, photosynthetic rate is an optimal factor for estimation of O3 absorption capacity. On the other hand, stomatal resistance and diffusive resistance are optimal factors of Pachira aquatica among various physiological ones. And we knew that CO2 absorption rate is a potential factor to evaluate gas absorption capacity regardless of plant species. But considering efficiency and practicality, diffusive resistance was the most effective factor for the estimation of O3 gas absorption.

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Numerical simulation of resistance performance according to surface roughness in container ships

  • Seok, Jun;Park, Jong-Chun
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제12권1호
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    • pp.11-19
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    • 2020
  • In recent years, oil prices have continued to be low owing to the development of unconventional resources such as shale gas, coalbed methane gas, and tight gas. However, shipping companies are still experiencing difficulties because of recession in the shipping market. Hence, they devote considerable effort toward reducing operating costs. One of the important parameters for reducing operating costs is the frictional resistance of vessels. Generally, a vessel is covered with paint for smoothing its surface. However, frictional resistance increases with time owing to surface roughness, such as that caused by fouling. To prevent this, shipping companies periodically clean or repaint the surfaces of vessels using analyzed operating data. In addition, studies using various methods have been continuously carried out to identify this phenomenon such as fouling for managing ships more efficiently. In this study, numerical simulation was used to analyze the change in the resistance performance of a ship owing to an increase in surface roughness using commercial software, i.e., Star-CCM+, which solves the continuity and Navier eStokes equations for incompressible and viscous flow. The conditions for numerical simulation were verified through comparison with experiments, and these conditions were applied to three ships to evaluate resistance performance according to surface roughness.

질소 보호 가스 첨가가 하이퍼 듀플렉스 스테인리스 밀봉용접재의 마모부식 저항성에 미치는 영향 (Influence of the nitrogen gas addition in the Ar shielding gas on the erosion-corrosion of tube-to-tube sheet welds of hyper duplex stainless steel)

  • 김혜진;전순혁;김순태;이인성;박용수
    • Corrosion Science and Technology
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    • 제13권2호
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    • pp.70-80
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    • 2014
  • Duplex stainless steels with nearly equal fraction of the ferrite(${\alpha}$) phase and austenite(${\gamma}$) phase have been increasingly used for various applications such as power plants, desalination facilities due to their high resistance to corrosion, good weldability, and excellent mechanical properties. Hyper duplex stainless steel (HDSS) is defined as the future duplex stainless steel with a pitting resistance equivalent (PRE=wt.%Cr+3.3(wt.%Mo+0.5wt.%W)+30wt.%N) of above 50. However, when HDSS is welded with gas tungsten arc (GTA), incorporation of nitrogen in the Ar shielding gas are very important because the volume fraction of ${\alpha}$-phase and ${\gamma}$-phase is changed and harmful secondary phases can be formed in the welded zone. In other words, the balance of corrosion resistance between two phases and reduction of $Cr_2N$ are the key points of this study. The primary results of this study are as follows. The addition of $N_2$ to the Ar shielding gas provides phase balance under weld-cooling conditions and increases the transformation temperature of the ${\alpha}$-phase to ${\gamma}$-phase, increasing the fraction of ${\gamma}$-phase as well as decreasing the precipitation of $Cr_2N$. In the anodic polarization test, the addition of nitrogen gas in the Ar shielding gas improved values of the electrochemical parameters, compared to the Pure Ar. Also, in the erosion-corrosion test, the HDSS welded with shielding gas containing $N_2$ decreased the weight loss, compared to HDSS welded with the Ar pure gas. This result showed the resistance of erosion-corrosion was increased due to increasing the fraction of ${\gamma}$-phase and the stability of passive film according to the addition $N_2$ gas to the Ar shielding gas. As a result, the addition of nitrogen gas to the shielding gas improved the resistance of erosion-corrosion.

연소조건 변화에 따른 LP가스버너의 배기특성 (Emission Characteristics of LP Gas Burner for the Variation of Combustion Conditions)

  • 이병곤;오택흠
    • 한국안전학회지
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    • 제16권4호
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    • pp.1-6
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    • 2001
  • An experimental study was carried out to investigate the emission characteristics of LP gas burner for the Practical combustion conditions including fm voltage, inlet area, gas Pressure, emission resistance, duct length and height. The result shows that CO is almost remains constant for the emission fan voltage, but significantly increases with the reduction rate of air inlet, up to 3000ppm at 50% of reduction rate. Also, the variation of gas pressure has no effect to CO of gas boiler due to its governor which controls gas pressure secondly, but it gives an rapid increase of CO for the gas range. The emission resistance test shows that CO is suddenly increased with the reduction rate of emission duct above 70% and main burner is stopped at 90%. The reverse wind test shows that CO is suddenly increased with the air velocity above 7m/s and main burner is stopped at 9m/s. The more horizontal length of emission duct is long and the vertical height is low, CO is infinitesimally increased.

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운전조건이 PEM 수전해 셀의 성능에 미치는 영향 (Influence of Operation Conditions on the Performance of PEM Water Electrolysis)

  • 장상엽;김재동;박진모;소영석
    • 한국가스학회지
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    • 제28권1호
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    • pp.65-72
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    • 2024
  • 재생에너지 자원이 풍부한 제주도에서 수전해 시스템을 활용하여 그린수소를 생산하는 실증단지를 준비 중이며, 수전해 시스템의 장기 운영시 상황을 검토하기 위하여, PEM 수전해 셀을 가속시험평가 하여 수전해 셀의 내구성을 검토하였고, 제주도 풍력기반의 전력패턴을 적용하였을 때 수전해 셀의 내구성을 검토하였다. 가속시험평가 (저전류-고전류 반복 인가)를 800시간 진행한 후, PEM 수전해 셀의 성능이 최대 10%, 운전조건에서 5.5% 감소되었으며, 임피던스 분석결과 PEM 수전해 셀의 Ohmic 저항보다 전극의 분극저항이 크게 증가한 것을 확인할 수 있다. 그리고 제주도의 풍력패턴을 적용하여 내구성평가를 진행한 경우, PEM 수전해 셀의 성능이 최대 1.6%, 운전 조건에서 1% 미만의 성능감소를 보여주었으며, 임피던스 결과 Ohmic 저항 및 전극의 분극저항의 변화가 작은 것을 알 수 있다.

고내식성의 신 마그네슘 코팅막 제작 (Preparation of New Corrosive Resistive Magnesium Coating Films)

  • 이명훈
    • Journal of Advanced Marine Engineering and Technology
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    • 제20권5호
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    • pp.103-113
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    • 1996
  • The properties of the deposited film depend on the deposition condition and these, in turn depend critically on the morphology and crystal orientation of the films. Therefore, it is important to clarify the nucleation occurrence and growth stage of the morphology and orientation of the film affected by deposition parameters, e.g. the gas pressure and bias voltage etc. In this work, magnesium thin flims were prepared on cold-rolled steel substrates by a thermo-eletron activation ion plating technique. The influence of nitrogen gas pressure and substrate bias voltage on their crystal orientation and morphology of the coated films were investigated by scanning electron microscopy (SEM) and X-ray diffraction, respectively. The diffraction peaks of magnesium film became less sharp and broadened with the increase of nitrogen gas pressure. With an increase in nitrogen gas pressure, flim morphology changed from colum nar to granular structure, and surface crystal grain-size decreased. The morphology of films depended not only on gas pressure but also on bias voltage, i.e., the effect of increasing bias voltage was similar to that of decreasing gas pressure. The effect of crystal orientation and morphology of magnesium films on corrosion behaviors was estimated by measuring anodic polarization curves in deaerated 3%NaCl solution. Magnesium, in general, has not a good corrosion resistance in all environments. However, these magnesium films prepared by changing nitrogen gas pressure showed good corrosion resistance. Among the films, magnesium films which exhibited granular structure had the highest corrosion resistance. The above phenomena can be explained by applying the effects of adsorption, occlusion and ion sputter of nitrogen gas.

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가스질화처리 적용을 통한 스마트무인기 머레이징강 로터허브 부품 품질개선 (Quality Improvement of Smart UAV Rotor-Hub Part Through Gas Nitriding of Maraging Steel)

  • 이명규;최성욱;김재무
    • 항공우주시스템공학회지
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    • 제8권2호
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    • pp.33-39
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    • 2014
  • Feathering spindle is one of the critical parts of the rotor system in the Smart Unmanned Aerial Vehicle(SUAV) that it was manufactured with special material, Maraging C300. During the initial ground and tie-down flight tests of the SUAV, surface of the feathering spindle contacting to the needle-roller bearings showed excessive wear and dent due to high vibrating loads transferred from the rotating blades. Gas nitriding process was applied to the bearing contact surface of the feathering spindle to increase surface hardness so as to improve the surface defects. This paper briefly presents the gas nitriding process adopted and the spindle quality improvements including wear and corrosion resistance.