• Title/Summary/Keyword: Gas Corrosion

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CORROSION OF STEEL GAS PIPELINE INDUCED BY SULFATE-REDUCING BACTERIA IN ANAEROBIC SOIL (혐기성 토양에 서식하는 황산염환원세균에 의한 가스배관의 미생물부식)

  • Li SeonYeob;Jeon KyungSoo;Kho YoungTai;Kang Tak
    • 한국가스학회:학술대회논문집
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    • 2001.10a
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    • pp.58-68
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    • 2001
  • Microbiologically influenced corrosion (MIC) of carbon steel gas pipeline in soil environments was investigated at field and laboratory MIC is very severe corrosion and it is not easy to distinguish this corrosion from Inorganic corrosion because of its localized, pitting-type character Therefore, it is important to provide proper assessment techniques for the prediction, detection, monitoring and mitigation of MIC. It is possible to predict the MIC risk, i.e., the activity of sulfate-reducing bacteria (SRB) through the analysis of soil environments. Chemical, microbiological and surface analysis of corrosion products and metal attacked could reveal the possibility of the occurrence of MIC. Various electrochemical and surface analysis techniques could be used for the study of MIC. Among these techniques, thin-film electrical resistance (ER) type sensors are promising to obtain localized corrosion rate of MIC induced by SRB. It is also important to study the effect of cathodic protection (CP) on the MIC In case of coated pipeline, the relationship between coating disbondment and the activity of SRB beneath the disbanded coating is also important.

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The Study on the Corrosion Behavior of STS 304 for Gas Boiler in the Condensed Water (응축수 중에서 가스보일러용 STS 304의 부식거동에 관한 연구)

  • Du Yun Byoung;Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.9 no.1 s.26
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    • pp.21-25
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    • 2005
  • This paper was studied on the corrosion behavior of STS 304 for gas boiler in the condensed water, the electrochemical polarization test of STS 304 for gas boiler in the condensed water was carried out. And the corrosion behavior of STS 304 was considered. The main results are as following: 1) As corrosion environment is acidified from neutrality, the polarization resistance of STS 304 decreases and the corrosion potential is less noble. 2) The corrosion reaction mechanism of STS 304 is cathodic control. 3) As corrosion environment is acidified, the passive potential range of STS 304 decreases. Also, the passive current density of STS 304 increases.

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A Study on Stress Corrosion Behaviors in Welded Zone of the API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG YOO-SIK;KIM YUONG-DAI
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.401-407
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    • 2004
  • This study is on the constant-current stress corrosion test related to the load stress in welded zone and non-welded zone of high tensile strength steel for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed global corrosion and narrow pitting, and the pitting was increased by increasing the load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel for natural gas transmission specimens was decreased suddenly, and the average relative electrode potential was higher and the average relative current was lower in welded zone than base metal. and the average relative electrode potential was decreased by increasing the load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone than base metal, and the corrosion rate was decreased by increasing the load stress.

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Evaluation of Hydrogen Sulfide Corrosion Inhibitors for Wet Gas Pipeline Steel

  • Huy, Vu Dinh;Thoa, Nguyen Thi Phuong;Phong, Tran Quoc;Hoang, Nguyen Thai
    • Corrosion Science and Technology
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    • v.4 no.3
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    • pp.95-99
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    • 2005
  • Wheel test and potentiodynamic polarization methods were used to evaluate the relative effectiveness of some hydrogen sulfide corrosion inhibitors for the wet gas pipeline API 5L grade X 65 steel. Five commercially corrosion inhibitors have been studied in the deoxygenated produced water solutions containing 10 ppm and 100 ppm of hydrogen sulfide. Based on the experiment results the steel corrosion inhibition mechanism in discussed and two most effective corrosion inhibitors are selected.

A Study on the Corrosivity according to Soil Characteristics and Electrolytic Protection for the Materials of Fuel Gas Pipe (토양 특성 및 전기방식에 따른 연료 가스용 강관의 부식 차이에 관한 연구)

  • Yim, Sang-Sik;Kim, Ji-sun;Ryu, Young-don;Lee, Jin-Han
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.16-22
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    • 2016
  • Coating pipe(PLP) has been generally used in buried site for protecting the corrosion. To prevent the damage by occurring the defect, other construction or execution works, an anti-oxidation environment was forcibly made by using protective potential. Coating and protective potential are applied simultaneously, but corrosion rate or defects are not easy to observe because soil composition has many uncertainty. Also, defect of coating pipe can not be directly observed. A corrosion coupon can easily measure a corrosion rate directly. The corrosion rate was measured with 6 scenarios using corrosion coupon during about 1 year(6 scenarios are based on soil type and protective potential or not in this research. Resultingly, the corrosion coupon has not occurred in the case of protected by potential current, but corrosion has occurred in a non-protected site. The corrosion rate was measured at least in the clay, and the propensity of corrosion rate was similar in other soil(sand and loams). The local corrosion has occurred in the clay because of high water content. On the other hand, general corrosion was occurred in sand and loams. Commonly, sand is not to corrosive soil. Although, corrosion occurred in sand can be estimated by chemical component and valid with chemical analysis report.

An Assesment of the Gas Pipeline Reliability Using Corrosion based Composite Failure (부식기반 복합고장을 고려한 가스배관의 신뢰도 평가)

  • Kim, Seong-Jun;Kim, Dohyun;Kim, Woosik;Kim, Young-Pyo;Kim, Cheolman
    • Journal of Korean Society for Quality Management
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    • v.47 no.4
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    • pp.739-754
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    • 2019
  • Purpose: The purpose of this paper is to develop a reliability estimation procedure for the underground gas pipeline in the presence of corrosion defects. Methods: Corrosion is one of the major causes of the gas pipeline failure. Several failure forms caused by corrosion have been studied. Among them, small leak and burst are considered in this paper. The composite failure of the two is defined by limit state function, and it is expressed with pipe parameters. Given a modified corrosion dataset, in order to obtain reliability estimations, the method of first order and second moment is adopted because of its simplicity. The computation processes are conducted with MATLAB coding. Results: According to numerical results, the probability of composite failure is affected by both small leak and burst. In particular, when corrosion depth stays at low level, it is consistent with the probability of burst failure. On the contrary, it is more influenced by the small leak failure as corrosion depth is increasing. In such case, the probability of composite failure is fast approaching to the safety limit. Conclusion: By considering the composite failure, more practical predictions of remaining life can be obtained. The proposed method is useful for maintenance planning of the underground gas pipeline.

Study on the Cavitation Damage of Cupronickel(70/30) Tube for Gas Absorption Refrigeration Machine

  • Lim, Uh-Joh;Jeong, Ki-Cheol;Yun, Byoung-Du
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.2
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    • pp.332-337
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    • 2004
  • The use of gas absorption refrigeration machine has considerably increased because of the shortage of the electric power in the summer and the regulation of freon refrigerant. Gas absorption refrigeration machine consists of a condenser, a heat exchanger. supplying pipes, a radiator etc, This system is likely to be corroded by acid. dissolved oxygen and gases, Cavitation erosion-corrosion by flow velocity of cooling water may happen in absorption refrigeration machine. In these cases. erosion and corrosion occur simultaneously. Then, it makes a serious damage with synergy effect. Therefore, this paper was studied on the cavitation damage of cupronickel(70/30) tube for gas absorption refrigeration machine, In the $30^{\circ}C$ tap water, linear polarization test and anodic polarization test were carried out for copper(C1220T-OL) and cupronickel(70/30) tube. Also, cavitation erosion-corrosion behavior of cupronickel (70/30) tube was considered, The main results are as following: (1) In the linear test, the corrosion current density of cupronickel(70/30) is higher than that of copper. (2) The erosion-corrosion rate of cupronickel(70/30) displayed later tendency than that of copper by vibratory cavitation in cooling water. (3) In cooling water, the progress mechanism of erosion-corrosion rate of copper and cupronickel(70/30) follows a pattern of incubation, acceleration, attenuation and a steady state period.

A Fuzzy Inference based Reliability Method for Underground Gas Pipelines in the Presence of Corrosion Defects

  • Kim, Seong-Jun;Choe, Byung Hak;Kim, Woosik;Ki, Ikjoong
    • Journal of the Korean Institute of Intelligent Systems
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    • v.26 no.5
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    • pp.343-350
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    • 2016
  • Remaining lifetime prediction of the underground gas pipeline plays a key role in maintenance planning and public safety. One of main causes in the pipeline failure is metal corrosion. This paper deals with estimating the pipeline reliability in the presence of corrosion defects. Because a pipeline has uncertainty and variability in its operation, probabilistic approximation approaches such as first order second moment (FOSM), first order reliability method (FORM), second order reliability method (SORM), and Monte Carlo simulation (MCS) are widely employed for pipeline reliability predictions. This paper presents a fuzzy inference based reliability method (FIRM). Compared with existing methods, a distinction of our method is to incorporate a fuzzy inference into quantifying degrees of variability in corrosion defects. As metal corrosion depends on the service environment, this feature makes it easier to obtain practical predictions. Numerical experiments are conducted by using a field dataset. The result indicates that the proposed method works well and, in particular, it provides more advisory estimations of the remaining lifetime of the gas pipeline.

Influence of the nitrogen gas addition in the Ar shielding gas on the erosion-corrosion of tube-to-tube sheet welds of hyper duplex stainless steel (질소 보호 가스 첨가가 하이퍼 듀플렉스 스테인리스 밀봉용접재의 마모부식 저항성에 미치는 영향)

  • Kim, Hye-Jin;Jeon, Soon-Hyeok;Kim, Soon-Tae;Lee, In-Sung;Park, Yong-Soo
    • Corrosion Science and Technology
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    • v.13 no.2
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    • pp.70-80
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    • 2014
  • Duplex stainless steels with nearly equal fraction of the ferrite(${\alpha}$) phase and austenite(${\gamma}$) phase have been increasingly used for various applications such as power plants, desalination facilities due to their high resistance to corrosion, good weldability, and excellent mechanical properties. Hyper duplex stainless steel (HDSS) is defined as the future duplex stainless steel with a pitting resistance equivalent (PRE=wt.%Cr+3.3(wt.%Mo+0.5wt.%W)+30wt.%N) of above 50. However, when HDSS is welded with gas tungsten arc (GTA), incorporation of nitrogen in the Ar shielding gas are very important because the volume fraction of ${\alpha}$-phase and ${\gamma}$-phase is changed and harmful secondary phases can be formed in the welded zone. In other words, the balance of corrosion resistance between two phases and reduction of $Cr_2N$ are the key points of this study. The primary results of this study are as follows. The addition of $N_2$ to the Ar shielding gas provides phase balance under weld-cooling conditions and increases the transformation temperature of the ${\alpha}$-phase to ${\gamma}$-phase, increasing the fraction of ${\gamma}$-phase as well as decreasing the precipitation of $Cr_2N$. In the anodic polarization test, the addition of nitrogen gas in the Ar shielding gas improved values of the electrochemical parameters, compared to the Pure Ar. Also, in the erosion-corrosion test, the HDSS welded with shielding gas containing $N_2$ decreased the weight loss, compared to HDSS welded with the Ar pure gas. This result showed the resistance of erosion-corrosion was increased due to increasing the fraction of ${\gamma}$-phase and the stability of passive film according to the addition $N_2$ gas to the Ar shielding gas. As a result, the addition of nitrogen gas to the shielding gas improved the resistance of erosion-corrosion.

Corrosion Rate of Buried Pipeline by Induced Alternating Current (교류가 유도되는 매설배관에서의 교류 부식속도 측정에 관한 연구)

  • Song H. S.;Kim Y. G.;Lee S. M.;Kho Y. T.;Park Y. S.
    • Journal of the Korean Institute of Gas
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    • v.5 no.3 s.15
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    • pp.63-72
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    • 2001
  • An alternating current (AC) corrosion using coupon and electric resistance (ER) probe has been studied. Coupon coupled with ER probe were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, In which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619 in case of coupon and 0.885 in case of ER probe.

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