• Title/Summary/Keyword: Gas Density

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Growth of Thin Film Using Chemical Bath Deposition Method and Their Photoconductive Characteristics (CBD 방법에 의한 CdS 박막의 성장과 광전도 특성)

  • Hong, K.J.;Lee, S.Y.;You, S.H.;Suh, S.S.;Moon, J.D.;Shin, Y.J.;Jeoung, T.S.;Shin, H.K.;Kim, T.S.;Song, J.H.;Rheu, K.S.
    • Journal of Sensor Science and Technology
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    • v.2 no.1
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    • pp.3-10
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    • 1993
  • Polycrystalline CdS thin films were grown on ceramic substrate using a chemical bath deposition method. They were annealed at various temperature and X-ray diffraction patterns were measured by X-ray diffractometer in order to study CdS polycrystal structure. Using extrapolation method of X-ray diffraction patterns for the CdS samples annealed in $N_{2}$ gas at $550^{\circ}C$ it was found hexagonal structure whose lattice constants $a_{o}$ and $c_{o}$ were $4.1364{\AA}$ and $6.7129{\AA}$, respectively. Its grain size was about $0.35{\mu}m$. Hall effect on this sample was measured by Van der Pauw method and studied on carrier density and mobility defending on temperature. From Hall data, the mobility was likely to be decreased by piezo electric scattering at temperature range of 33K and 150k and by polar optical scattering at temperature range of 150K and 293K. We measured also spectral response, sensitivity (${\gamma}$), maximum allowable power dissipation and response time on these samples.

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Characterization of CdSe Thin Film Using Chemical Bath Deposition Method (Chemical Bath Deposition 방법으로 제작한 CdSe 박막의 특성)

  • Hong, K.J.;Lee, S.Y.;You, S.H.;Suh, S.S.;Moon, J.D.;Shin, Y.J.;Jeong, T.S.;Shin, H.K.;Kim, T.S.;Song, J.H.;Rheu, K.S.
    • Journal of Sensor Science and Technology
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    • v.2 no.1
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    • pp.81-86
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    • 1993
  • Polycrystalline CdSe thin films were grown on ceramic substrate using a chemical bath deposition (CBD) method. They were annealed at various temperature and X-ray diffraction patterns were measured by X-ray diffractometer in order to study CdSe polycrystal structure. Using extrapolation method of X-ray diffraction patterns for the CdSe samples annealed in $N_{2}$ gas at $450^{\circ}C$ it was found hexagonal structure whose lattice parameters $a_{o}$ and $c_{o}$ were $4.302{\AA}$ and $7.014{\AA}$, respectively. Its grain size was about $0.3{\mu}m$. Hall effect on this sample was measured by Van der Pauw method and studied on carrier density and mobility depending on temperature. From Hall data, the mobility was likely to be decreased by piezo electric scattering at temperature range of 33 K and 200 K, and by polar optical scattering at temperature range of 200 K and 293 K. We measured also spectral response, sensitivity (${\gamma}$), maximum allowable power dissipation and response time on these samples.

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A Fuel Cell Generation Modeling and Interconnected Signal Analysis using PSCAD/EMTDC (연료전지 발전시스템의 PSCAD/EMTDC 모델링 및 계통연계에 따른 전력신호 분석에 관한 연구)

  • Choi, Sang-Yule;Park, Jee-Woong;Lee, Jong-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.5
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    • pp.21-30
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    • 2008
  • The fuel cell generation convert fuel source, and gas directly to electricity in an electro-chemical process. Unlike traditional and conventional turbine engines, the process of fuel cell generation do not burn the fuel and run pistons or shafts, and it has not revolutionary machine, so have fewer efficiency losses, low emissions and no noisy moving parts. A high power density allows fuel cells to be relatively compact source of electric power, beneficial in application with space constraints. In this system, the fuel cell itself is nearly small-sized by other components of the system such as the fuel reformer and power inverter. So, the fuel cell energy's stationary fuel cells produce reliable electrical power for commercial and industrial companies as well as utilities. In this paper, a fuel cell system has been modeled using PSCAD/EMTDC to analyze its electric signals and characteristics. Also the power quality of the fuel cell system has been evaluated and the problems which can be occurred during its operation have been studied by modeling it more detailed. Particularly, we have placed great importance on its power quality and signal characteristics when it is connected with a power grid.

First-time estimation of HCHO column in major cities over Asia using multiple regression with satellite data (위성자료와 다중회귀분석법을 이용한 아시아 주요도시의 포름알데하이드 칼럼농도 추정연구)

  • Choi, Wonei;Hong, Hyunkee;Park, Junsung;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.31 no.6
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    • pp.523-530
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    • 2015
  • A Multiple Regression Method (MRM) is used for the first time with Ozone Monitoring Instrument (OMI) and Moderate Resolution Imaging Spectroradiometer (MODIS) data to estimate formaldehyde (HCHO) Vertical Column Density (VCD). For a 3.5-year period from January 2005 through July 2008, HCHO VCD estimation is investigated in cities over Asia in two categorized areas: (1) Major cities in Northeast Asia (Beijing, Seoul, and Tokyo), (2) Major cities in Southeast Asia (New Delhi, Dhaka, and Bangkok). In the Major cities in Northeast Asia, there are good agreements between HCHO estimated by the multiple linear regression method ($HCHO_{MRM}$) and HCHO measured by OMI ($HCHO_{OMI}$) (0.78 < $R^2$ < 0.82). However, in Major cities in Southeast Asia, there were poor agreements between $HCHO_{OMI}$ and $HCHO_{MRM}$ (0.24 < $R^2$ < 0.39). In addition, an unbiased assessment of the MRM performance using modeling and validation groups shows that the performance of the MRM based on separate modeling and validation groups is comparable to that using all the data for deriving Multiple Regression Equations (MREs). This study demonstrates that MRM can be an alternative tool for HCHO estimation in certain areas over Asia.

Fabrication of Electroconductive $Si_3N_4$-TiN Ceramic Composites by In-Situ Reaction Sintering (In-Situ 반응소결에 의한 전도성 $Si_3N_4$-TiN 복합세라믹스 제조)

  • Lee, Byeong-Taek;Yun, Yeo-Ju;Park, Dong-Su;Kim, Hae-Du
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.577-582
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    • 1999
  • In order to make the electroconductive $Si_3N_4$-TiN composities, the Si-Ti(N) compacts were nitrided at $1450^{\circ}C$ for 20hours, and then they were post-sintered by a gas-pressure-sintering technique at 1TEX>$1950^{\circ}C$ for 3.5 hours. As starting powders, commercial si powder of about $10\mu\textrm{m}$, two types of Ti powders of 100 and 325 mesh, and fine-sized TiN of $2.5\mu\textrm{m}$ powders were used. In the $Si_3N_4$-TiN sintered bodies used Ti powders, the relative density and fracture strength and electrical conductivity are low due to the existence of large amounts of coarse pores. However, in the $Si_3N_4$-TiN composite used TiN powder, the fracture toughness, fracture strength and electrical resistivity were $5.0MPa{\cdot}m^{1/2}$, 624MPa and $1400{\omega}cm$, respectively. The dispersion of TiN particles in the composite inhibited the growth of $Si_3N_4$ in the shape of rod and made strong strain field contrasts at the $Si_3N_4$-TiNinterfaces. It was recognized that microstructural control is required to improve the electrical conductivity and mechanical properties of $Si_3N_4$-TiN composites by dispersing TiN particles homogeneously.

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Diagnosis of the Liquid Transportation Pipe in the Petroleum Industry using Sealed Gamma-ray Source(137Cs) (밀봉감마선원(137Cs)을 이용한 석유화학산업의 유체이송배관 내 가동 중 이상 진단기술)

  • Kim, Jin-Seop;Jung, Sung-Hee;Kim, Jong-Bum
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.794-799
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    • 2005
  • With the quantitative growth of the petroleum industry, the pipe facilities that connect each process increased significantly and the corresponding maintenance and repair costs of the pipe facilities increased as well. The diagnosis techniques to check a pipe efficiency while in operation are few in Korea, but in the advanced countries the pipe diagnosis using gramma-ray source was on-going research since 1960's. In this study, field experiments were performed to analyze the reasons for abnormal operation of the pipe connected to a distillation tower, and the degree of abnormality was estimated using a sealed gamma-ray source ($^{137}Cs$). Gamma radiation counts were measured by a detector (NaI) positioned outside the pipe-wall diametrically opposite to the gamma source. The results showed that a gas zone section's distribution pattern was different from the pattern of nearby fluid in a pipe. Th diagnosis technique using a gamma radiation source was proved to be an effective and reliable method, offering the information on the fluid distribution in pipe.

Effect of Active Master Packaging System on Preservation of Fresh Shiitake Mushrooms in Supply Chain (유통과정에서 생표고버섯에 대한 Active 마스터 포장 시스템의 적용 효과)

  • An, Duck Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.3
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    • pp.402-408
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    • 2016
  • Master packaging system consists of an inner individual package and secondary outer package. During the stages of chilled transport and distribution, the combination of primary individual package and secondary package was used to maintain a modified atmosphere for shiitake mushrooms. During the retail stage at higher temperature ($25^{\circ}C$), the primary individual package was exposed to display conditions after dismantling of the secondary packaging. The master packaging system was constructed to contain eight individual $30-{\mu}m$ thick polypropylene film bags of 500 g shiitake mushrooms inside a $40-{\mu}m$ low-density polyethylene bag. Carbon dioxide absorbent material [$Ca(OH)_2$] and/or moisture absorbent (superabsorbent polymer) were designed in their required amounts based on respiration characteristics and then applied to the outer secondary packaging in sachet form. Gas concentration of the packaging, temperature, and humidity were monitored throughout transport and storage. The quality of shiitake mushrooms was measured at the retail stage to determine the packaging effect. During the distribution stage of 108 h, $O_2$ and $CO_2$ concentrations in the master packaging system were maintained at 9~11% and 1~4% in the inner packaging, respectively, which are good for quality preservation. Compared to the control, the master packaging with $CO_2$ and/or moisture absorbents improved mushroom preservation and particularly reduced decay.

Thermal Insulation and Flame Retardant Properties of Cement Based Super Light-weight Inorganic Thermal Insulation using 100㎛ Grade Glass Bubble (100㎛급 글라스 버블 혼입 시멘트계 초경량 무기 단열재의 단열 및 난연특성)

  • Son, Bae-Geun;Song, Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.642-649
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    • 2021
  • Energy saving standard for buildings are strengthened, the application of exterior insulation finishing system and thickness of insulation materials are increasing. Most buildings with exterior insulation finishing system is applied organic insulating material. Organic insulating material have workability, economic feasibility, reduction in construction cost, and excellent thermal insulation performance. However, Organic insulating material is very vulnerable to heat, so when a fire occurs, rapid fire spread and toxic gas are generated, causing many casualties. Inorganic insulating material can be non-combustible performance, but it is heavy and has low thermal insulation performance. Mineral wool has higher thermal insulation performance than other types of inorganic insulating material, but mineral wool is disadvantageous to workability and vulnerable to moisture. Glass bubble are highly resistant to water and chemically stable substances. In addition, the density of the glass bubble is very low and the particles are spherical, fluidity is improved by the ball bearing effect. Glass bubbles can be used with cement-based ino rganic insulating material to impro ve the weight and thermal insulatio n perfo rmance o f cement-based inorganic insulation. This study produced a inorganic insulating materials were manufactured using cement-based materials and glass bubble. In order to evaluate the insulation performance and flame retardant performance of cement-based super light-weight inorganic insulating materials using with glass bubble, insulation performance or flame retardant and non-combustible performance were evaluated after manufacturing insulating materials using micro cement and two types of glass bubbles. From the test result, Increasing the mixing ratio of glass bubbles improved the insulation performance of cement-based super light-weight inorganic insulating materials, and when the mixing ratio of glass bubbles was 10%, it sho wed sufficient flame retardant and no n-co mbustible perfo rmance.

Effect of O2/Ar+O2 concentration on phase stability of transparent Mn doped SnO2 monolayer film (혼합기체 O2/Ar+O2 농도 변화가 Mn 도핑된 SnO2 투명전도막의 상 안정성에 미치는 영향)

  • Kim, Taekeun;Jang, Guneik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.4
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    • pp.154-158
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    • 2021
  • The optical transmittance of Mn-doped SnO2 monolayer film increased gradually from 80.9 to 85.4 % at 550 nm wavelengths upon increasing the O2/Ar+O2 concentration rate from 0 to 7.9 % and the band gap energy changed from 3.0 to 3.6 eV. The resistivity tended to decrease from 3.21 Ω·cm to 0.03 Ω·cm, reaching a minimum at 2.7 %, and then gradually increased from 0.03 to 52.0 Ω·cm at higher O2/Ar+O2 gas concentration ratio. Based on XPS spectra analysis, the Sn 3d5/2 peak of Mn-doped SnO2 single layer shifted slightly from 486.40 to 486.58 and O1s peak also shifted from 530.20 to 530.33 eV with increase the O2/Ar+O2 concentration ratio. Therefore, the XPS spectra results indicate that a multiphase with SnO and SnO2 coexisted in the sputtered Mn-doped SnO2 monolayer film.

Anthracite Oxygen Combustion Simulation in 0.1MWth Circulating Fluidized Bed (0.1 MWth 급 순환유동층에서의 무연탄 연소 전산유체역학 모사)

  • Go, Eun Sol;Kook, Jin Woo;Seo, Kwang Won;Seo, Su Been;Kim, Hyung Woo;Kang, Seo Yeong;Lee, See Hoon
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.417-428
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    • 2021
  • The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MWth Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MWth Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m3. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO2 concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.