• Resources Recycling
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• v.27 no.3
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• pp.30-38
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• 2018

In this study, the behaviors of Fe selective chlorination in ilmenite ore by using PVC or $CO-Cl_2$ gas mixture as reducing agents under the condition of 1173 K, for 60 minutes were investigated. The weight loss ratio was 28% when PVC was applied as the reducing agent. The condensate formed at the outlet of reaction tube was identified as $FeCl_2$ by X-ray diffraction analysis. From these results, it was observed that iron in ilmenite ore reacted with HCl gas and Fe was selectively removed in the form $FeCl_2$. However, when $CO-Cl_2$ gas mixture was used as a reducing agent, the weight reduction ratio was 54%, and the condensate formed at the outlet of reaction tube after the experiment was estimated to be $FeCl_3$. It was observed that the ilmenite ore reacted with the $CO-Cl_2$ gas mixture and was simultaneously removed in the form of $FeCl_3$ and $TiCl_4$. However, the results of X-ray diffraction of ilmenite ore after the reaction showed that Fe was almost removed.

• Journal of the Korean Society of Tobacco Science
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• v.29 no.2
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• pp.146-151
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• 2007

Gas phase and particulate phase radicals in mainstream cigarette smoke were determined Electron Spin Resonance(ESR) spectroscopy. The free radicals in particulate phase have been investigated by benzene extract of Cambridge Filter Pad containing the smoke condensate. Spin trapping method in conjunction with ESR was used to investigate free radicals in the gas phase of cigarette smoke. Several analytical experiments were conducted in order to determine the optimal conditions for maximum signal intensities and reproducibility of results. All the tests were optimized and normalized using the University of Kentucky 2R4F reference cigarette. The optimal conditions were 0.6 mL for analysis volume of ESR, $4{\sim}5\;mL$ for collection volume of spin-adducts, and PBN for quantification of free radicals in gas phase. The radical levels of Kentucky 2R4F cigarettes were found $2.18{\times}10^{14}\;spins/cig.$ and $2.10{\times}10^{15}\;spins/cig.$ in gas phase.

• Corrosion Science and Technology
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• v.22 no.5
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• pp.351-358
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• 2023

Although many thermal power plants use heat recovery systems, high exhaust gas temperatures are maintained due to corrosion at dew points and ash deposits caused by condensate formation. The dew point of exhaust gas is primarily determined by the concentration of SO₃ and steam, and various experiments and calculation equations have been employed to estimate it. However, these methods are known to be less suitable for exhaust gases with low SO₃ concentrations. Therefore, in this study, since the temperature of the exhaust gas is expected to decrease due to the low-load operation of the coal-fired power plant, sulfuric acid condensation and low-temperature corrosion are anticipated. We aimed to conduct a quantitative evaluation to propose ways to prevent damage by limiting operating conditions and improving facilities. The experimental results showed that the corrosion rate increased linearly with rising temperatures at a certain sulfuric acid concentration. Furthermore, variations in sulfuric acid concentrations generated during the current power plant operation process did not significantly affect the dew point, and the dew point of sulfuric acid under these conditions was observed to be between 120 - 130 ℃.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.11 no.4
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• pp.183-188
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• 1978

In this study, gas chromatographic analysis was carried out on volatile constituents of cooked squid for the object of obtaining information on the characteristic flavor of the cooked squid meat. The results obtained are as follows: 1) Methanol was the most effective solvent for the extraction of volatile constituents of squid meat. 2) Twenty five and thirty two peaks were detected from the condensate collected in cold traps which were immersed in ice water and dry ice-acetone, respectively. In these compounds, five kinds of volatile organic acids such as acetic acid, butyric acid, iso-valeric acid, valeric acid, and caproic acid were identified. 3) Eleven peaks were detected from the head space vapor collected in cold trap which is immersed in liquid nitrogen. Volatile amines identified in these components are as follows; methylamine, trimethylamine, dimethylamine, ethylamine, and iso-propylamine.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.9
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• pp.817-824
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• 2000

The fluidized solid particles not only increase heat transfer rates but have a cleaning function eliminating contaiminated substances caused from condensate water. An experiment was performed to measure heat transfer rates and pressure drops in a fluidized heat exchanger with circulating solid particle for constant heat transfer rate. As a results, the heat transfer rate increased by 26.9~2.6%, heat transfer coefficient by 11.9~2.7%, and pressure drop by 79.1~10.9% at the gas velocity of 6.1 ~12.1 m/s and solid particle flow rate of 100~50 kg/h with the heat exchanger of H: 50 mm, $D_p=2 in,\; and\;D_{BP}$=30 mm.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2012.10a
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• pp.55-57
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• 2012

Suez운하를 이용할 경우 부산항에서 로테르담항까지의 수송거리가 11,340마일이 북극해 항로를 이용할 경우 6,860마일로 36%가 줄고 수송기간도 10일 이상 단축되므로 북극해항로를 통한 유럽과 아시아간의 상업적인 수송이 이뤄진다면 해운회사들의 물류비용이 대폭 절감될 것으로 전망된다. 이런 시점에서 2011년 9월 한-러 국장급 해운회담이 열렸으며, 2011년 11월 23일 부산 누리마루 APEC House에서 "북극해항로 상업운항의 현황과 전망"이라는 주제로 국제세미나가 개최 되었다. 현재 북극해 항로를 통과한 선박이 2007년 2척, 2008년 3척, 2009년 4척, 2010년 10척이었던 것이 2011년에는 34척 총 82만톤의 통과 수송이 이뤄졌고, 러시아 북극내의 물동량은 2백20만톤에 달할 것으로 전망되었으며, 2012년의 통과 물동량은 100만톤을 상회 할 것으로 전망된다. 이에 북극해 항로에 대한 소개와 빙하지역을 항해하는 선박에 대한 운항지침에 대하여 검토해보고저 한다.

• Archives of Pharmacal Research
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• v.5 no.2
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• pp.71-77
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• 1982

Improvements in the analytical methodology used in the gas chromatographic/mass spectral analysis of phenolic compounds from cigarette smoke are described. For the direct analysis of crude samples, pyridine extraction and the glass capillary column GC was used for the separation of phenolics as trimethylsilyl derivativatives. The separations of cigarette smoke on Carbowax 20M and SE-54 wall coated open tubular columns are given. Improved methodology for the routine quantitation of the identified components using the computer-controlled multiple ion selection technique of MS presented. Considerations pertaining to routine analyses of a multitude of complex smoke samples are also discussed.

• Journal of the Korean Society of Safety
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• v.35 no.3
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• pp.96-104
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• 2020

The numerical simulations were conducted to investigate the thermal-fluid phenomena occurred inside the experimental apparatus during a PCCS, used to remove heat released in accidents from a containment of light water nuclear power plant, operation. Numerical simulations of the flow and heat transfer caused by wall condensation inside the containment simulation vessel (CSV), which equipped with 18 vertical heat exchanger tubes, were conducted using the commercial computational fluid dynamics (CFD) software ANSYS-CFX. Shear stress transport (SST) and the wall condensation model were used for turbulence closure and wall condensation, respectively. The simulation using the actual size of the apparatus. However, rather than simulating the whole experimental apparatus in consideration of the experimental cases, calculation resources, and calculation time, the simulation model was prepared only in CSV. Selective simulation was conducted to verify the effects of non-condensable gas(NC gas) concentration, CSV internal pressure, and wall sub-cooling conditions. First, as a result of the internal flow of CSV, it was observed that downward flow due to condensation occurred surface of the vertical tube and upward flow occurred in the distant place. Natural convection occurred actively around the heat exchanger tube. Due to this rising and falling internal flow, natural circulation occurred actively around the heat exchanger tubes. Next, in order to check the performance of built-in condensation model using according to the non-condensable gas concentration, CSV internal flow and wall sub-cooling, the heat flux values were compared with the experimental results. On average, the results were underestimated with and error of about 25%. In addition, the influence of CSV internal pressure and wall sub-cooling was small, but when the condensate was highly generated due to the low non-condensable gas concentration, the error was large compared to the experimental values. This is considered to be due to the nature of the condensation model of the CFX code. However, in spite of the limitations of CFD, it is valid to use the built-in condensation model of CFD for PCCS performance prediction from a conservative perspective.

• Plant Journal
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• v.9 no.3
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• pp.38-42
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• 2013

Submarine gas fields have focused because of the increasing fuel cost, the environmental regulations, and the safety & NIMBY problems. LNG-FPSO which is available for acid gas removal, recovery of the condensate & LPG and Liquefaction in topside process is one of high technology offshore structures. On the other hands, it is necessary to verify the pre-treatment efficiency by the ship motion and to apply to the design for LNG-FPSO. This study is to develop the pre-treatment technology for LNG-FPSO as taking account to the process efficiency by ship motion effects and the area optimization. Based on the simulation results, it founds that hybrid process shows the low circulate rate, the low heat duty and the small size of column dimensions compared to typical amine process. It will be verified the process efficiency in the various conditions by sea states as performing the 6-DOF motion test and CFD simulation.

• Journal of the Korean Society of Visualization
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• v.14 no.2
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• pp.18-24
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• 2016

This paper presents an experimental investigation to visualize cross-sectional two-phase flow structure and identify liquid-gas interface for condensation of steam at a low mass flux in a slightly inclined tube using the axial-viewing technique, which permits to look directly into flow during condensation of steam. In this technique, two-phase flow is viewed along the axis of a pipe by locating a high-speed video camera in front of a viewer that is fitted at the outlet of the pipe. A short section of the pipe is illuminated and is recorded through the viewer, which is kept free of liquid by mildly introducing air. Experiments were conducted in a pipe of 19.05 mm in inner diameter at atmospheric pressure. Cross-sectional two-phase flow structure is obtained at a steam mass flux of $2.62kg/m^2s$ as a function of steam quality in the range from 0.5 to 0.9. The results show that stratified-wavy flow is a unique flow pattern observed in the scope of the present study. Condensate film thickness, stratification angle and void fraction were measured from the obtained flow structure images. Finally, heat transfer coefficient was calculated using the measurement data and discussed in comparison with existing correlations.